IRG Documents Database and Compendium


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Development of threshold values for boron compounds in above ground exposures: Preliminary trials
1998 - IRG/WP 98-30179
Boron is increasingly used both as an initial and remedial treatment for protecting wood against fungal and insect attack. While establishing lethal dosages for boron against insects through feeding tests is relatively simple, establishing thresholds for fungal attack poses more of a challenge. Tests using boron dispersed in agar artificially surround the fungus with both boron and excess nutrient...
J J Morrell, C M Freitag, S Unger


The influence of staining fungi on the decay resistance of wood treated with alkylammonium compounds
1984 - IRG/WP 3308
Although found to be very effective in laboratory tests, alkylammonium compounds (AAC's) have failed to perform as well in field stake tests. Examination of leachability showed that this was not the cause. The present study investigated the possibility that staining fungi, (which have been observed to rapidly infect the field stakes), degrade the AAC wood preservative. Soil-blocks were tr...
J N R Ruddick


Environmentally benign wood preservatives based on organic biocide antioxidant combinations: A brief review of laboratory and field exposure results and discussion of a proposed mechanism
2004 - IRG/WP 04-30335
The combination of various organic biocides with commercial antioxidants generally increased the biocides’ efficacy 2-3 fold against wood-destroying fungi in short-term laboratory decay tests, and some positive results have been obtained after 2-4 years of outdoor exposure. The two antioxidants principally examined, propyl gallate and butylated hydroxytoluene, are low cost and, since both are f...
T Schultz, D D Nicholas, W Henry, C Pittman, D Wipf, B Goodell


Recovery of copper, chromium, and arsenic compounds from the waste preservative-treated wood
1991 - IRG/WP 3651
In Japan, about 40 percents of waste wood is incinerated and the residue is dumped into the landfill site. The waste preservative-treated wood, which is mixed in nontreated wood, is incinerated in the same way, too. However, it will cause the serious problems that the gases contained with high concentration arsenic compounds are discharged from the smokestacks of the incineration facilities and th...
A Honda, Y Kanjo, A Kimoto, K Koshii, S Kashiwazaki


The potential application of rapid gas-chromatographic assay of microbial respiration to the monitoring of wood decay in field trial situations
1983 - IRG/WP 2196
Gas chromatographic detection of microbial activity (C02 production) within stakes in a field trial situation would appear to provide a sensitive, non-destructive and relatively rapid method for the quantitative assessment of preservative treatments. Most consistent results were obtained when stakes were removed from the soil, washed, saturated with water and incubated in sealed PVC tubes at 25°C...
M A Line


Chemical and biological investigations of double-vacuum treated windows after 5 years in service
1983 - IRG/WP 3219
In 1980 The Swedish Wood Preservation Institute initiated an investigation to study the degradation of TBTO and possible fungal attack in double-vacuum treated window joinery in service during 5 years. A hospital in Gothenburg was chosen that was built during 1969 to 1976. Both untreated and double-vacuum treated windows of Pinus sylvestris were used. A brown alkyl oil type paint (Nordsjö system ...
J Jermer, M-L Edlund, B Henningsson, W Hintze, S V Ohlsson


Log fumigation prevents enzyme-mediated sapwood discolorations in hardwoods
1993 - IRG/WP 93-10003
Non-microbial sapwood discolorations in hardwood lumber can cause economic loss by degrade of quality. Based on the hypothesis that the enzyme-mediated sapstain may develop in part from byproducts of parenchyma cells in wood, reshly felled logs of red oak (Quercus spp.) and sugar hackberry (Celtis laevigata) were fumigated under a plastic tarp with methyl bromide. Log sections were checked after f...
E L Schmidt, T L Amburgey


Bibliography on the use of boron compounds for the preservation of wood
1973 - IRG/WP 315
This bibliography is based on an earlier literature survey prepared by J. Thornton and Wm. E. Bruce (O.E.C.D. Document No. 27/DAS/CSI/M/91) which was enlarged and revised for a meeting in Paris in October 1968 (Document 27/DAS/CSI/M554) by Professor W. Bavendamm of Reinbek. The latter (1968) document with its 166 references has now been extended and brought up to date. Acknowledgments are due to B...
R Cockcroft, J F Levy


The production of extracellular hydrogen peroxide by some brown-rot fungi
1990 - IRG/WP 1446
The role of hydrogen peroxide (H2O2) has been discussed in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by detecting the oxidation of the chromogen 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horse radish peroxidase (HPR). ABTS and HPR were added to a solid wood based culture media. In this study ...
A-C Ritschkoff, L Paajanen, L Viikari


A laboratory evaluation of tributyltin ethanesulphonate as an aqueous fungicide in wood preservation
1983 - IRG/WP 3229
Toxic limit data, using both leached and unleached wood test blocks, are reported for aqueous solutions of tributyltin ethanesulphonate against four Basidiomycete fungi, Poria placenta, Gloeophyllum trabeum, Coriolus versicolor and Coniophora puteana. An in situ study of the tributyltin compound in Scots pine and ponderosa pine sapwood has been carried out, using the technique of 119mSn Mössbauer...
R Hill, P J Smith, J N R Ruddick, K W Sweatman


Fungitoxic effect of the quaternary ammonium compounds wood preservatives against the Ascomycetes and Deuteromycetes
1997 - IRG/WP 97-30138
Results of investigation on fungitoxic value of the three formulations of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethylbenzylammonium bromide, alkylbenzyldimethylammonium chloride) in relation to the surface wood colouring (moulds) and soft-rot fungi have been presented. The agar-plate (screening) and agar-wood plate for mouldi...
J Wazny, P Rudniewski


