IRG Documents Database and Compendium


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Leaching of Arsenic from Mulch Made from Recycled Construction and Demolition Wood
2005 - IRG/WP 05-50232
Mulch made from recycled construction and demolition (C&D) wood has been reported to contain chromated copper arsenate (CCA)-treated wood and potentially release arsenic in the leachate by rainfall. Such recycled wood mulch is commonly masked with iron-oxide colorant, which is known to combine with arsenic. The objective of this study was to evaluate the levels of arsenic leaching from C&...
T Shibata, H M Solo-Gabriele, T G Townsend, B Dubey


The new National Directive on wood preservation in the Netherlands
1998 - IRG/WP 98-50101-03
In the Netherlands the major part of treated timber is sold under the KOMO-certificate. The National Directive for vacuum pressure treated timber on which certification is based, is currently being revised. The new National Directive will contain a code of good practice including maximum leaching figures. It incorporates quality requirements for treated timber, existing legislative requirements an...
W J Homan, J K B Kwisthout, J Dubelaar


Copper leaching from Kemwood ACQ and Embalit CBC treated wood products
2000 - IRG/WP 00-50150
TNO has performed a study on the leaching of copper from Kemwood ACQ and Embalit CBC treated wood products, further referred to as ACQ and CBC. The sawn dry wood has been impregnated using an industrial vacuum-pressure process with ACQ (with or without Ultrawood 4) or with CBC, under supervision of Flexchemie B.V. After treatment samples have been transported and subjected to leaching tests at TNO...
P Esser, W L D Suitela, H Trompetter


Effectiveness of CCA fixation to avoid hexavalent chromium leaching
2002 - IRG/WP 02-50187
It is generally assumed that hexavalent chromium in chromated copper arsenate wood preservative is substantially reduced to trivalent chromium during fixation and that the potential to leach the more toxic CrVI is minimal. However, there are occasional claims some hexavalent chromium remains in wood after fixation and that small amounts of CrVI are available for leaching. One problem is that ot...
P A Cooper, D Jeremic, Y T Ung


The possible role of mobile CCA components in preventing spore germination in checked surfaces, in treated wood exposed above ground
2001 - IRG/WP 01-30263
Untreated check surfaces are often exposed in CCA-treated lumber of refractory species used above ground since, during weathering, some checks develop beyond the preservative penetrated zone. However, decay is seldom observed in these checks even after many years of exposure. It is hypothesized that minor amounts of mobile CCA preservative components redistribute during weathering into checks, and...
S Choi, J N R Ruddick, P I Morris


Evaluating possibilities of leaching of deltamethrin and TCMTB (insecticides and fungicide for protecting wood) by rain water or by soaking in water
1988 - IRG/WP 3464
Deltamethrin and TCMTB have been subjected to several field leaching tests on freshly fallen trees and in the laboratory, using standard EN 84. All the trials gave the same results and confirm that Deltamethrin and TCMTB are not washed out after they have been allowed to penetrate the trunk surface properly. According to the EN 84 standard, less than 1% Deltamethrin and less than 1.7% TCMTB were r...
J S Duguet, V Dartigues


Improvement of wood decay resistance by tannin impregnation
1991 - IRG/WP 2380
The fungical effect of tannins is appraised after exposure of treated woods samples to wood rotting fungi. A screening-test is carried out with several solutions containing extracts of two kinds of tannins; a condensed tannin derived from Quebracho heartwood (Schinopsis sp.) and a hydrolyzable one extracted from chestnut heartwood (Castanea sativa Mill). If a fungicidal action was indeed found it ...
D Dirol, A Scalbert


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Délavabilité de bois ronds traités avec un sel CCA dans des conditions réelles de stockage. Incidence pratique de la fixation accélérée par étuvage. Impact effectif sur l'environnement
1993 - IRG/WP 93-50001-23
Un essai de terrain a été organisé pour mesurer concrètement, dans des conditions aussi proches que possibles des conditions réelles de terrain, les pertes effectives en produit de traitement lorsque le bois traité est soumis à des intempéries. L'essai a été conduit sur des bois ronds (poteaux), traités en autoclave par procédé Bethell avec un sel CCA de type C, avec comme fi...
M Rayzal, F Larroze


Comparative study on leaching of CCA from treated timber: Modelling of emission data
1994 - IRG/WP 94-50027
Results of a comparative study on leaching of CCA from treated timber are reported. The study aims at investigating the applicability of prestandard leaching test methods for modelling purposes. Prestandards used are the European standard proposed by CEN/TC38/WG11 and NEN 7345 (Dutch prestandard for building materials). Parameters of study are type of fixation, wood species (pine - spruce), specim...
G M F Van Eetvelde, M Stevens, L Van der Mijnsbrugge


