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Performance of borate-treated lumber in a protected, above-ground field test in Japan
2004 - IRG/WP 04-30344
This document is supplemental to the previous IRG document (Tsunoda et al., 2002). An experiment to simulate the sill plate (dodai) of the Japanese houses was conducted at the termite field test site of the Wood Research Institute in Kagoshima, Japan where two economically important subterranean termite species [Coptotermes formosanus Shiraki and Reticulitermes speratus (Kolbe)] are established. ...
K Tsunoda, A Byrne, P I Morris, J K Grace


Borate diffusion from fused borate rods in douglas-fir transmission poles
1994 - IRG/WP 94-30042
Pressure-treated utility poles have given many years of excellent service, but their lifetime is often shortened by internal decay of the untreated heartwood center, particularly in refractory species, such as Douglas-fir. This paper reports the distribution of boron from fused borate rods installed in CCA-treated Douglas-fir transmission poles. The boric acid equivalent was roughly monitored by t...
T L Highley, W Finney, F Green III


Termite resistance of borate-treated lumber in a three-year above-ground field test in Hawaii
2000 - IRG/WP 00-30236
A protected above-ground field test simulating the sill plate (dodai) used in conventional Japanese housing construction was established in both Hawaii and Japan to examine the efficacy of disodium octaborate tetrahydrate (DOT, 2% and 3% shell and through) wood treatments. In Hawaii, chromated copper arsenate (CCA, 4 kg/m3) and ammoniacal copper zinc arsenate (ACZA, 4 kg/m3) were included in the t...
J K Grace, R J Oshiro, A Byrne, P I Morris, K Tsunoda


Borate Protection and Termites: Variation in Protection Thresholds Explained
2006 - IRG/WP 06-20324
Laboratory and field data reported in the literature are confusing with regard to ‘adequate’ protection thresholds for borate timber preservatives against subterranean termites. The confusion is compounded by differences in termite species, timber species and test methodology. Laboratory data indicate a borate retention of 0.5% mass/mass (m/m) boric acid equivalent (BAE) would cause > 90% t...
B C Peters, C J Fitzgerald


Performance of borate-treated lumber after 8 years in an above-ground termite field test in Hawaii
2006 - IRG/WP 06-30390
We report eight years of field study results from a protected above-ground field test in Hawaii simulating the sill plate (dodai) used in conventional Japanese housing construction. Field tests were established in both Hawaii and Japan to examine the efficacy of disodium octaborate tetrahydrate (DOT, 2% and 3% BAE shell and through) wood treatments. In Hawaii, chromated copper arsenate (CCA, 4 kg...
J K Grace, A Byrne, P I Morris, K Tsunoda


Performance of borate-treated lumber in a protected, above-ground field test in Japan
2006 - IRG/WP 06-30395
This document is supplemental to the previous IRG document (Tsunoda et al. 2004). An experiment to simulate the sill plate (dodai) of the Japanese houses was conducted at the termite field test site of the Research Institute for Sustainable Humanosphere of Kyoto University in Kagoshima Pref., Japan where two economically important subterranean termite species [Coptotermes formosanus Shiraki and R...
K Tsunoda, A Byrne, P I Morris, J K Grace


Preliminary screening of a boron based wood preservative for biological efficacy (fungicidal) in treated timber
2006 - IRG/WP 06-30396
The resistance of Pinus radiata D.Don sapwood blocks, treated with a boron based preservative, to attack by five wood destroying fungi (Fomitopsis lilacino-gilva, Coniophora olivacea, Gloeophyllum abietinum (boron resistant), Serpula lacrymans and Perenniporia tephropora) was investigated. A phenyl pyrazole termiticide (fipronil) was also incorporated into the formulation to examine if its presen...
S R Przewloka, J A Hann, P Vinden


One year performance of graveyard stakes in the Northern Territory of Australia
2006 - IRG/WP 06-30398
This paper presents the one year progress performance of in ground graveyard stakes exposed to numerous termite species and decay fungi in tropical field conditions. The field study examines the efficacy of a new timber preservative formulation developed at the University of Melbourne, Australia. The biocides used in the formulation are fipronil (a phenyl pyrazole) and trimethyl borate. The pre...
B Ahmed, J Hann, S Przewloka, P Vinden, P Blackwell, P Plews


Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


Copper borate for the protection of engineered wood products
2006 - IRG/WP 06-40334
Copper borate was evaluated for use in protecting oriented strand board (OSB) from mould, decay, and termites. Aspen OSB bonded with either phenolic or isocyanate resin was treated with several formulations of copper borate at various loadings from 0.26 to 4 percent by weight. These panels were then tested to determine the impact of the preservative on mechanical properties as well as resistance ...
R Smart, W Wall


Potential for controlling carpenter ants in utility poles with borates
2007 - IRG/WP 07-10623
Carpenter ants (genus Camponotus) are important scavengers and predators in the ecosystems in which they occur. Because they excavate and tunnel into wood, carpenter ants are considered structural pests in many parts of North America where they overlap with human activity. The excavation of extensive galleries in wood by carpenter ants can seriously compromise the physical properties of wood in ...
M Mankowski


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Treatment of Green Logs infested by Exotic Pest: Case Study of the Emerald Ash Borer: Agrilus planipennis Fairmaire
2007 - IRG/WP 07-10628
Invasive alien insect species periodically infest forests in the United States causing the destruction of plant species and decimating populations, resulting in significant economic and ecological losses for areas involved. The Emerald Ash Borer (EAB) was first discovered on North American soil in the summer of 2002 near Detroit, Michigan and has since spread to several other Midwestern states and...
P Nzokou, S Tourtellot, D P Kamdem


Developments in Borate Treatment of Canadian Species for Decay and Termite Resistance
2007 - IRG/WP 07-30443
The increased interest in boron treatment of wood over the past 20 years is mainly due to its environmental acceptability, potentially deep penetration in wood, and its efficacy against decay and termites. Based on Forintek’s research in the past two decades, the boron penetration and retention requirements for decay and termite protection in various national and international standards for Cana...
Jieying Wang, P Morris, S McFarling, T Byrne


Performance of softwood preservative treated stakes after 4 years exposure in-ground to decay fungi and termites in tropical Australia
2008 - IRG/WP 08-10643
This field study was based on the 1993 IUFRO method and designed as a graveyard (in-ground) test in the tropical region of the Northern Territory to examine the efficacy of novel preservative formulations developed as alternative protection for softwood timber against decay fungi and termites for Hazard Class 3 and 4. This study was supported by the Forest and Wood Products Research and Develop...
B M Ahmed (Shiday), J R J French, S R Przewloka, P Vinden, J A Hann, P Blackwell


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Soft Rot Determines Service Life of L-joints with Low Borate Loading
2008 - IRG/WP 08-30470
As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and amabilis fir) in 1990. The treated material had a low initial retention of only 0.2% boric acid equivalent and analysis after 5 years revealed no detectable borate close to the tenon. Nev...
P I Morris, J Wang, J K Ingram


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Performance of Fasteners in Treated Wood: A Comparative Study
2009 - IRG/WP 09-40465
Fastener performance is an important property for treated wood. Published data on screw and nail performance for different preservative systems currently on the market are, however, limited. In this study, screw and nail withdrawal strength for southern pine wood treated with ACQ (above ground and ground contact), MCQ (above ground and ground contact), borate (disodium octaborate tetrahydrate – ...
Q Wu, T Shupe, J Curole, K Ragon, M Voitier, M Freeman, D Ring


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Effect of Nano-Silver Treatment on Densified Wood Properties. Part One: Swelling, Recovery Set, Bending Strength
2010 - IRG/WP 10-40533
In this research the effect of Nano-Silver treatment on compressed wood properties, was studied. Wood specimens were cut from Popolus alba (poplar) and impregnated with Nano-Silver and water. Then the saturated samples were compressed through radial direction in a hot press under pressure of 6 MPa, for 1 and 4 hours. The temperatures of press were 150°C and 175°C. Swelling (24h), recovery set ...
G Rassam, H Reza Taghiyari, B Jamnani, M Ali Khaje


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