The detection of organic solvent preservatives in wood by thin-layer chromatography
1975 - IRG/WP 357
A simple and rapid method for the detection of common organic solvent wood preservative materials is described. The method uses thin-layer chromatography after leaching of the preservative from sections of timber with chloroform. RF values and the sensitivity of the method are discussed and a routine procedure for identification of the organic and organometallic preservatives is proposed. Methods ...
B G Henshaw, J W W Morgan, N Williams


Prevention of non-microbial sapwood discolorations in hardwood lumber: chemical and mechanical treatments
1997 - IRG/WP 97-30137
Sapwood discolorations in hardwood lumber that are non-microbial in origin result from the formation of pigmented starch-like granules in ray parenchyma cells. These discolorations can be prevented by treating unseasoned lumber with an antioxidant (sodium bisulfite). Exposing unseasoned lumber to microwaves or treating logs with fumigants also will prevent these discolorations. Subjecting unseason...
T L Amburgey, S Kitchens


Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda


The use of light organic solvents in industrial wood preservation - an environmental perspective
1995 - IRG/WP 95-50040-22
The paper examines the evolving regulatory environment concerning the use of hydrocarbon solvents in industry and, in particular, the European wood preserving sector. The implications of the proposed EU Directive on industrial solvent use are explained and possible responses to such regulation examined, including process modification, product changes and emission abatement, where necessary. The de...
G A Ewbank


A quantitative weathering study of wood surfaces modified by chromium VI and iron III compounds
1989 - IRG/WP 2330
Thin veneers of Pinus radiata were treated with dilute aqueous solutions of chromium VI and iron III compounds and exposed to natural weathering for 35 days. Zero-span tensile strength and weight losses of treated veneers were compared with losses observed in untreated specimens In a study designed to demonstrate the applicability of strength and weight loss measurements to the rapid quantitative ...
P D Evans, K J Schmalzl


Borates as wood preserving compounds: The status of research in the United States
1989 - IRG/WP 3542
This paper describes the extensive, on-going cooperative research effort among government and university research laboratories and industry to fully evaluate the potential for borates as wood preservatives in the United States. Research is discussed in terms of laboratory evaluations, field testing and mill trials, pilot plant pressure treatment studies, and remedial treatments. Future research pl...
H M Barnes, T L Amburgey, L H Williams, J J Morrell


Persistence and residual activity of organophosphorus termiticides in soil and prevention against the degradation of chlorpyrifos
1991 - IRG/WP 1518
The persistence and the residual activity of four comercial organophosphorous termiticides, Chlorpyrifos, Fenitrothion, Tetrachlorvinphos, Pyridaphenthion, in soil were studied under laboratory conditions. The persistence and the residual activity of four organophosphorous termiticides in two types of soil decreased with the lapse of time. These termiticides were mostly degraded by microorganisms ...
T Iijima, M Tanaka, M Higaki


The importance of blue stain attack for the colonization by wood-rotting fungi of wood not in contact with the ground
1988 - IRG/WP 1349
When used in constructions not in contact with the ground, wood has been shown often to proceed from blue stain to moulds. The appearance of wood rotting fungi is normally delayed. Solid wood artificially inoculated with the blue stain fungus Pullularia pullulans was shown to permit germination of Pycnoporus cinnabarinus basidiospores. This was demonstrated by the use of an indirect and a direct b...
J Bjurman


Preliminary observations on tributyltin treated Scots pine sapwood using 119Sn (Mössbauer and NMR) spectroscopic techniques
1984 - IRG/WP 3312
119mSn Mössbauer data are presented for bis(tributyltin) oxide, tributyltin ethanesulphonate, bis(tributyltin) carbonate and tris(tributyltin) phosphate, both in the pure form and in Scots pine sapwood. The structures proposed for these compounds, in the solid state, are supported by 119Sn nuclear magnetic resonance spectroscopy.
R Hill


Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar


A new preservative - A double-edged sword
1990 - IRG/WP 3573
Increasing environmental pressures on the use of pesticides throughout the world will impact more on the use of all wood preservatives. In particular the use of traditional wood preservatives and methods of application are under close scrutiny. The industry is responding to the challenge of developing alternative products and systems but faces great problems due to the excellent performance and sa...
M Connell, J A Cornfield, G R Williams


Future insecticidal treatments for wood products
1980 - IRG/WP 3140
Protective measures involving chemical treatment of wood use only a narrow range of toxic materials which are divisible into two groups, (i) those that are water-soluble, (ii) those that are soluble only in organic solvents. It is generally true to say that, as far as protection against insects is concerned, the former are stomach poisons while the latter are largely (though not exclusively) conta...
D J Cross


Chemical and biological investigations of double-vacuum treated windows after 7½ years in service
1985 - IRG/WP 3339
Earlier investigations of double-vacuum treated windows after five years in service have shown that tributyltin oxide (TBTO) degrades to di- and monobutyltin compounds and that the resistance of the wood against decay decreases. An investigation 2.5 years later of the same windows shows that the degradation of TBTO proceeds fast. After 7.5 years in service only 15-35% of the remaining organotin co...
M-L Edlund, J Jermer, B Henningsson, W Hintze


Performance of proprietary formulations of anti-sapstain preservatives on Hevea brasiliensis timbers in laboratory tests
1989 - IRG/WP 3532
A total of 10 proprietary and two experimental formulations were assessed for their effectiveness against sap-stain caused by Botryodiplodia theobromae on Rubberwood (Hevea brasiliensis). Sterilized wood samples 5x20x40 mm³ were dipped in the test chemicals for 60 seconds and then inoculated with 0.5 ml of culture filtrate of Botryodiplodia theobromae for incubation in sterile, damp petri dishes....
L T Hong


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