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Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Natural durability transfer from sawmill residues of white cypress (Callitris glaucophylla). - Part 4: Analysis of extracts and treated wood for active components
2000 - IRG/WP 00-20215
In order to facilitate the commercial implementation of a large project aimed at recovering 'waste' durability components from sawmill residues of Callitris glaucophylla, it has been essential to develop analytical methodology for the important bioactive components of the heartwood extract. This methodology will be used 1) to standardise the activity of successive production batc...
Hui Jiang, M J Kennedy, L M Stephens


Fungal colonisation of the keelson and associated structures of a nineteenth century wooden frigate: Concepts of community structure and development
1994 - IRG/WP 94-10072
The early stages of microbial colonization and succession of wooden surfaces exposed to the sea have been extensively studied as have the community structures of archaeological timbers subjected to submergence and then retrieval from the sea. The frigate UNICORN, a largely intact 19th century wooden ship based in Dundee, Scotland, provides the microbial ecologist with a unique opportunity to study...
N A White, J W Palfreyman, G M Smith


A preliminary comparison of GC, HPLC and ELISA analysis of resin acids in pulp mill effluents
1997 - IRG/WP 97-20120
Resin acids are naturally occurring diterpenoid carboxylic acids present in most Canadian softwoods. There are eight common resin acids that are classified into two groups; the abietanes and the pimaranes. During processing of wood products they can be released into the environment where they are of concern because of their acute toxicity toward fish and other aquatic life. Traditionally resin aci...
A N Serreqi, K Stark, Xiumei Feng, J N Saddler, C Breuil


Detection of wood decay fungi in wood using a PCR-based analysis
1998 - IRG/WP 98-10279
We have developed a DNA-based assay to reliably detect brown rot and white rot fungi in wood at different stages of decay. DNA, isolated by a series of CTAB and organic extractions, was amplified by the polymerase chain reaction using published universal primers and basidiomycete-specific primers derived from ribosomal DNA sequences. We have surveyed 7 species of brown rot fungi, 7 species of whit...
C Jasalavich, A Ostrofsky, J Jellison


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


Surface retentions of PCP, TCMTB and MTC obtained during a field trial of antisapstain formulations
1993 - IRG/WP 93-20002
Formulations containing NaPCP or TCMTB and MTC were included as reference products in a recent field trial of antisapstain formulations in Queensland. Retentions of these actives on the surface of treated sawn Pinus elliottii were monitored by ultrasonic solvent extraction of excised samples and analytical determination by high performance liquid chromatography. Distribution of actives with depth ...
D E Ferlazzo, M D Needham, M J Kennedy


Determination of boron levels in solution and in treated wood
1994 - IRG/WP 94-20041
Four methods of measuring boron levels in solutions were investigated. The methods compared included the azomethine-H method which is commonly used in soils and plant tissues, the methods outlined in the Australian Standard AS 1605 (1974) and in Wilson (1958), and the atomic absorption spectrophotometry method. Defect-free radiata pine (Pinus radiata D. Don) sapwood and wood flakes were treated to...
F J Romero, P Vinden, P Kho


The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform...
E Melcher, H-W Wegen


Susceptibility of antisapstain fungicides to rain wash-off
1994 - IRG/WP 94-30046
Results of trials using miniature timber packets and simulated rain wash-off are described. Six fungicidal actives in five commercial antisapstain formulations were involved, and a clear influence of rainfall timing after antisapstain treatment was demonstrated. Differences between actives and formulations were most marked where water-spray was applied in the first hour after treatment, though eve...
R N Wakeling, D J Cross, D R Eden, P N Maynard


Sampling and analysis of NeXgen-treated timber
1998 - IRG/WP 98-20134
Green sawn timber surfaces of the softwood Caribbean pine and the hardwood white cheesewood were treated by dipping, spraying, and precise spiking with the antisapstain product NeXgen. After storing for either two hours or two weeks, the treated surfaces were sampled by one of four alternative protocols, which included two involving a square wad sampling punch (one hit or six hits), one involving ...
M J Kennedy, D E Ferlazzo, T L Woods, M H Freeman


The identification of organic compounds in wood using thermal desorption GC-MS - possibilities and limitations
2001 - IRG/WP 01-20224
There is a clear need for the analytical characterisation and identification of organic compounds and their derivatives in different phases especially in timber. In this context the paper describes a rapid and powerful gas chromatographic method for the determination of insecticides, biocides and "other" organic substances in treated and/or modified wood. The main advantage of this procedure is th...
P Jüngel, E Melcher


Micromorphology of decay in Keruing heartwood by the basidiomycetes Phellinus contiguus and Dacrymyces stillatus
2002 - IRG/WP 02-10454
This study aimed to characterise the micromorphology of fungal decay in a wooden handrailing in an above ground exposure at the Thames embankment in London. Keruing heartwood (Dipterocarpus spp.) was determined as the construction timber and the two basidiomycetes Phellinus contiguus and Dacrymyces stillatus identified as main decay organisms. Their decay patterns within Keruing heartwood were...
G Kleist, M Ray, R J Murphy


