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Electrochemical deterioration of wood in sea-water
1981 - IRG/WP 464
In the specialistic literature only few items can be found dealing with the specific kind of wood deterioration called electrochemical corrosion of wood. This deterioration occurs predominantly on marine vessels, yachts, and other marine craft where wood is jointed by means of various metal connectors. Up to date information demonstrates that in wood surrounding copper connectors, when in proximit...
J Raczkowski


Copper based water-borne preservatives: Copper adsorption in relation to performance against soft rot
1987 - IRG/WP 3452
As part of a fundamental study concerned with the performance of copper based water-borne preservatives the adsorption of copper from aqueous solutions by 4 hardwood and 1 softwood species has been studied. Experiments were conducted to determine the influence of solution pH, solution concentration and solution temperature. The results obtained were consistent with an acid form ion-exchange mechan...
P M S Rennie, S M Gray, D J Dickinson


The effect of added nutrients on growth rate and decay capacity of Serpula lacrymans
1990 - IRG/WP 1427
At the previous meeting a new technique was presented that enables both fungal growth rate and wood decay rate to be measured using the same timber specimen. The technique (IRG/WP/1384) has previously been carried out with 1% malt as the sole nutrient within the small jar that provides the inoculum for this method. Results presented here relate to an additional level of 5% malt, with or without a ...
J D Thornton, A McConalogue


EPR observation of Mn(II) in decayed wood
2002 - IRG/WP 02-10443
Preliminary Electron Paramagnetic Resonance (EPR) studies of copper/chromium (CC) treated spruce wood, subjected to laboratory soil decay test showed increased intensities of Mn(II) EPR signal in partially decayed specimens. Several reasons might be responsible for this phenomenon: Mn(II) could originate from the wood after being released from the typical ligand binding, from reduction of other Mn...
M Petric, M Humar, P Kalan, F Pohleven, U Schoknecht, M Šentjurc


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


A quantitative weathering study of wood surfaces modified by chromium VI and iron III compounds
1989 - IRG/WP 2330
Thin veneers of Pinus radiata were treated with dilute aqueous solutions of chromium VI and iron III compounds and exposed to natural weathering for 35 days. Zero-span tensile strength and weight losses of treated veneers were compared with losses observed in untreated specimens In a study designed to demonstrate the applicability of strength and weight loss measurements to the rapid quantitative ...
P D Evans, K J Schmalzl


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


The movement of iron into field test stakes
1987 - IRG/WP 2284
Failed and sacrificial stakes recovered from the Westham Island field test site were examined for their iron content. Varying amounts were recorded, which were greatest in the failed stakes. The possible role of the iron taken up by the below ground portion of the stakes, in accelerating the decay process and/or the preservative leaching is under investigation. The reaction of the iron with the ch...
J N R Ruddick, P I Morris


The action of siderophores isolated from Gloeophyllum trabeum on the structure and crystallinity of cellulose compounds
1991 - IRG/WP 1479
Low molecular weight, high affinity iron-binding compounds (siderophores) were isolated from the brown-rot fungus Gloeophyllum trabeum. The compounds were shown to be inducible by iron starvation and could be purified by ultra-filtration, ethyl acetate extraction, column chromatography and preparative HPLC. The isolated compounds were shown by analytical and immunological techniques to be produced...
J Jellison, V Chandhoke, B Goodell, F Fekete, N Hayashi, M Ishihara, K Yamamoto


A model for attack at a distance from the hyphae based on studies with the brown rot Coniophora puteana
1995 - IRG/WP 95-10104
In timber infested by brown rot fungi, a rapid loss in strength is attributed to production of hydroxyl radicals (HO·) at a distance from the hyphae. The immediate precursor is Fenton's reagent (Fe(II)/H2O2), but the pathways leading to Fe(II) and H2O2 have remained unclear. Cellobiose dehydrogenase, purified from cultures of Coniophora puteana, will couple oxidation of cellodextrins to ...
S M Hyde, P M Wood


The biocidal efficacy of sulphates against basidiomycetes
1999 - IRG/WP 99-30192
Copper sulphate is used for the preservation of wood since decades. However, if copper sulphate is not combined with a compound it can be leached up to 50% and more from the treated wood. Previous results for leached wood indicated that the loss of biological efficacy against soft rot corresponds to leaching of copper. For basidiomycetes, however, the effectiveness decreases much more rapidly. The...
H Leithoff, E Melcher


