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Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Biocidal property of the phenolic fraction of ethanol extractives of Hopea parviflora heartwood
1993 - IRG/WP 93-30003
Natural resistance of some species of timber to fungal decay and insect damage (particularly termite) is ascribed toxic nature and quantity of certain chemical substances present in the cell wall of heartwood. These chemical substances generally known to be Phenolic and Polyphenolic compounds (Rao 1982). Earlier investigations on extractives were mainly in relation to resistance of timber to decay...
R V Krishnan, K S Theagarajan, H S Ananthapadmanabha, M Nagaraja Sharma, V V Prabhu, H C Nagaveni


Leaching tests on CCA-treated wood using inorganic salt solutions
1984 - IRG/WP 3310
Pinus radiata sapwood treated to approximately 10 kg/m³ with Tanalith NCA or Tanalith C-type CCA preservatives was ground to a fine powder and samples were then leached with solutions of calcium chloride, calcium nitrate, magnesium nitrate, or a mixture of potassium di-hydrogen orthophosphate and di-potassium hydrogen orthophosphate, at 0.03M-1.00M solution concentrations. Leached wood samples we...
D V Plackett


Analysis of the boron content of preservative treated oak and pitch pine heartwood before and after leaching
1992 - IRG/WP 92-3697
Studies to determine the effects, if any, of a variety of boron formulations on heartwood of English oak and American Pitch pine have been previously reported (King et al (1991)). Small wood blocks were treated, at 10°C or 45°C, with borax, polybor or Boracol 20 for periods of 1 month or 4 months then analysed or continuously leached with tap water for a period of 1 month. Reported results showe...
S McCutcheon, G M Smith, J W Palfreyman, B King


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


Wood cement composites using spent CCA treated wood
1999 - IRG/WP 99-50126
The feasibility of using spent or out-of-service CCA treated wood as a component of wood/cement composites was evaluated. Cold pressed wood particle cement boards were made using CCA treated particles from a red pine (Pinus resinosa Ait.) pole removed from service and from untreated red pine wood from a new pole. Boards were manufactured using a range of wood to cement ratios and water to cement r...
Chen Huang, P A Cooper


A new process for in situ polymerization of vinyl monomers in wood to delay boron leaching
1998 - IRG/WP 98-40110
Efforts were accelerated on effective use of boron compounds in wood preservation owing to their environmentally safe characteristics and relatively low costs in addition to their well-known high bioactivity and fire resistant properties. Although having these unique favorable properties, they are readily leachable from treated wood at humid conditions. Therefore, they had limited market for exter...
M K Yalinkilic, W Dwianto, Y Imamura, M Takahashi


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Fixation of chromated wood preservatives through technical drying
1990 - IRG/WP 3623
Twin samples of sawn timber of Pinus sylvestris and Picea sp. were treated with copper-chromate-containing wood preservatives and subsequently kiln resp. air dried. After drying, the distribution of preservative and rate of fixation were determined. Drying of freshly treated wood in a condenser type kiln at temperatures of 60°C and 80°C and in a vacuum type kiln at 55°C with a pressure of about...
R-D Peek, H Klipp


Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


Upgrading the fungal resistance of OSB
1999 - IRG/WP 99-40138
There is a perception that oriented strand board (OSB) is less resistant to fungl than plywood under conditions of moderate exposure to moisture. Douglas fir-faced plywood (DFP) has been suggested as a benchmark for acceptable durability under such conditions. This project was initiated to determine the minimum level of low-toxicity chemical treatment needed to upgrade the fungal resistance of OSB...
P I Morris, J E Clark, D Minchin, R Wellwood


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


Resistance of board materials against fungal decay: A comparative experiment on Kolle flask tests method and direct test method
1985 - IRG/WP 2243
Two sets of plywood (Aucoumea klaineana Pierre) 7 and 11 ply, treated by two preservatives, and untreated, were tested by two methods: 1. Kolle flask test method on malt-agar substrate according to the French standard NF B 51.295; 2. A direct test method in non sterile conditions according to DocNo: IRG/WP/2214. The exposure time far both methods was 12 weeks. After exposure, the degree of attack ...
G R Y Déon, L N Trong


Residual CCA levels in CCA treated poles removed from service
2000 - IRG/WP 00-50152
Fifty-two CCA treated poles removed from service after 1 - 50 years were sampled at different depths from their below ground and above ground zones and the preservative levels and mass balances related to the location in the pole and pole age. Generally CCA retentions were still well above the toxic threshold for decay in even the oldest poles. This confirms the good leach resistance of CCA and th...
P A Cooper, D Jeremic, J L Taylor


