IRG Documents Database and Compendium


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Differences and their causes of CCA and CCB efficacay among some softwoods and hardwoods
1991 - IRG/WP 3656
Wood blocks from two softwoods and two tropical hardwoods species treated with different concentrations of CCA, CCB, and combinations of CrO3, CuS04, H3BO3 were subjected to the decay by brown rot fungus, Tyromyces palustris. CCA maintained good effect both in softwoods and hardwoods, while CCB and the other combinations lost their effectiveness after leaching. Chemicals leached from CCA treated w...
K Yamamoto, M Rokova


Comparison of Temporal Changes in Metal Leaching and Aquatic Toxicity from Wood Treated with CCA and Alternative Preservatives
2005 - IRG/WP 05-50236
This study compares the temporal variation of chemical leaching and aquatic toxicity of wood treated with chromated copper arsenate (CCA) and other copper-based wood preservatives (alkaline copper quaternary (ACQ), copper boron azole (CBA), copper citrate (CC) and copper dimethyldithiocarbamate (CDDC)). Treated wood blocks were leached for 21 days and the leachate collected was analyzed for prese...
B Dubey, T G Townsend, G Bitton, H M Solo-Gabriele


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Leaching from field test stakes. Part 2: The distribution in and leaching from different parts of test stakes
1994 - IRG/WP 94-50026
Field test stakes treated with Boliden K33 (copper, chromium and arsenic) and Cuprinol Tryck (CT86) (copper and N-alkylbenzyldimethylammoniumchloride) respectively were exposed in ground contact at two different test fields in Sweden and rejected due to decay after 2 to 28 years. Stakes treated with the same preservatives were also exposed during 7 years above ground. The test stakes have been ana...
F G Evans, B Nossen, M-L Edlund


A report of the Technical Recommendations documents for the Canadian Wood Protection and Preservation Facilities and an environmental study of storm water runoff from anti-sapstain treatment plants
1988 - IRG/WP 3478
With the completion of the Final draft of the Technical Recommendations (TR) documents for the Wood Preservation and Wood Protection Industry, there are naturally questions on what is expected from these documents and how Environment Canada and Provincial regulatory agencies may interact with the wood preservation industry. In general, it is expected that the Canadian Wood Preservation and Protect...
G Das, V N P Mathur


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


Possible durability transfer from durable to non durable wood species. The study case of teak wood
2001 - IRG/WP 01-10392
Teakwood is well known for its excellent natural durability, mostly due to its high proportion of extracts. Amongst these extracts, quinones, and more precisely some naphtoquinones (such as lapachol) and anthraquinones (such as tectoquinone) appear to play a crucial role in the resistance to wood decay organisms. At a laboratory scale, sawdust from malaysian teak heartwood has been extracted under...
M-F Thévenon, C Roussel, J-P Haluk


Methods for the assessment of wood preservative movement in soil
1995 - IRG/WP 95-50040-08
This paper presents preliminary results from a series of experiments constructed to provide laboratory data for the evaluation of the leaching of wood preservatives into and through soil. The experiments included: i) measurement of the adsorption of preservatives by soil; ii) determination of the concentration gradient of preservatives in soil following percolation of preservative solution through...
G E Holland, R J Orsler


Collaborative soft rot tests: Final Report
1978 - IRG/WP 2106
Since preparation of Document No: IRG/WP/258 results have been received from the remaining collaborators. Thus there is a little further to add to the conclusions already derived, those in Document No: IRG/WP/251 being as follows: 1) the exposure system used sometimes resulted in excessive weight gains in the sterile check blocks. Consequently the corrected loss in weight of the test blocks could ...
J G Savory, J K Carey


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


The effect of aqueous leaching on moisture uptake by CCA-treated blocks during soil burial
1987 - IRG/WP 2283
Mass loss, moisture content and nitrogen data from two soil burial experiments with untreated and CCA-treated Scots pine (Pinus sylvestris L.), Sitka spruce (Picea sitchensis Carr) and lime (Tilia vulgaris Hayne) are presented. These show that aqueous leaching of CCA-treated wood prior to burial significantly reduces its subsequent moisture uptake from soil. In the case of lime, a reduction in the...
C A Green, G M Smith, B King


A comparison of the leaching resistance of copper 2-ethanolamine and copper ethylenediamine treated Scots pine
2000 - IRG/WP 00-30233
The depletion of copper from copper 2-ethanolamine and copper ethylenediamine treated Scots pine blocks was investigated. A greater leaching resistance was found for copper 2-ethanolamine, which retained ca. 86% and ca. 50% copper after water and buffer leaching, respectively. Leached amine treated blocks also contained significant residual amine. This was consistent with other observations linked...
Xiao Jiang, J N R Ruddick