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


A study of methanogenesis and sulphate-reduction: A possible source of explosive gas mixtures in a gold mine
1989 - IRG/WP 1399
Previous work isolated anaerobic bacteria from timbers and drainage water in a gold mine. The present work identifies the predominant methanogen in the mine ecosystem as Methanobacterium bryantii and sulphate-reducing isolates as Desulphovibrio desulphuricans and Desulphotomaculum antarcticum. Laboratory studies using model systems evaluate the activity of methanogenic and sulphate-reducing bacter...
L D Abraham, J F Putterill, A A W Baecker


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


The natural durability of wood in different use classes - PART II
2006 - IRG/WP 06-10598
The natural durability of important European wood species has been tested on 3970 speci¬mens in field trials. The wood was exposed at five test sites in Germany with different climates, at each site in European use class 4 and 3 (with and without soil contact). Within European use class 3 three different expositions were tested: vertical with sheltered end grain, vertical unsheltered and horizont...
A O Rapp, U Augusta, K Brandt


Effect of fire retardants (monoammonium phosphate and diammonium phosphate, mixture of monoammonium phosphate and borax and ammonium sulphate) on beech wood with dipping and Lowry methods
2006 - IRG/WP 06-40350
In this study, the possibilities of using four kinds of chemicals as fire retardants with 12% concentration for beechwood (Fagus orientalis Lipsky) was surveyed. Providing testing samples that are related to the measurement of fire resistance properties according to JIS A-1321-1975 standard were evaluated. Wood samples were impregnated with Lowry and dipping methods. In this study, samples impregn...
M Akhtari, D Parsapajouh, M Arefkhani


Effect of fire retardants (monoammonium phosphate and diammonium phosphate, mixture of monoammonium phosphate and borax and ammonium sulphate) on beech wood with dipping and Lowry methods
2006 - IRG/WP 06-40350
In this study, the possibilities of using four kinds of chemicals as fire retardants with 12% concentration for beechwood (Fagus orientalis Lipsky) was surveyed. Providing testing samples that are related to the measurement of fire resistance properties according to JIS A-1321-1975 standard were evaluated. Wood samples were impregnated with Lowry and dipping methods. In this study, samples impregn...
M Akhtari, D Parsapajouh, M Arefkhani


Gypsum effects on ‘dry rot’ wood degradation as a function of environment
2007 - IRG/WP 07-10624
‘Dry rot’ fungi are a unique group of brown rot fungi that can degrade wood away from ground contact where other fungi fail to colonize. Successfully occupying this niche is partially due to efficient water and nutrient transport, but mobilizing elements, notably calcium (Ca) and iron (Fe), from adjacent building materials has also been implicated in their success. Here we report a series of t...
J Schilling, J Jellison


Chelator-Mediated Fenton Chemistry in Wood Degraded by Fungi
2007 - IRG/WP 07-10618
Wood specimens were colonized by individual isolates of brown rot, white rot, soft rot and blue (sap) stain fungi. Ethyl acetate extracts of the ground wood were analyzed for their iron-reducing capabilities using a ferrozine-based assay. Extracts from wood colonized by brown rot fungi showed a significantly greater iron-reducing capability than extracts from wood colonized by white rot fungi or n...
B Goodell, G Daniel, J Jellison, Yuhui Qian


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Effects of chlorothalonil (CTN) and butylated hydroxytoluene (BHT) on microbial communities involved in the deterioration of wood using T-RFLP II: Results from field studies
2007 - IRG/WP 07-30429
The effects of Chlorothalonil (CTN) and Butylated Hydroxytoluene (BHT) on microbial species diversity in wood and the surrounding soil are being assessed by Terminal Restriction Fragment Length Polymorphism (T-RFLP). CTN was selected as a trial organic wood preservative, and the non-biocidal BHT was evaluated for its synergistic effects with CTN. ACQ-C was a positive control and untreated SYP sta...
G T Kirker, M L Prewitt, S V Diehl


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Mechanical strength of wood from the Vasa shipwreck
2008 - IRG/WP 08-20381
Samples from three ancient ship wrecks (Vasa, Elefanten, and Gröne Jägaren) and recent oak samples as reference were examined with regard to mechanical strength using the high-energy multiple impact (HEMI) - test method, which delivers the resistance to impact milling (RIM) of a material. Adoption and optimisation of the test method for the particular sample size of the wooden drilling cores was...
A O Rapp, C Brischke, C R Welzbacher, T Nilsson, C Björdal


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