Assessment of untreated Papua New Guinean timbers against subterranean termites. Progress Report 1
1990 - IRG/WP 1436
Eight major commercial timber species (Intsia palembanica, Pometia pinnata, Homalium foetidum, Dracontomelon dao, Calophyllum spp., Eucalyptus deglupta, Nothofagus spp., and Alstonia scholaris) were exposed in ground contact against termites. Five replicates of heartwood stakes of 25x25x250 mm³ of each species were randomly embedded in the soil. Results after 24 months exposure showed that Kwila ...
M Rokova, H C Konabe


Factors affecting the resistance of fibre building boards to fungal attack
1975 - IRG/WP 252
Fungal decay is initiated at lower moisture contents in standard and tempered hardboards (18%) than in pine sapwood (26%). In contrast, in a saturated atmosphere, the equilibrium moisture contents of standard hardboard (14%) and of tempered hardboard (12.5%) are much lower than the moisture content permitting decay initiation whilst the equilibrium moisture content of pine sapwood (25.1%) approach...
C Grant, J G Savory


Susceptibility of heartwood of three Pinus species to attack by the subterranean termite Coptotermes acinaciformis (Froggatt)
1994 - IRG/WP 94-20026
Heartwood of plantation-grown Pinus elliottii (slash pine), Pinus caribaea (Caribbean pine) and Pinus radiata (radiata pine) was obtained from a range of locations throughout Australia and New Zealand for use in a field bioassey with subterranean termites. Timber stock was analysed for a number of stilbene and flavonoid heartwood extractive components which could contribute to variation in suscept...
M J Kennedy, L L Dixon, B C Peters


Leaching from field test stakes. Results from two different methods of analysis
1993 - IRG/WP 93-50013
Field test stakes treated with Boliden K33 containing copper, chromium and arsenic exposed at three different fields in Sweden and rejected due to decay, have in two studies been analysed regarding leaching and remaining preservatives. The stakes have been exposed during 20 to 43 years. The density of the stakes and content of copper, chromium and arsenic have been determined in the top part of th...
F G Evans, M-L Edlund


Effects of heart wood extractives in Dahoma (Piptadeniastrum africanum) on decay resistance to white- and brown-rot fungi
2004 - IRG/WP 04-10536
Dahoma (Piptadeniastrum africanum) is a durable but a lesser utilised tropical hardwood species from Ghana that has the potential of being used as an alternative to Iroko (Milicia excelsa) for many end uses. However, the timber gives off a strong odour especially when wet and during processing. The high durability and the strong odour of the timber could be due to the presence of extractives in th...
Zeen Huang, K Maher, S A Amartey


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


The influence of UV and IR radiation on leaching of copper and chromium from preservative-treated pine and spruce
1992 - IRG/WP 92-3687
The influence of artifical UV- and IR-radiation on the leaching of copper and chromium components of a CCB-preservative from freshly treated pine and spruce was evaluated. On small pinewood samples it could be shown, that the leaching of copper and chromium can considerabely be reduced by UV-radiation. A Philips HPA lamp type reduced the leaching most effective. IR-radiation lead to higher leachin...
H Militz


Comparative study on the leaching of wood preservatives between natural exposure and accelerating laboratory conditions
1999 - IRG/WP 99-50134
Impregnated specimens with CCA, ACQ, and BAAC were subjected to leaching tests. Specimens of 2x2x1 cm3 in size were used for the laboratory leaching test for 10 days according to JIS K 1571. Specimens of 25x1 x1 cm3 were used for outdoor leaching test for 6 months. Total leaching amounts of boron per cm3 of specimens treated with BAAC were 325 µg in the laboratory test and 206 µg in the outdoor ...
K Yamamoto, S Motegi, A Inai


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


The resistance of wood coated with different water-borne paints against colonisation by decay fungi
1996 - IRG/WP 96-10165
The susceptibility of wood painted with model paints of known composition to decay fungi was tested without previous weathering. Included in the study were five alkyd emulsion paints and five acrylic paints; one linseed oil paint and two solvent-borne alkyd paints. It was found that several components influenced the susceptibility of these paints. The results of the present study indicate that the...
J Bjurman


A comparison of shower test results from CCF, CCZF, CCB and Cu-quat treated timber
1995 - IRG/WP 95-50054
The shower test quantifies the amount of specific preservative components which leach from treated timber under simulated open storage conditions. The test method measures leaching from both organic and inorganic salt treated timber. Shower tests of CCF, CCZF, CCB and Cu-quat treated timber which have been performed over the last 5 years by TNO are reviewed and compared. Leached components are qua...
M J Boonstra, A J Pendlebury, P Esser


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