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Commercial antisapstain chemicals in New Zealand
1980 - IRG/WP 3142
Almost all sawn timber of exotic softwoods (principally Pinus radiata) and a large proportion of indigenous sawn timber receives an antisapstain chemical treatment to prevent fungal degrade during subsequent seasoning, storage, or transportation (if exported). Antisapstain chemicals are also widely used to protect freshly peeled round produce during drying. A further, specialised, use is as the fu...
J A Butcher


Health and safety regulations on the use of wood preservatives in Switzerland
1980 - IRG/WP 3148
There is not any doubt that the chemical protection of wood (besides the architectional-constructional wood protection) is of utmost importance for the increase of the durability of technically used timber. The toxic properties of wood preservatives make certain legal regulations necessary for the protection of human beings, animals and the environment. Thereby wood preservatives fall under the po...
O Wälchli


Some practical implications from recent research on the fixation of CCA preservatives
1975 - IRG/WP 358
The mechanism of fixation of CCA preservatives is briefly described. If the temperature is increased during the primary fixation period, the formation of intermediate fixation compounds is less extensive. The length of the primary fixation period is of practical interest. It is determined by preservative composition and concentration, temperature and wood species. Diagrams are given for Pinus sylv...
S-E Dahlgren


Fungicidal effectiveness of amended alkylammonium compound
1987 - IRG/WP 3421
Amendment of didecyldimethylammonium chloride was attempted to improve its fungicidal effectiveness and properties of treating solutions. Addition of copper definitely increased effectiveness in controlling wood decay fungi, although metal corrosiveness and stability of treating solutions was unsatisfactory. Further amendment with stabilizer(s), anticorrosive agent(s) and sequestering agent(s) res...
K Tsunoda, K Nishimoto


Effect of species, retention and conditioning temperature on copper stabilization and leaching for ACQ-D
2004 - IRG/WP 04-30342
The time to stabilization or equalization of the copper component of ACQ-D was highly dependent on treating solution concentration (preservative retention) and post treatment temperature. Stabilization was rapid for low preservative retentions but extended times were needed for wood treated with higher concentration solutions. The extent of stabilization was also concentration dependent with a h...
Y T Ung, P A Cooper


Characterization of Poria indoor brown-rot fungi
1995 - IRG/WP 95-10094
The heterogeneous group of "Poria" fungi causing brown rot in buildings and also of wood in ground contact comprises Antrodia vaillantii, Antrodia serialis, Antrodia sinuosa, Antrodia xantha and Tyromyces placenta. These fungi have similar morphological appearance and biology. Their nomenclature has a confusing history and is still not uniform. As a consequence, misinterpretations may occur. SDS p...
O Schmidt


Protection of rubberwood timber. Part 1: Impregnation with boron preservatives
1989 - IRG/WP 3551
Rubberwood (Hevea brasiliensis) were treated with a 3% proprietary mixture of borax/boric acid using three different treatment schedules i.e. full-cell, full-cell to refusal and full-cell with 12 cycles of vacuum/pressure. Freshly cut samples had mean preservative retentions of 187 kg/m³, 214 kg/m³ and 178 kg/m³ respectively. Pre-air dried samples for one week had retentions of 252 kg/m³, 308 ...
L T Hong, C C K Liew


Screening wood preservatives: Comparison of the soil block, agar block and agar plate tests
1993 - IRG/WP 93-20001
Several test procedures have been developed over the years to screen potential biocides for their value as wood preservatives. Each test has inherent advantages and disadvantages. In this paper the relative merits of the soil block, agar block and agar plate tests are compared. Eight commercially available biocides encompassing inorganic and organic systems were tested against four basidiomycete d...
K J Archer, D D Nicholas, T Schultz


Ammoniacal wood preservatives for use in non-pressure treatment of spruce and aspen poplar. Part 2
1984 - IRG/WP 3274
A series of thermal diffusion treatments were carried out on unseasoned white spruce (Picea glauca (Moench) Voss) lumber and air dry aspen poplar (Populus tremuloides Michx.) timbers using an ammoniacal copper arsenate wood preservative. Under the specific conditions described, certain charges of lumber met the present Canadian Standards Association Wood Preservation Committee's requireme...
C D Ralph, J K Shields


Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick


EPA’s Current Views on Heavy-Duty Wood Preservative Regulation
2003 - IRG/WP 03-50206
This paper describes the current EPA system for regulating pesticides and wood preservatives. In particular it focuses on the voluntary phase-out of CCA for residential uses after December 30, 2003, which was agreed between the CCA manufacturers and EPA. Even though the EPA reached an agreement with industry to phase out CCA for residential uses, EPA is continuing the most rigorous risk assessmen...
F T Sanders


Efficacy of waterborne copper naphthenate as preservative for northern hardwood species
1995 - IRG/WP 95-30091
Northern red oak (Quercus rubra) and red maple (Acer rubrum) cubes pressure treated with waterborne formulation of copper naphthenate were evaluated for resistance to attack by brown fungi Gloeophyllum trabeum (Pers. ex Fr.) Murr. (Madison 617 ATCC 11539) and Poria placenta (Fr.) Cooke (Madison 698, ATCC 11538), white rot fungi Trametes versicolor (L. ex Fr.) Pilat (R-105 from Jeff Morrell), Irpex...
D P Kamdem, R Fair, M H Freeman


