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A field test on susceptibility of wood-based board materials to moulds
1989 - IRG/WP 3545
A field test on susceptibility of wood-based board materials to mould growth was carried out under practical, but severe, service-conditions. A total of 19 commercially available composite boards were investigated. It was found that all board materials tested were not completely immune to mould attack. Test results revealed that among the three main categories of wood-based boards involved, partic...
Qiao Wang, B Henningsson


Comparison of laboratory tests and field experiments for the estimation of emissions from treated wood
2005 - IRG/WP 05-50224-6
The authorisation procedure for biocidal products according to the European Biocides Direc¬tive in¬cludes the assessment of possible environmental risks by the emission of ac¬tive ingre¬dients. This needs an input of data on the expected emissions of biocides into environmental com¬part¬ments. The procedures for the estimation of these emissions should be harmonised. La¬boratory test proceÂ...
U Schoknecht


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Uptake of copper by mycelium of wood decay fungi growing on copper S-substituted thioglycolate containing nutrient media
1998 - IRG/WP 98-10291
Mycelia of Trametes versicolor, Coniophora puteana and Poria monticola were grown on potato dextrose agar (PDA) media, containing various concentrations of copper N,N-dimethyldithiocarbamoylacetate (which may be regarded as a copper S-substituted thioglycolate). The tested copper compound revealed relatively low fungicidal activity. After 13-18 day growing period, we determined concentrations of a...
M Humar, M Petric, F Pohleven, P Kalan


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers by the vermiculite-burial method. (+ correction document of 25 July 1990)
1990 - IRG/WP 2354
Heartwood of copper-chrome-arsenic (CCA) treated kempas (Koompassia malaccensis), tualang (Koompassia excelsa) and keruing (Dipterocarpus spec.) was found to be susceptible to soft rot in recent pole surveys. Standardized heartwood blocks were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay for twelve weeks by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicula grisea...
R-D Peek, A H H Wong


FTIR characterization of copper ethanolamine - wood interaction
1999 - IRG/WP 99-20154
The interaction of copper ethanolamine (Cu-EA) and wood components was studied by using Fourier transform infrared spectroscopy (FTIR). In Cu-EA treated wood, significant reduction was noticed on the band attributed to carbonyl vibration from carboxylic groups at 1735±5 cm-1 and an increase in band intensity was obtained from carbonyl in carboxylate at 1595±5 cm-1. The same observation was made ...
Jun Zhang, D P Kamdem


Changes of EPR spectra of wood, impregnated with copper based preservatives, during exposure to Antrodia vaillantii
2000 - IRG/WP 00-10355
Spruce wood (Picea abies) samples were impregnated with two different aqueous solutions: copper(II) octanoate with ethanolamine or copper(II) sulfate (cCu = 1,0 x 10-2 mol/l). Impregnated and unimpregnated test pieces were exposed to wood rotting fungus Antrodia vaillantii. Some strains of this fungus are known as copper tolerant. After four weeks of exposure to A. vaillantii, we could not detect ...
M Humar, M Petric, F Pohleven, M Å entjurc


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


Effect of remediation on the release of copper, chromium, and arsenic from particleboard made from CCA treated wood
2001 - IRG/WP 01-50170
This study sought to determine the effect of remediation with oxalic acid (OA) extraction and Bacillus licheniformis fermentation on the release of copper, chromium, and arsenic from particleboard made from remediated wood particles and also investigates durability of the particleboard against white and brown- rot fungi. Particleboard samples were manufactured using untreated, CCA-treated, OA-extr...
S N Kartal, C A Clausen


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


Less pollution due to technical approaches on accelerated steam fixation of chromated wood preservatives
1988 - IRG/WP 3487
Steaming of freshly treated wood at 100°C to 120°C initiates a spontaneous fixation of copper-chromate-containing wood preservatives. For the performance, a suitable anticorrosive equipment is necessary. Good results can be achieved using a separate steaming equipment which allows a rapid heating of the wood. While warming-up, in the wood some preservative solution extends and can be partly extr...
H Willeitner, R-D Peek


Limnoria quadripunctata Holthuis - a threat to copper-treated wood
1983 - IRG/WP 4100
This paper presents the first reported attack by the crustacean marine wood-borer Limnoria quadripunctata Holthuis of CCA treated eucalypt piles. The attack occurred after 12 years service of the piles in the River Derwent at Hobart, Tasmania. Attack by both this borer and Limnoria tripunctata Menzies is also reported in CCA treated softwoods and hardwoods over periods ranging from 5 to 22.9 years...
J E Barnacle, L J Cookson, C N McEvoy


Leaching of Copper from ACQ treated wood exposed above ground
2004 - IRG/WP 04-50219
The leaching of chemicals of ACQ Type C treated wood exposed above ground for 16 months was studied. Commercially treated Hem-fir boards (Tsuga heterophylla Raf. and Amabilis fir Forb) of 37.5 mm by 87.5 mm were used. The amounts of chemical leached monthly by the rainfall were determined and the leachate was collected and analyzed. Also, the environmental factors influencing the leaching were ...
P A Chung, J N R Ruddick


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


Effects of biocides on the extracellular mucilaginous material (ECMM) produced by two wood rotting basidiomycetes
2003 - IRG/WP 03-10469
Growth and production of extracellular mucilaginous material (ECMM) by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture, supplemented with the biocides CuSO4 and cyproconazole. The production of biomass in G. trabeum was significantly influenced by the concentration of CuSO4 in the medium. When CuSO4 was...
D Vesentini, D J Dickinson, R J Murphy


Leaching Characteristics of Alder Wood Treated with Copper Based Wood Preservatives
2005 - IRG/WP 05-50225
In this study, it was designed for determining leaching characteristics of CCA and alternatives wood preservatives. Alder wood blocks were treated with CCA (1 % and 2 %), ACQ-1900 (2 % and 3 %), ACQ-2200 (1 % and 2 %), Tanalith E 3491 (2 % and 2.8 %), Wolmanit CX-8 (% 1 and 2 %). Leaching studies were conducted according to AWPA E11-97. Copper analyses of leachate were determined Atomic absorption...
A Temiz, Ü C Yildiz, E D Gezer, S Yildiz, E Dizman


Leaching of components from CCF treated timber in ground contact
1998 - IRG/WP 98-50108
In order to investigate the depletion of different CCF-salts during service small stakes (10*10*450mm³) were treated with five water-borne wood preservatives and after fixation brought into ground contact for several years. After failing some of the broken down stakes were used to determine the remaining concentration of relevant ions and their distribution in different segments of the stakes. A...
E Melcher


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Changes of copper and chromium content after leaching in wood impregnated with the CCB and CB preservatives
2000 - IRG/WP 00-50147
The objective of the study was impregnated with CCB and CB preservatives pine wood of moisture content varying from 12% to 55% subjected to leaching. Losses of copper and chromium were determined for individual layers of wood up to 3 cm from the girth. The results were compared to the total amount of metals determined in water extracts. The degree of leaching of metal ions from wood of 55% moistur...
B Mazela


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Relating CCA fixation to leaching of CCA components from treated products
1995 - IRG/WP 95-50045
The relationship between chromium fixation in CCA-C treated wood, as determined by CrVI analysis of solution expressed from treated wood and the leaching of Cu, Cr, As and CrVI in a simulated rain test are evaluated for dimension lumber (2"x6") and pole sections. Leachate concentrations after 2 hour exposure to a misting spray (about 300 mm cumulative rainfall) decrease rapidly with increased degr...
P A Cooper, R MacVicar, Y T Ung


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