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Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Investigations into the use of Maleic Anhydride/Sodium Hypophosphite as a Wood Modification Process
2020 - IRG/WP 20-40891
The formation of crosslinked bonds between wood constituents is believed to be an effective way to stabilize wood against wet conditions. The possibility to use maleic anhydride (MA) combined with sodium hypophosphite (SHP) as crosslinking agents was studied, using Scots pine sapwood and a model compound. The modified wood showed weight gain and bulking effect after treatment and subsequent Soxhle...
I Kim, D Jones, O Karlsson, D Sandberg, O N Antzutkin, F Ullah Shah


Elucidation of reactive sites of wood modified with acetic anhydride: Insights from density functional theory calculations
2020 - IRG/WP 20-40892
Density functional theory (DFT) was employed to investigate the interaction of cellulose and lignin with acetic anhydride for explaining the wood modification process. Atoms in molecules (AIM) and reduced density gradient (RDG) along with non-covalent interaction (NCI) plots were used to analyse the intermolecular bonding characteristics. Cellulose was modelled with a cellobiose unit (dimer of glu...
V Ponnuchamy, A Sandak, J Sandak, R Herrera Diaz


Future development of durability assessment of wood, according to typical usage of preservative-treated wood and naturally durable wood in Japan
2020 - IRG/WP 20-20675
A market of preserved wood products in Japan has two unique histories. First is the market shift to residential ground sills from utility poles and sleepers; the other is the stop of CCA treatment caused by the new effluent standard. In 2018, around 85% of preserved wood products used for residential ground sills were treated with non-CCA such as Cu-based agents. Since the market of treated wood h...
T Osawa, W Ohmura, H Kurisaki


A summary of decay performance with citric acid and sorbitol modification
2020 - IRG/WP 20-40898
Application of wood-based products as construction materials is one piece of the big puzzle to mitigate climate change. Wood is susceptible to biological deterioration. Environmentally motivated legislation is making the use of biocides less attractive from a commercial perspective. Ideally, a wood modification technology should be of low cost, water based and make use of thermal curing. This rese...
G Alfredsen, E Larnøy, G Beck, J Biørnstad, L R Gobakken, C A S Hill, A Treu


Macro biological degradation of wood treated with sorbitol and citric acid – first results from marine environment and termite exposure
2020 - IRG/WP 20-40901
Most European wood species are rapidly and severely degraded in termite-infested areas and the marine environment. There is a need for new solutions, especially in the marine environment, since we lack wood preservatives approved for marine applications in Europe. Several wood modification systems show high resistance against both marine borers and subterranean termites. However, the existing comm...
A Treu, L Nunes, E Larnøy


NewSiest-Enhancement of UV stability of thermally modified wood through envelope impregnation with nanobased stabilisers
2020 - IRG/WP 20-40909
Thermal modification is a process which improves the properties of wood, resulting in a material that can be disposed at the end of the product life cycle without presenting an environmental hazard. Thermally modified wood retains as a natural product and the grain, original colour variances and characteristics of wood are still present. However, exposure to daylight causes brightening or greying ...
K Srinivasa, M Petrič


Enhancing the durability of low durability Eucalyptus plantation species: a review of strategies
2020 - IRG/WP 20-40910
Eucalyptus species native to Australia have shown excellent growth rates, good physical properties and resistance to diseases. As a result, they are widely planted globally for a variety of uses. One negative aspect of many of these faster growing species is that they have a high percentage of low durability heartwood that resists preservative treatment. In Australia, large plantations of these sp...
K C Wood, J J Morrell, W Leggate


Plasma treatment of wood - a review of 15 years of research in Göttingen
2021 - IRG/WP 21-40913
Wood is an important renewable resource and can be found omnipresent in everyday life. Its natural properties offer numerous advantages regarding physical, mechanical but also aesthetic aspects, but also challenges that one has to address with various modification methods. Driven by the desire to promote the use of promising new technologies using plasmas, there has been a close research network ...
P Sauerbier, R Köhler, G Avramidis, W Viöl, H Militz


Influence of weathering on surface roughness of thermally modified wood
2021 - IRG/WP 21-40915
Thermally modified wood is exposed to weathering similarly as other wood-based building materials. It has been reported that if thermally modified wood is exposed to weathering, its moisture performance might decrease fairly fast. The aim of this study was to determine whether this phenomenon is associated with crack formations or roughness. Norway spruce, thermally modified spruce, wax-treated th...
E Kerzic, B Lesar, M Humar


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Effect of Heat Treatment on Physical and Mechanical Properties of Oriental Beech Wood (Fagus orientalis L.)
2021 - IRG/WP 21-40923
The present study aims to investigate the influence of heat treatment on physical and mechanical properties of Oriental beech wood (Fagus orientalis Lipsky.). Samples were exposed to temperature levels of 130˚C, 160˚C, and 190˚C for 3, 6, and 9 h. Selected physical and mechanical properties including compression strength parallel to grain, compression strength perpendicular to grain, bending st...
M D Ghalehno, D Chu, B N Sheshkal, M Humar, M Bahmani


Assessing the Performance of Wood-based Materials Exposed to Termite Risk – A New Experimental Approach
2022 - IRG/WP 22-10989
Termites are able to degrade a large number of building materials including wood, wood-based panels, biobased insulation, and polymers. The risk for a material of being degraded by termites depends on its composition, on its accessibility, and also on the behavior and the biology of the termite species considered. Within the EU project Click Design, we investigated the durability, under laboratory...
M Kutnik, I Paulmier, C Brunet, D Ansard, M Montibus