Chromated copper arsenate preservative treatment of hardwoods. Part 2: leaching performance of seven North American hardwoods
1997 - IRG/WP 97-30132
Seven North American hardwood species were treated with 2% CCA-C solution and fixed at temperatures of 21°C and 50°C and conditions of high relative humidity (95%) as described in Part 1 of this presentation. Red pine (Pinus resinosa) was included as a softwood for comparison. Adequately fixed wood blocks (99.9% chromium fixation) were exposed to leaching tests according to AWPA E11-87 test. Par...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Biosorption of metals for wood waste effluent clean up
1997 - IRG/WP 97-50090
The common filamentous fungi can sorb metal ions from aqueous solutions. The biosorption of metal ions like copper Cu2+, chromium Cr6+ and arsenic As5+ by dead fungal mycelia was investigated. Two industrial fermentation byproducts are tested: Mucor miehei and Aspergillus oryzae. The adsorption of metal ions depends on parameters such as chemical treatment of fungi before biosorption (acid or basi...
S Legay, G Labat


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


A laboratory bioassay method for testing preservatives against the marine borers Limnoria tripunctata, L. quadripunctata (Crustacea) and Lyrodus pedicellatus (Mollusca)
1990 - IRG/WP 4159
A laboratory culture and bioassay method is described for the marine borers Limnoria tripunctata, Limnoria quadripunctata, and Lyrodus pedicellatus. The methods were tested in a bioassay using established marine preservatives. The attack produced on blocks treated with CCA or creosote in some ways paralleled the attack found in the sea. Limnoria tripunctata attacked treated and untreated pine bloc...
L J Cookson


Marine performance of preservative treated Southern pine panels. - Part 1: Exposure in Newport, Oregon
2000 - IRG/WP 00-10368
The ability of selected wood preservative to protect southern pine sapwood against marine borer attack was evaluated over a 6 year period in Yaquina Bay, Oregon. The site exposed the wood to potential attack by both Teredo navalis and Limnoria spp. Both creosote and CCA provided excellent protection at moderate retentions, while ACQ produced slight differences in performance depending on the coppe...
R G Rhatigan, J J Morrell, A R Zahora


Basilit CCFZ. Further studies on ecotoxicological behaviour
1992 - IRG/WP 92-3722
Basilit CCFZ is a new developed water based preservative for the protection of timber in hazard class 4 and 5 (ground-, fresh- and salt-water contact). The active components of this salt are copper, chromium, zinc and fluorine. In addition to primarily studies on the acute toxicity against organisms of the aquatic food chain a long term ecotoxicological study was performed. In a prolonged toxicity...
H W Wegen


Fouling assemblage development on copper-chromium-arsenic-treated timber submerged in European waters
2002 - IRG/WP 02-50181
The effect of the anti-marine-borer timber preservative CCA on community development of non-target marine fouling animals was investigated. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m3 of wood, plus untreated controls were submerged at seven coastal sites (Portsmouth, UK; La Tremblade (2 sites), France; Ria Formosa, Portugal; Sagres, Portugal; Kristineberg, Swed...
C Brown, R J Eaton, S M Cragg, P Goulletquer, A Nicolaidou, M J Bebianno, J Icely, G F Daniel, T Nilsson, A J Pitman, G Sawyer


The ecotoxicology assessment of wood preservatives and their active ingredients by means of germination tests using cress - A critical consideration
1999 - IRG/WP 99-50125
With putting the Biocidal Products Directive 98/08/EC (BPD) in place an environmental risk assessment for wood preservatives and impregnated timber is requested. To assess possible risks, suitable test methods are required, which reveal the ecotoxicological profile including environmental fate and behaviour of treated commodities. Germination and growth tests could contribute to the determination ...
P Jüngel, A O Rapp, E Melcher


Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


Report on the efficacy and performance of the insecticide candidate termiticide in H2 field trials
2004 - IRG/WP 04-10516
This paper explains the field results of phenol pyrazole treated timber against in an above ground mound colonies of Coptotermes acinaciformis (Froggatt). C. acinaciformis (‘termites’) are the major pest of human structures throughout tropical and sub tropical regions, causing billions of dollars in damage to timber-in-service worldwide. The result of this field test have shown that candidate ...
B M Ahmed, P Vinden, J Hann, J R J French


Co-operative tests concerning influence of solvent and drying method on the toxic limit of wood preservatives against Basidiomycetes. Preliminary report
1971 - IRG/WP 204
In the Working Group II of the Organization for Economic Co-operation and Development working group on wood preservation (now International Research Group on wood preservation) it was agreed that more knowledge was necessary concerning the influence of the solvent on the toxic limit of organic solvent types of wood preservatives against Basidiomycetes. A test program was drawn up and after discuss...
T Hof


Environmentally benign wood preservatives based on organic biocide antioxidant combinations: A brief review of laboratory and field exposure results and discussion of a proposed mechanism
2004 - IRG/WP 04-30335
The combination of various organic biocides with commercial antioxidants generally increased the biocides’ efficacy 2-3 fold against wood-destroying fungi in short-term laboratory decay tests, and some positive results have been obtained after 2-4 years of outdoor exposure. The two antioxidants principally examined, propyl gallate and butylated hydroxytoluene, are low cost and, since both are f...
T Schultz, D D Nicholas, W Henry, C Pittman, D Wipf, B Goodell


Performance of copper-chrome formulations in ground contact in five test sites in New Zealand
1996 - IRG/WP 96-30113
Copper-chrome-arsenate (CCA), copper-chrome-boron (CCB), copper-chrome-fluoride (CCF) and copper-chrome-phosphate (CCP) have been tested at four retentions each in ground contact (25 x 50 x 500 mm³ radiata pine sapwood stakes) for 16 years in five test sites in New Zealand. Results to date show that test site characteristics have a marked effect on relative performance. In a warm and wet site (an...
M E Hedley, R N Wakeling, J Foster, B E Patterson


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