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Microscopic analysis of southern pine utility pole core segments
1992 - IRG/WP 92-1542
Fifteen macroscopic core descriptive categories were evaluated by microscopic analysis for accuracy in detecting decay and judging decay severity. Five categories were good indicators of decay as decay was detected in 28 of 48 samples. Five categories were possible indicators of early decay as decay was detected in 6 of 40 core segments and an additional 18 contained hyphae. The remaining five cat...
S E Anagnost, C J K Wang, M Wright


Improved preservative penetration of spruce after pre-treatment with selected fungi. II. Creosote treatment, analysis and strength testing
1998 - IRG/WP 98-40106
This paper describes the creosote treatment and analysis of logs pre-treated with selected fungal agents as a method of increasing the porosity of the wood prior to preservative treatment. The paper also reports the subsequent strength testing of the timber to evaluate the effects of the fungal pre-treatment on the structural integrity of the wood. European spruce logs were pre-treated with eithe...
E J Tucker, A Bruce, H J Staines, B Rosner, K Messner


Controlled envelope treatments of Pinus sapwood, achieved by modifications to impregnation process and carrier solvents
2003 - IRG/WP 03-40258
Specimens of slash pine or radiata pine were treated to a target retention of 0.02% m/m permethrin with conventional light organic solvent fluids or with oil-modified fluids (Tanalith® T). Best achievable envelopes from LOSP fluids were poorly controlled, penetrating not only the target outer 0-5 mm zone (mean 0.019%, RSD 28%), but also breaking through into the 5-10 mm zone (mean 0.013%, RSD 37%...
M J Kennedy, P R S Cobham


Properties of cellulose degraded by the brown rot fungus, Postia placenta
1988 - IRG/WP 1350
To gain further understanding of the nature of the cellulose depolymerizing agent or agents of brown-rot fungi, brown-rotted cellulose was chemically and physically characterized. Various culture conditions, such as low nitrogen and elevated oxygen levels, did not induce degradation of cellulose by Postia placenta in liquid cultures. Therefore, brown-rotted cellulose for analysis was prepared by a...
T L Highley, R E Ibach, T K Kirk


The suitability of isothiazolone microemulsions as long term wood preservatives
1997 - IRG/WP 97-30150
Microemulsion formulations of 4,5 dichloro-2-n-octyl-4-isothiazolin-3-one were investigated to determine the leaching potential of these formulation types as well as their efficacy against decay fungi. These patented low leaching formulations exhibited good anti fungal efficacy in standard tests combined with minimal leaching of the active ingredient from the wood. The data suggests that the excel...
B M Hegarty, Bing Yu, L E Leightley


Cyclic delamination analysis of preservative-treated wood/FRP interfaces
2002 - IRG/WP 02-40244
Wood preservative chemicals can interfere with adhesive properties when bonding wood laminates or wood/FRP (Fiber Reinforced Polymer) laminate composites. In this work we studied the effects of various wood preservative treatments, and pre- and post-treatment on wood/wood and wood/FRP bond durability using a severe cyclic delamination test (ASTM D-2559). Pre-treatment of individual laminates with ...
C Tascioglu, B Goodell, R Lopez-Anido


Remediation of a site contaminated with creosote and CCA - a case study
1998 - IRG/WP 98-50101-12
Over sixty years of wood preservation activity conducted by ImpregNor at Ilseng, Norway, has caused serious contamination of the soil. High concentrations of creosote have been found at two separate sites, one in connection to the creosote wood preservation plant, and one further downstream were residues from the creosote preservation have been deposited. High levels of chromium, copper and arseni...
T Rødsand, K Hellum, H Lillemaehlum


Bibliographie sur les produits organiques en solvant pour la préservation du bois
1972 - IRG/WP 313
Le présent travail exécuté dans le cadre do la Section III du Groupe International de la Préservation du bois a pour but de rassembler, en vue d'éventuelles études plus approfondies sur le sujet ou sur l'un de ses aspects, les principales et relativement récentes références sur les produits de protection des bois en solvant, souvent appelés, et parfois improprement, pro...
H Alliot


Silafluofen: Novel chemistry and versatility for termite control
1995 - IRG/WP 95-30069
A novel silicon - containing insectizide, HOE 084498 ('Silafluofen'), with a favourable toxicological profile, has shown activity against a broad spectrum of agricultural and environmental health pests. Results from laboratory and field studies around the world have demonstrated that silafluofen is effective at protecting timber from attack by various species of termite and wood-...
A J Adams, A Jermannaud, M-M Serment


Detection of dry rot by air analysis
1992 - IRG/WP 92-2399
Detection of dry rot (Serpula lacrymans) at an early stage appears to be very difficult in practice. Also control inspections in buildings, after remedial treatment of dry rot, have a limited accuracy. The use of trained dogs in Denmark initiated the idea for this research on the possible use of air analysis as a detection method. The Centre for Timber Research-TNO (TNO-CHT) and the Institute for ...
P Esser, A C Tas


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