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Wood Hydrophobic Modification by Mixed Wax Emulsions
2018 - IRG/WP 18-40839
An environmental-friendly, economical and facile method to construct hydrophobic system for improving wood repellency was applied in this study. Using paraffin wax and carnauba mixed wax O/W emulsions can simultaneously fabricate continuous wax films and rough structures in wood internal and external surface under appropriate heat treatment. In the study, single and mixed wax emulsions of 4% solid...
C Chen, W Wang


Improvement of short rotation teak wood properties through thermal modification
2018 - IRG/WP 18-40842
Teak (Tectona grandis L.f) is one of the most popular tropical timber species. Nowadays, the source of long rotation teak is limited in the availability. Many wood processing industries use short rotation teak, which has lower quality especially in durability and dimensional stability. Heat treatment is an eco-friendly method improving dimensional stability and durability of wood. The objectives o...
L A Pratiwi, I W Darmawan, B George, A Merlin, C Gérardin, S Dumarçay, T Priadi, P Gérardin


Developments within COST Action FP1303 related to the modification of wood
2018 - IRG/WP 18-40847
COST Action FP 1303 (Performance of bio-based building materials) was established in 2013 with the main aim to improve the knowledge on the performance of bio-based materials used as building products and the assessment of factors influencing these, with the aim of increasing their service life. This Action has helped in understanding the interlinked relationships between durability, product aesth...
D Jones


Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Dimensional stability and decay resistance of montmorillonite- furfuryl alcohol modified wood
2019 - IRG/WP 19-40856
Poplar (Populus cathayana) wood was impregnated successively by organo-montmorillonite (OMMT; in concentration of 2%) and furfuryl alcohol (FA, in concentrations of 15%, 30% and 50%) in a two-step method to prepare OMMT-FA modified wood. The modified wood samples were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Moreover, wood physical and a...
L Zhang, J Cao


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Mineralization of European oak with various ionic salt solutions to achieve an in situ precipitation of calcium oxalate
2019 - IRG/WP 19-40861
Thin specimens of European oak (Quercus spp.) with the dimensions of 4 × 20 × 50 mm3 were treated with various aqueous ionic salt solutions of calcium chloride, potassium oxalate and calcium acetate. Additionally, the oak was treated with combinations of calcium chloride and potassium oxalate, as well as calcium acetate and potassium oxalate with the aim to precipitate in situ the water insolubl...
T Franke, T S Volkmer


An overview of recent studies involving the thermal modification of hardwood species
2019 - IRG/WP 19-40869
This paper outlines recent activities related to the thermal modification of hardwood species, and particularly to tropical hardwood species. Timber demand is ever increasing, but this is being limited by the necessity to protect virgin forest stands. As such, the majority of supply of popular species is being met from juvenile short rotation stands. The limited age from these stands often plays a...
D Jones, M Gaff, F Kacik


Charring of Norway spruce wood surface – an alternative surface modification technique?
2019 - IRG/WP 19-40870
Charring is an old wood surface treatment technique, mainly performed on wooden façade elements with the aesthetical aims, but also with the purpose of protection. This flame treatment method can be grouped into heat treatment processes. Below the top charred layer of damaged wood there is a layer which is during flame treatment exposed to high temperatures in anoxic or semi-anoxic conditions. Th...
M Petric, M Pavlic, J Zigon


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


Towards better integration of wood protection in the forestry wood industry chain - a case study on hybrid poplar
2019 - IRG/WP 19-50359
Wood and wood products are limited in service life as in the forest ecosystem trees at end of their life are degraded to re-enter the bio-geochemical cycle. Humans can select wood species with a level of natural durability fit for an envisaged end use. Mainly those applications that require a long service life under conditions that are similar to those at soil level in a forest ecosystem have been...
J Van Acker