The effect of water-repellent additives on the leaching of CCA from simulated southern Yellow pine decks
2000 - IRG/WP 00-50158
End-matched SYP boards were pressure-treated with CCA or CCA in combination with commercial water repellent additives. After fixation and drying, the boards were placed in plastic boxes and exposed outside in Harrisburg, NC. Plastic supports were used to keep the boards above the water collected. Over a period of five months, rain run-off water from 14 natural rainfalls were collected and analyzed...
F Cui, P J Walcheski


Effects of fixation conditions and seawater on leaching of wood treated with marine retention CCA
1997 - IRG/WP 97-50088
The effect of post-treatment conditioning temperature and humidity on leaching of chromated copper arsenate (CCA) was compared in seawater and deionized water. Southern pine cubes treated to 40 kg/m3 CCA were stored at 2° C and 82% relative humidity (RH), 24° C and 65% RH, or 32° C and 30% RH for 3, 10, or 17 days. Cubes were then leached in deionized water or artificial seawater. The rate of l...
S T Lebow


Fixation of copper-chrome-arsenic treated timber: A comparison of leaching methodologies
1996 - IRG/WP 96-50075
Five packs of kiln dried radiata pine heartwood were treated with copper-chrome-arsenic preservative treated, utilising a modified Bethell treatment schedule. Two methods of determining the level of preservative fixation were compared. These included the diphenylcarbazide method and simulated rainfall testing. The fixation levels were generally higher for tests involving simulated rain leaching. F...
S Walley, P R S Cobham, P Vinden


Leaching characteristics, decay and termite resistance of treated wood with boron compounds, N'-N-(1,8-Naphthalyl) hydroxylamine (NHA-Na), and hydroxynaphthalimide (NHA-H)
2003 - IRG/WP 03-30307
Despite many advantages of boron wood preservatives, boron itself does not adequately protect wood in ground contact and exterior applications because its natural diffusibility and susceptibility to leaching. As a result of previous studies to limit or decrease boron leaching, several fixation systems have been developed. In this study, we evaluated the effects of N'-N-(1, 8-Naphthalyl) h...
S N Kartal, Y Imamura


An appraisal of methods for environmental testing of leachates from salt-treated wood; part 1
1998 - IRG/WP 98-50115
The magnitude and diversity of leaching tests with salt-treated wood, performed by institutes as well as industry, strongly appeal for harmonisation towards one single method. That procedure should be well-defined, cost- and time-effective and moreover be extended with a clear detection and interpretation scheme. The paper(s) presented here tend to evaluate 2 existing leaching methods, the ENV 12...
G M F Van Eetvelde, M Stevens, F Mahieu, H-W Wegen, A Platen


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


On-site test for indicative determination of leaching of components of preservatives from treated timber
1993 - IRG/WP 93-50001-12
In the late eighties the environmental concern about treated timber increased and it is still a hot issue in the Netherlands. From the environmental point of view three phases in the timbers life cycle can be distinguished: - the production phase - the service life - the waste phase. In the Netherlands at this moment much emphasis is laid on the production phase. In 1992 this has led to a new legi...
W J Homan, H Militz


Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi


The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren


Report on the co-operative leaching tests
1975 - IRG/WP 246
The Work reported here was undertaken at the request of CEN to see (1) whether the standard beaker leaching method under discussion at CEN, and based on the German DIN could be made less labour intensive; and (2) whether the leaching parameters could be expressed in more general terms so that alternative procedures could be used. A co-operative experiment was set up in which the amount of leaching...
J W W Morgan


Chlorothalonil: A new ground contact wood preservative
1992 - IRG/WP 92-3712
Extensive investigations have been conducted in recent years on the performance of chlorothalonil (tetrachloroisophthalonitrile) as a ground contact wood preservative. Efficacy information is presented on a soil block test with 11 Basidiomycetes, a fungus cellar evaluation, above-ground field testing against termites in Australia and Hawaii, and ground-contact field stakes installed in Florida (9 ...
P E Laks, T L Woods


Comparing the resistance of a number of lesser known species of tropical hardwoods to the marine borer Limnoria using a short term laboratory assay
2003 - IRG/WP 03-10500
Naturally durable species of timber are used as an alternative to preservative treated timber for marine structures, but many species have not been evaluated for their potential for use in this environment. EN 275 specifies a 5-year test period - too long a period for screening tests to be economically viable. In this study, durability was assessed by measuring the production of faecal pellets by ...
L M S Borges, S M Cragg, J R Williams


Silafluofen, a new insecticide against wood-boring insects and termites
1991 - IRG/WP 3666
Hoe 084498 (proposed common name: Silafluofen) is a new insecticidal compound from Hoechst Aktiengeesellschaft and has been extensively tested to determine its potential use as an insecticide against wood-boring insects and soil termites. Various tests in official institutes indicate a good activity against several wood-boring insects and soil termites. The active ingredient is resistant to weathe...
G Rustenburg, C J Klaver


Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching. According to BPD hazard assessment has to be carried out f...
N Morsing


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


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