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


Effect of post-treatment processing on leachability of ACZA-treated douglas-fir lumber
1998 - IRG/WP 98-50109
The effect of post-treatment procedures that more rapidly precipitate copper, zinc, and arsenic in douglas-fir treated with ammoniacal copper zinc arsenate (ACZA) on subsequent leaching resistance were investigated at two retentions (6.4 and 40 kg/m3). Total leaching was greater from boards treated to the higher retention. At both levels, copper was lost at the highest rate. Post-treatment process...
J J Morrell, C S Love, S Kumar, C M Freitag


Biological and chemical investigations for the assessment of the environmental impact of wood preservative components
1999 - IRG/WP 99-50127
This study was carried out in order to investigate the suitability of biological and chemical techniques to evaluate the environmental impact of wood preservatives depleted from impregnated wood. Small specimens (15*25*50 mm3) of Scots pine sapwood (Pinus sylvestris) were treated with a CCB salt. After fixation the treated and untreated samples were washed-out according EN 84, and the different le...
E Melcher, H-W Wegen


Leaching of CCA from Bombax ceiba catamarans in operation for 15 years
2002 - IRG/WP 02-50191
Core samples of wood at random were collected from all the timber pieces of each of the three catamarans made of CCA treated logs of Bombax ceiba put to continuous service for the last 15 years at the Lawson's Bay fishing village, Visakhapatnam. The samples were dried to constant weight, powdered, digested and analyzed for the residual salts of the preservative. The residual content of ...
V Kuppusamy, M Balaji, M V Rao, K S Rao


Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper


A review of the efficacy and uses of deltamethrin for wood preservation
1996 - IRG/WP 96-30105
The synthetic pyrethroid deltamethrin, is one of the most active insecticides available for protecting and curing wood from attack by beetles and termites. Freshly felled trees can be protected against bark beetles by spraying to run off with a 0.025% Al solution (K-Otek EC25) with negligible leaching. Alternatively, sawn timber may be dipped in a 0.0125% Al solution for short to medium term prote...
A J Adams, J L Lindars


Inorganic preservative levels in soil under treated wood decks after 8 years natural exposure in Borås, Sweden
2005 - IRG/WP 05-50233
Inorganic preservative components (Cu, Cr and As) were measured to a depth of 150 mm under deck structures made with Scots pine lumber treated with several different wood preservatives and installed in Borås Sweden 8 years ago. Higher contaminant levels were observed mainly under the drip lines and in the top 50 mm of soil. Under CCA treated decks, soil arsenic concentrations increased from ba...
P A Cooper, Y T Ung, M-L Edlund, J Jermer


Modelling of copper emission fron treated wood leached according to NEN 7345 and ENV 1250.2
1996 - IRG/WP 96-20097
A series of water leaching experiments is carried out investigating pine and spruce treated and fixed using different copper-containing preservative solutions and process technologies. Water changes took place as prescribed in the Dutch standard NEN 7345 and the European test method ENV 1250.2, each of the leachates being chemically analysed for their copper content. Irrespective of the preservati...
G M F Van Eetvelde, S G L Michon, M Stevens


The influence of extractives on the natural durability of selected Ghanaian hardwoods
2004 - IRG/WP 04-10530
A study of the durability of Nauclea diderrichii, Nesogordonia papaverifera, Corynanthe pachyceras and Glyphaea brevis in laboratory and field tests showed the first three species performed well against a range of fungi and termites. Sapwood of C. pachyceras also performed well against these biodeteriogens. The role of extractives in conferring natural durability was assessed. Total extractive con...
C Antwi-Boasiako, A J Pitman, J Barnett


Evaluation of wood preservatives for Nordic wood preservation class AB
2002 - IRG/WP 02-30297
In the Nordic countries there are restrictions in the use of wood preservatives based on chromium and arsenic. For above ground use, class AB according to the Nordic system, only copper based preservatives are allowed in Sweden. Thus several new preservatives, copper based or metal free are now used. They have been approved by the Nordic Wood Preservation Council after passing laboratory tests ag...
M-L Edlund, J Jermer


Termite durability of sugi (Cryptomeria japonica) heartwood kiln-dried under high-temperature process in relation to wood extractives
2005 - IRG/WP 05-10547
Termite durability of sugi heartwood samples kiln-dried under a high-temperature process were evaluated by using Reticulitermes speratus (Kolbe) as a test termite sp. The n-hexane extractives of these samples were analysed by a GC technique. The less termite durability was shown on the wood samples dried under the high-temperature process, in comparison with that of the air-dried samples. No GC-p...
S Shibutani, E Obataya, K Hanata, S Doi


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