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Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton


A non-VOC approach of solvent-based wood preservatives for remedial treatment
2016 - IRG/WP 16-30681
Solvent-based wood preservatives are the workhorses in the field of remedial treatment. Due to new European regulations on the indoor air quality there is an increasing pressure on the VOC-content on these solvent-based product types. The transfer of these European regulations into national law is left up to each European member state and handled in different ways. E.g. France has introduced a VO...
M Pallaske, S Hellkamp, P Jüngel


Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick


Activity of wood preservatives against mould fungi
2016 - IRG/WP 16-30695
The resistance of experimental and commercial wood preservatives to mould fungi was determined using a method recommended by the Building Research Institute Instruction. The research of the inhibiting actions of the growth of fungi was carried out on the Scots pine wood Pinus sylvestris L. and beech Fagus sylvatica L. The most active compounds against mould were experimental herbicidal ionic li...
J Zabielska-Matejuk, A Stangierska


Influence of pressure phase impregnation time on the uptake and distribution of wood preservatives in Scots pine material of diverse treatability
2016 - IRG/WP 16-40752
In spite of the general opinion that Scots pine sapwood is easy to impregnate considerable variations in treatability are reported. In order to study impregnation results of diverse Scots pine sapwood treated with increasing process times, Scots pine sapwood from two different predefined treatability groups was impregnated. A copper solution was used as impregnation agent in ten different vacuum p...
K Zimmer, B Kerfriden


10 year Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2017 - IRG/WP 17-30718
A round robin involving 15 European participants was set up in 2006. The round robin consisted of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. The laboratory test results were reported in an earlier IRG paper (IRG/WP13-20535) but are included also in this paper in order to facilitate the comparison with the field test...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, E Melcher, R Moeller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Prevention of fungal damage of oil and date palm wood by organic acids
2017 - IRG/WP 17-10877
Felled palm trunks are susceptible to fungi as long as their moisture content is above fibre saturation. During this period, palm wood has to be protected against mould and rot fungi. Environmental-friendly organic acids are suitable. Small samples of oil palm (Elaeis guineensis) and date palm (Phoenix dactylifera) wood were treated with 1 to 10% solutions of acetic acid and propionic acid, respec...
M Bahmani, O Schmidt


Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen


Guidance on the European Biocidal Products Regulation Concerning Efficacy of Wood Preservatives
2017 - IRG/WP 17-20627
In Europe wood preservatives belong to Product Type 8 (PT8) of the Biocidal Products Regulation (BPR, EU n. 528/2012), which regulates the authorisation of biocidal active substances and products in the European market. The applicant, who aims to obtain authorization to place a product onto the European market, needs to submit data to substantiate the label claims for the intended uses. Label cla...
I Stephan, M Kutnik, E Conti, M Klamer, L Nunes, J Van Acker, R Plarre


Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl


Efficacy of Erythropleum suaveolens (potrodom) and Distemonanthus benthamianus (bonsamdua) water extractives on the durability of five Ghanaian less used timber species of varying perviousness and retentiveness
2017 - IRG/WP 17-30705
Conventional wood preservatives are not only toxic to target bio-deterioration organisms but also to humans, other organisms and the environment. In an effort to find preservatives that are less toxic or non-toxic to man, other organisms and the environment, efficacy of branch bark and heartwood water extracts (0.65 g/ml) of Erythropleum suaveolens (potrodom) and Distemonanthus benthamianus (bonsa...
A Asamoah, K Frimpong-Mensah, C Antwi-Boasiako


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


The Protective Effect of Different Tree Bark Extractives against Decay Fungi
2017 - IRG/WP 17-30707
There are various modification methods which increase the resistance of wooden materials. Due to recent environmental regulations, there is a need for new and environmentally-friendly wood preservatives. In this study, six different tree bark extractives were evaluated for their wood resistance against fungal degradation. For this purpose, the white rot fungi (Tramates versicolour) and brown rot f...
Ö Özgenç, S Durmaz


Anti-fungal activity of rutin and rutin-metal complexes as wood protectants
2017 - IRG/WP 17-30708
The anti-fungal activity of Rutin, a flavonoid, alone or complexed with copper or zinc was investigated in a petri dish test with Gloeophyllum trabeum and Trametes versicolor as the test fungi. Rutin and the Rutin-metal complexes showed significant inhibition against each fungus. Rutin-Cu and Rutin-Zn strongly inhibited the brown rot fungus, G. trabeum, while Rutin and Rutin-Zn inhibited T. versic...
Li Yan, J J Morrell, Jie Zhong, Xiuzhu Mao


Liquefaction of woody waste: A novel approach in wood protection from CNSL based liquefied wood polyols
2017 - IRG/WP 17-30711
Liquefaction of lingo-cellulosic biomass is one of the thermo-chemical conversion processes for developing new materials, adhesives, preservatives and energy systems. The process also provides an opportunity to utilize waste wood such as saw-dust, woody wastes, branches and twigs for the development of value added products. Thus, this research paper deals with an investigation of antifungal and a...
A Kumar, G B.Nagarajappa, S Singh Chauhan


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd


Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor


Penetration behaviour of different hydrophobic carrier substances for oily wood preservatives in Beech and Scots pine sapwood
2017 - IRG/WP 17-40804
The use of creosote as a wood preservative has a long history. Current areas of application are railway sleepers, transmission poles, timber bridges and marine applications. If the approval for creosote will not be prolonged, alternative wood preservatives will be needed. As the penetration behaviour after pressure impregnation of different alternative oily products in this fields of application i...
M Starck, A Gellerich, H Militz


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Exterior paint for the future - Will there be any dry-film preservatives left?
2017 - IRG/WP 17-50332
Wooden houses have a long tradition in several of the Nordic countries. Wood can be protected in various ways; constructional, chemically and by surface treatment. The use of various types of exterior paints as a surface treatment is a common way to prolong the durability of the wood. To further protect the painted surface against growth of fungi and algae, dry-film biocides remains an essential p...
H Jensen, M Sandve, S M Lystvet


Liquefied wood polyols: Ecofriendly bio-based preservative for sustainable protection of wood from Termite attack
2018 - IRG/WP 18-10916
The major problems encountered in both indoor and outdoor utilization of wood are biological decay due to termite. The modification of wood with liquefied wood polyols has been found to be effective against termite attack. The liquefaction of wood aims to utilize woody wastes which are being generated during primary and secondary processing of wood in wood based industry. One of promising approach...
A Kumar, A John, T S Mehra, A K Pandey, S Singh Chauhan


Certification system for treated wood and wood preservative in the relation to regulations in Japan
2018 - RG/WP 18-20639
Certification system about wood protection products in Japan is described to understand the interaction between regulations and certifying organizations. Major regulations are Building Standard Law, Chemical Substances Control Law, Poisonous Deleterious Substances Control Act, Japanese Industrial Standards, and Japanese Agricultural Standard (JAS). Treated wood products are certified with JAS mark...
K Yamamoto, I Momohara


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