Wood modification reduces the feeding rate of the wood boring crustacean, Limnoria quadripunctata
2022 - IRG/WP 22-10993
Adult Adult Limnoria search for new wood once their current piece disintegrates from tunnelling. During this time, they do not have access to wood so experience a period of starvation and must feed again once settled. Wood modification offers protection to marine structures by reducing the feeding rate of Limnoria and therefore can reduce recruitment of adults from distant pieces of wood. Chemical...
L S Martin, S Lande, M Westin, S M Cragg


Results of the resistance of acetylated wood against marine borers at three Italian sites after five years of sea immersion
2022 - IRG/WP 22-10994
The aim of this research was the determination of resistance of acetylated wood against marine decay in use class 5 (EN 335) in temperate sea waters. The resistance of acetylated Pinus radiata (radiate pine) in solid and medium density fibreboard (MDF) panels is compared with that of the untreated Scots pine, radiata pine and other untreated wood of European species such as Fagus sylvatica (Europe...
S Palanti, F Stefani, M Andrenacci, M Faimali, I Guarneri, M Sigovini, D Tagliapietra


Analysis of wooden shingles after seven years of exposure
2022 - IRG/WP 22-20690
Wood is a traditional roofing material in the Alpine regions. In the 17th century, wooden roofing was typically used on more important buildings. Still, today it is predominately used on huts and houses in the hilly regions of northern and north-western Slovenia. Because wooden roofing is expensive, we investigated the possibility of extending the service life of the roofing through impregnation a...
M Humar, B Lesar, D Kržišnik, E Keržič, B Jemec


Green approach in wood mineralization for improvement of fire properties
2022 - IRG/WP 22-30769
Various treatments have been developed in order to improve fire properties of wood. Because the use of some flame retardants can release toxic compounds in the event of a fire, leading to poisoning or even death of people from smoke inhalation, the use of no-toxic and more ecologically acceptable flame retardants is preferable. Mineralization of wood with the incorporation of carbonates has proven...
A Pondelak, R Repič, L Škrlep, N Knez, F Knez, A S Škapin


A novel wood preservation technology improving durability and water-related properties
2022 - IRG/WP 22-40926
A newly developed silicone oil (Archroma Management GmbH, Switzerland) was tested for wood modification purposes. Scots pine sapwood was treated with aqueous solutions of this silicone oil and showed a penetration of the modification agent into the wood cell wall. Both, biological durability and moisture-related properties, experienced significant improvements by the modification. Besides, the mod...
L Emmerich, H Militz, M Vila


Durability against fungal decay of sorbitol and citric acid (SorCA) modified wood
2022 - IRG/WP 22-40928
Most European-grown wood species are susceptible to biological degradation, specifically, they suffer from a poor resistance against wood-destroying fungi. Therefore, prior to outdoor exposure, wood has to be treated either by applying a protective coating on its surface or by full-volume impregnation with antifungal chemicals. However, due to environmental and health concerns, the most frequently...
K Kurkowiak, L Emmerich, H Militz


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Molecular dynamics investigation of wood modification with furfuryl alcohol
2022 - IRG/WP 22-40931
Molecular dynamics (MD) was applied to investigate and understand the structural characteristics and the interaction of cellulose and lignin with furfuryl alcohol for explaining the wood modification process. A single chain of cellulose polymer model and a softwood lignin model was considered to represent cellulose and lignin polymers. The obtained radial distribution function results revealed tha...
V Ponnuchamy, J Sandak, A Sandak


Chemical modification of cellulose nanofibrils for tailoring properties of composites
2022 - IRG/WP 22-40934
Due to its natural abundance, complete biodegradability and excellent properties, cellulose is one of the most promising materials for the production of bio composites, as well as one of the most promising fillers for biodegradable polymer composites. This is also true for nanocellulose. A large number of hydroxyl groups on the surface of fibers or fibrils enables a whole series of chemical reacti...
I Poljanšek, J Levanič, V Ž Bogataj, V Vek, P Oven


The influence of thermal modification and surface charring to different levels on wettability of Norway spruce wood
2022 - IRG/WP 22-40942
The wood can alternatively be protected from water absorption by thermal modification and charring. Both techniques cause certain chemical and physical changes in the wood, the extent of which depends on the level of temperature applied. The objective of this study was to determine how the combination of charring to different levels and thermal modification affects the chemical, morphological, and...
J Žigon, C Gerardin, M E P Wålinder, P Gerardin


Mechanical Properties of Thermally Modified Wood after twelve Months of Field Exposure
2022 - IRG/WP 22-40945
This study aimed to evaluate the durability and mechanical properties of two different woood species, namely beech (Fagus sp.) and silver fir (Abies alba), from Bosnia and Herzegovina thermally modified at three different temperatures and duration at maximum temperature. Samples of the mentioned wood species wood (Abies alba) were prepared according to EN 408+A1 standard. The maximum 4-point bendi...
R Hasanagić, M Bahmani, L Fathi, M Humar


Effect of densification of Eucalyptus nitens and E. obliqua on moisture uptake, swelling, decay resistance, and fire performance
2022 - IRG/WP 22-40946
Some Australian Eucalyptus species that are abundantly available have low natural durability and poor resistance to fire. These same species are also extremely difficult to treat with preservatives or fire retardants using conventional pressure treatment methods due to a large proportion of refractory heartwood. The aim of this research was to understand whether thermo-mechanical densification had...
B Hassan, J J Morrell, F Wiesner, W Wu, B Belleville, K C Wood


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