Your search resulted in 78 documents. Displaying 25 entries per page.
A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick
Comparison of Micronized Copper Particle Sizes
2010 - IRG/WP 10-30538
The particle sizes of micronized copper formulations derived from treating liquids were compared with those deposited in wood treated with those liquids. The intent was to determine if agglomeration occurs in the liquids during the treatment process, if screening of the agglomerates occurs in the wood and if there are any apparent differences in the particle sizes in the wood. Three formulations...
C R McIntyre
Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre
Studies on Effect of pH on Copper Availability in Copper-Based Preservatives
2010 - IRG/WP 10-30549
Laboratory methods have been employed to investigate the pH effect on the copper solubility of basic copper carbonate. The pH was controlled using two different approaches. One was with the adjustment of pH of the solutions by acid or base using sulfuric acid or sodium hydroxide until the solution equilibriums were obtained for each defined pH. A second approach was to control pH with buffer sol...
L Jin, P Walcheski, A F Preston
Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora
A comparison of the corrosion of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-40515
With the replacement of chromate copper arsenate (CCA) by alkaline copper wood preservatives, there have been reports of increasing corrosion of metal fasteners and connectors in contact with treated wood. This may be explained by the presence of more mobile copper in the treated wood. One novel industrial response has been to develop a wood preservative based on an aqueous solution containing sus...
M Kofoed, J N R Ruddick
Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman
Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora
Quantification of mobile copper (II) levels in micronized copper treated wood
2011 - IRG/WP 11-40550
The purpose of this study is to quantify the mobile copper(II) levels in micronized copper treated wood using electron paramagnetic resonance (EPR) spectroscopy. A correlation between EPR and EDX intensities on mobile copper levels in a series of copper sulphate treated wood was created as a calibration standard. Laboratory treatments using micronized copper formulations were then carried out and ...
Wei Xue, P Kennepohl J N R Ruddick
Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem
Use of X-Ray Micro-Computed Tomography to Visualize Copper in Preservative Treated Wood
2012 - IRG/WP 12-20488
This study tests the hypothesis that X-ray micro-computed tomography will be able to visualize the distribution of copper in wood treated with a micronized wood preservative containing copper carbonate. A small wood block measuring 12 x 12 x 19 mm was cut from a 2.4 m x 51 mm x 51 mm southern pine batten that had been treated with a micronized wood preservative. Tomograms of the wood block were ob...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden, M A Knackstedt
Mobilized copper(II) concentrations in earlywood and latewood of micronized copper treated red pine
2012 - IRG/WP 12-30596
Electron paramagnetic resonance (EPR) was used in conjunction with energy dispersive x-ray spectroscopy (EDX) to quantify total copper and mobilized copper retentions in MCQ and MCA treated red pine. The MCQ treated red pine was found to have higher copper retention than that of the MCA treated one. Earlywood in general had higher total copper content than latewood. The mobilized and complexed cop...
Wei Xue, P Kennepohl, J N R Ruddick
A case study of investigating fungi that affect traditional Japanese shake roof with/without copper plates
2013 - IRG/WP 13-10810
A Japanese traditional shake roof is made from split logs. To keep the roof long, copper (Cu) plates are often inserted between the shakes. It has been thought that Cu elements from copper plates would flow out when a shake roof is exposed to rain and inhibit growth of wood rotting fungi. Actually there are some examples where the Cu plates seem to be effective in preventing fungal damage, but on ...
T Wada, Y Fujiwara, Y Fujii, R Kigawa
Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre
Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick
Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani
Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar
Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products.
In this study the efficacy of wood treated with micronized copper, zinc oxide and their
mixture was compared to that of wood treated with soluble amine copper oxide with
subterranean termites in a laboratory test. All of the formulations tested were effective in
controlling wood degradation by the term...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani
Chemistry of copper preservative treated wood
2014 - IRG/WP 14-30651
The reaction chemistry of micronized copper wood preservatives is fundamentally different from any previous inorganic preservative system. In order to study the chemistry, analytical procedures had to be developed which allowed the determination of the total copper as well as the copper which reacted with the wood forming copper-wood complexes. With the success of this approach it also became poss...
Wei Xue, P Kennepohl, J N R Ruddick
Evaluation of color and gloss in decorative applied to cases of Pinus radiata wood impregnated (D. Don) copper type C azole micronized
2015 - IRG/WP 15-20571
Six treatments (one control and five decoration coatings) were applied to radiata pine wood treated with micronized copper azole (uCA-C), for outdoor use (R3) at a rate of 3.08 kg/m3 retention (T2). One decoration coating was applied before impregnation treatment: Prestain P (T3), and two, were applied in mixture with the uCA-C preservative Black Cylinder (T5) and Red Cylinder (T4). Two varnish we...
R Garay, M Inostroza
Environmental Fate of Micronized Copper
2015 - IRG/WP 15-50310
The environmental fate of wood preservatives is an important aspect to estimate the health and environmental impact. Although biocides from treated wood may be released into the soil, water or air, the latter pathway is frequently neglected in favour of leaching studies. Nonetheless, wood dust is well known to cause a variety of adverse health effects, in particular diseases to the respiratory tra...
C Civardi, L Schlagenhauf, J Benz, C Hirsch, J Van den Bulcke, M Schubert, J Van Acker, P Wick,
Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton
Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick
Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris
Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans