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Biosourced hybrid phenolic resins as coatings for the protection of wood and wood composites
2019 - IRG/WP 19-30745
Biosourced phenolic resins, based on the phenol-formaldheyde (PF) type, were prepared for their application as coating for wood and wood composites protection, especially against fire. The resins were synthesized by combining an organic polymeric matrix with another inorganic phase. The organic phase was prepared substituting phenol by natural phenolic compounds such as lignin and tannins. The ino...
P L de Hoyos-Martínez, R Herrera, J Labid, F Charrier El Bouhtoury


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


Influence of the substitution of phenol with lignin cleavage products in phenol-formaldehyde impregnation resins for wood modification on the fungal decay resistance and impregnation depth
2024 - IRG/WP 24-30805
The impregnation modification of wood with phenol-formaldehyde (PF) resins increases the woods dimensional stability and resistance against fungal decay. However, to decrease the usage of non-renewable resources, the substitution of phenol has been a topic of scientific interest. Lignin is a currently underutilized resource with a chemical structure that contains phenolic units. For adhesive appli...
J Karthäuser, L Tarentino, A Treu, H Militz, G Alfredsen


Chestnut tannin-furfurylic resins for wood preservation: influence of the proportion of tannins as a copolymer
2025 - IRG/WP 25-30816
Tannin, which is present in all plants, is the most abundant polyphenol globally and can be extracted using water or organic solvents such as acetone, ethanol and methanol. Tannins are classified into two categories: condensed tannins (catechin-based polymers) and hydrolysable tannins (sugar esters with galloyl units). Previous studies have demonstrated its potential as a raw material for modifyin...
J V Dorini-Falavinha, C Gerardin-Charbonnier, P Cademartori


Investigation of Impregnation Factors for Biomass-Based Phenol-Formaldehyde Resins
2025 - IRG/WP 25-41044
This study investigates the impregnation factors affecting the treatment of wood with biomass-based phenol-formaldehyde (PF) resins, such as impregnation methods, resin properties, and setting parameters like time and pressure. The goal is to ensure effective resin penetration into the wood cell wall structure, thereby enhancing wood durability and mechanical properties. Previous literature has la...
Y-C Huang, T-H Lin, P-Y Kuo


Towards Sustainable Wood Protection: PF resins-impregnated Paper Honeycombs and the role of Processing Parameters analysis by Response Surface Methodology
2025 - IRG/WP 25-41045
Honeycomb paperboard is an important wood-derived product and also an emerging new material to combine with wood panels. It is commonly applied as cushioning materials with excellent mechanical performance, and high demands in packaging market. The aims of this study were to enhance the durability of honeycomb paperboard using PF resins of various molecular weights (Mw 200, Mw 500, Mw 700), partic...
Y-C Wu, P-Y Kuo


Developing a Novel Bio-based PF Resin as Wood Preservative and Explore its Synthesis Route Using RSM Methodology
2025 - IRG/WP 25-41046
Phenol-formaldehyde (PF) resin treatment has long been recognized as one of the most effective and widely used wood preservation methods, offering exceptional durability, dimensional stability, and resistance against biological degradation. However, traditional PF synthesis relies heavily on petroleum-derived phenol, raising concerns about environmental impact and resource sustainability. To date,...
H-C Ye, Y-C Wu, T-H Lin, P-Y Kuo


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