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Investigations into the use of Maleic Anhydride/Sodium Hypophosphite as a Wood Modification Process
2020 - IRG/WP 20-40891
The formation of crosslinked bonds between wood constituents is believed to be an effective way to stabilize wood against wet conditions. The possibility to use maleic anhydride (MA) combined with sodium hypophosphite (SHP) as crosslinking agents was studied, using Scots pine sapwood and a model compound. The modified wood showed weight gain and bulking effect after treatment and subsequent Soxhle...
I Kim, D Jones, O Karlsson, D Sandberg, O N Antzutkin, F Ullah Shah


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


A summary of decay performance with citric acid and sorbitol modification
2020 - IRG/WP 20-40898
Application of wood-based products as construction materials is one piece of the big puzzle to mitigate climate change. Wood is susceptible to biological deterioration. Environmentally motivated legislation is making the use of biocides less attractive from a commercial perspective. Ideally, a wood modification technology should be of low cost, water based and make use of thermal curing. This rese...
G Alfredsen, E Larnøy, G Beck, J Biørnstad, L R Gobakken, C A S Hill, A Treu


Macro biological degradation of wood treated with sorbitol and citric acid – first results from marine environment and termite exposure
2020 - IRG/WP 20-40901
Most European wood species are rapidly and severely degraded in termite-infested areas and the marine environment. There is a need for new solutions, especially in the marine environment, since we lack wood preservatives approved for marine applications in Europe. Several wood modification systems show high resistance against both marine borers and subterranean termites. However, the existing comm...
A Treu, L Nunes, E Larnøy


NewSiest-Enhancement of UV stability of thermally modified wood through envelope impregnation with nanobased stabilisers
2020 - IRG/WP 20-40909
Thermal modification is a process which improves the properties of wood, resulting in a material that can be disposed at the end of the product life cycle without presenting an environmental hazard. Thermally modified wood retains as a natural product and the grain, original colour variances and characteristics of wood are still present. However, exposure to daylight causes brightening or greying ...
K Srinivasa, M Petrič


Enhancing the durability of low durability Eucalyptus plantation species: a review of strategies
2020 - IRG/WP 20-40910
Eucalyptus species native to Australia have shown excellent growth rates, good physical properties and resistance to diseases. As a result, they are widely planted globally for a variety of uses. One negative aspect of many of these faster growing species is that they have a high percentage of low durability heartwood that resists preservative treatment. In Australia, large plantations of these sp...
K C Wood, J J Morrell, W Leggate


Plasma treatment of wood - a review of 15 years of research in Göttingen
2021 - IRG/WP 21-40913
Wood is an important renewable resource and can be found omnipresent in everyday life. Its natural properties offer numerous advantages regarding physical, mechanical but also aesthetic aspects, but also challenges that one has to address with various modification methods. Driven by the desire to promote the use of promising new technologies using plasmas, there has been a close research network ...
P Sauerbier, R Köhler, G Avramidis, W Viöl, H Militz


Influence of weathering on surface roughness of thermally modified wood
2021 - IRG/WP 21-40915
Thermally modified wood is exposed to weathering similarly as other wood-based building materials. It has been reported that if thermally modified wood is exposed to weathering, its moisture performance might decrease fairly fast. The aim of this study was to determine whether this phenomenon is associated with crack formations or roughness. Norway spruce, thermally modified spruce, wax-treated th...
E Kerzic, B Lesar, M Humar


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Effect of Heat Treatment on Physical and Mechanical Properties of Oriental Beech Wood (Fagus orientalis L.)
2021 - IRG/WP 21-40923
The present study aims to investigate the influence of heat treatment on physical and mechanical properties of Oriental beech wood (Fagus orientalis Lipsky.). Samples were exposed to temperature levels of 130˚C, 160˚C, and 190˚C for 3, 6, and 9 h. Selected physical and mechanical properties including compression strength parallel to grain, compression strength perpendicular to grain, bending st...
M D Ghalehno, D Chu, B N Sheshkal, M Humar, M Bahmani


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