Your search resulted in 1122 documents. Displaying 25 entries per page.
Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston
Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick
Field Stake Performance of Parallel Strand Lumber Treated with Waterborne Copper Naphthenate
2008 - IRG/WP 08-40435
Wood and wood products have been considered a premium building material for residential and industrial structures for many centuries. More recently, structural composite lumber (SCL) products have played an increasing role in satisfying the needs of the building industry. However, both wood and wood composites are naturally biodegradable materials which require enhanced durability when used in ce...
G P Merrick, M H Freeman, J A Brient
Corrosion of fastener and connector in contact with alkaline copper treated wood – it is a problem
2008 - IRG/WP 08-40437
For many decades, chromated copper arsenate (CCA) was the most common wood preservative used in North America for residential and industrial applications. Since December 31, 2003, the use of CCA for residential application was voluntarily terminated. One of the most widely accepted alternative wood preservatives in Western Canada is Alkaline Copper Quaternary Compound (ACQ). This paper will compar...
J N R Ruddick
Wood preservative obtained by recycling – preliminary selection of leaching inhibitor
2008 - IRG/WP 08-50252
Based on recycling of used household batteries, a process was developed to enable the recovery of major manufacturing components, leading to a solution of zinc (32 g.l-1) and manganese (15 g.l-1) salts, free of heavy metals. The potential use of the above solution as wood preservative was demonstrated by means of assays both of fungicidal activity -using white and brown rot fungi- and of insectici...
C Ibáñez, C Mantero, G Cecchetto, M Rabinovich, M Cerdeiras
Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali
Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi
Antifungal Activities of Three Supercritical Fluid Extracted Cedar Oils
2009 - IRG/WP 09-30501
The antifungal activities of three supercritical CO2 (SCC) extracted cedar oils, Port-Orford-cedar (POC) (Chamaecyparis lawsoniana), Alaska yellow cedar (AYC) (Chamaecyparis nootkatensis), and Eastern red cedar (ERC) (Juniperus virginiana L), were evaluated against two common wood decay fungi, brown-rot fungi (Gloeophyllum trabeum) and white-rot fungi (Trametes versicolor). The statistical analysi...
Tianchuan Du, T F Shupe, Chung Y Hse
Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond
Effects of new fixative additives on leachability of boron wood preservatives
2009 - IRG/WP 09-30507
Borates are well known with their protective capacity against both fungi and insects with low mammalian toxicity and environmental acceptable. However, boron itself does not ensure the appropriate protection for wood in the exterior applications because of their easily depletion from the treated wood under wet conditions. In this study, the potential use of monoglyceride and polyvinyl alcohol prod...
A Mohareb, J Henry, E Wozniak, P Gérardin
Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang
The Form of Copper: Does It Really Matter?
2009 - IRG/WP 09-30513
In recent years, several micronized copper formulations for lumber treatment have supplanted the solubilized copper formulations that in turn replaced CCA after its voluntary relabeling in 2004. The micronized or dispersed copper systems use finely ground but solid copper particles and deposit those particles within the wood framework. In contrast, copper in the soluble formulations is relativel...
C R McIntyre, M H Freeman, T F Shupe, Q Wu, D P Kamdem
Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro
Enhanced uptake of wood modification agents in “bioincised” wood
2009 - IRG/WP 09-40445
The permeability of refractory wood species e.g. Picea abies and Abies alba is reduced resulting in a radial penetration of chemical solutions of only a few millimetres. Exploitation of these wood species is therefore not possible for many applications. A novel biotechnological method (European patent 05027812.6) based on the pre-treatment of wood with the white-rot fungus Physisporinus vitreus si...
F W M R Schwarze, M Schubert
Environmental Emission of Wood Preservatives: Interpretation of Data Relevant to BPD Risk Assessments
2009 - IRG/WP 09-50259
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. The leaching rates can be derived from laboratory testing and from field testing. The relationship between laboratory and f...
D G Cantrell
Leaching of the copper component from full scale decking boards during one summer season
2009 - IRG/WP 09-50260
The leaching of copper has been tested in laboratory and in outside exposure for freshly treated pine sapwood samples with three different copper preservatives, Cu HDO, copper quat and copper triazoles. We found in the laboratory leaching test that a fixation with warming to 60 °C (140 °F) for 48 hours without drying and then drying in the laboratory in room temperature gave the lowest leaching of copper. We also found that surface treatments with wood oils reduced the leaching, and that washing of the surface before testing had no effect.
Full scale decking board samples (0.25 m2) were then exposed outdoors for rain. The rain water was collected and analysed for copper. After one summer season (about 600 mm rain) we found that the leaching differ for the three preservatives. All samples with a water borne surface treatment had the lowest leaching, about half the amount of untreated.
F G Evans
Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung
Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe
Sensitivity to Copper of Basidiospores from Copper Tolerant Fungi: Fomitopsis palustris and Oligoporus placentus
2010 - IRG/WP 10-10707
Copper continues to be an important fungicide in wood preservation. It is the primary component of the preservatives that have replaced chromated copper arsenate for treated wood in residential construction in North America. However, a co-biocide is normally needed to protect against copper tolerant organisms. Previous work has shown that the spores of at least one copper tolerant fungus, Oligopo...
C S Woo, P I Morris
A genomic sequencing approach to study wood decay and copper tolerance in the brown rot fungus, Antrodia radiculosa
2010 - IRG/WP 10-10720
We used Illumina paired-end short read sequencing (76 nt, 300 bp insert size) to produce a de novo assembly of the genome of Antrodia radiculosa, a copper-tolerant brown rot fungus that is capable of aggressive wood decay. Quality analysis of the base calls in the dataset (8.95 Gb) showed that the majority of the nucleotide sequence was of the highest quality with 5% in the lowest quality group. ...
J D Tang, T Sonstegard, S Burgess, S V Diehl
Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan
The Relative Performance of an Organic Preservative System under UC3A and UC3B Conditions using Two Test Methods
2010 - IRG/WP 10-20429
Coated L-joints have been used for decades to evaluate the performance of wood preservatives in protected environments. This study was conducted using matched coated and uncoated L-joints to simulate above ground protected and unprotect exposures. When exposed to constant moisture in a greenhouse environment, coated and uncoated L-joints give very similar performance results. In contrast, exposi...
C F Schauwecker, A Zahora, A F Preston
Determination of a fixation time of wood preservatives: A discussion paper
2010 - IRG/WP 10-20436
The intention of that paper is to initiate a discussion on the basis of a French method in combination with a German approach regarding the need of a method for the determination of a fixation time and especially to obtain input as well as ideas concerning a possible test design. Since no harmonised European approach exists up to now concerning the determination of a fixation time, CEN TC 38 (2009...
E Raphalen, E Melcher
Toward an assessment of copper bioavailability in treated wood
2010 - IRG/WP 10-20445
Many modern wood preservative systems rely on copper (Cu). Some oxalate-producing fungi detoxify Cu by immobilizing it in crystals, and this may decrease its physiological availability (bioavailability). Cu bioavailability may also decrease during wood treatment. Cu retention in wood, however, is typically measured as a weight-to-volume concentration without an estimate of its bioavailability and ...
J S Schilling, J J Inda
Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma