IRG Documents Database and Compendium


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Sterilization of mango wood (Mangifera indica L.) without heat
1995 - IRG/WP 95-30065
Researches revealed that boric acid can play an important role for sterilizing wood instead of heating. Wet (green) mango boards (Mangifera indica L.) were pressure treated in treating cylinder at initial vacuum of 508 mm Hg for 15 minutes and impregnation pressure of 7 kg/cm² for 4 hours with 5% solution (w/v) of 1:1:1 commercial grade (95% pure) sodium dichromate, copper sulphate and boric acid...
A K Lahiry


The reliability of colouring methods for the determination of biflourides and boron in spruce wood
1994 - IRG/WP 94-20036
From practical reasons, qualitative spraying methods are widely used for the detection of bifluorides and boron in wood. The main aim of this research was to detect whether the concentration of the active ingredient in the coloured area is equal or greater than the toxic value against basidiomycetes. Both colouring methods, Z-A reagent for fluorides and curcuma reagent for boric acid, are a reliab...
R Grell, M G Sanders, W J Homan, H Militz


A comparative study of CCA type C and B treated poles in service
1993 - IRG/WP 93-50001-05
CCA K33 type B and C treated utility poles, 9 pieces of each treatment type, were analyzed for preservative retention after 11 years in use. Borings were taking 1 m above and 0.3 m below the ground line. Also total amount of copper, chromium and arsenic was determined in soil surrounding the poles. The solubility of these active components in soil was monitored by using different leaching procedur...
A J Nurmi


The dip diffusion treatment of tropical building timbers in Papua New Guinea
1972 - IRG/WP 310
In Papua New Guinea a dip diffusion process using a multi salt preservative developed by C.S.I.R.0. has been in commercial use for 8 years. Over 200 million super feet (236,000 m³ ) of timber has been treated during this period and current rate of treatment is 34 million super feet (80,400 m³ ) of timber per year in 70 licenced treatment plants. The process has been found to be simple to apply, ...
C R Levy, S J Colwell, K A Garbutt


Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


A Preliminary Report on the Properties of Engineered Wood Composite Panels Treated with Copper Naphthenate
2005 - IRG/WP 05-40294
This paper reports on our preliminary investigation of the properties of randomly oriented strandboard which had waterborne or powdered copper naphthenate (CuN) incorporated into the board during manufacture. When compared to zinc borate-treated controls (ZnB), the mechanical properties of strandboard (MOR, MOE, work-to-maximum load, internal bond strength) were not adversely affected by treatmen...
J W Kirkpatrick, H M Barnes


Leachability And Decay Resistance of Copper-Treated Wood
2004 - IRG/WP 04-30337
Samples of scots pine sapwood (Pinus sylvestris L.) were treated with solutions of (Copper II sulfat-5 hydro + fluoroboric acid) and (Copper II sulfat-5 hydro + fluoroboric acid + boric acid) in order to determining to leachability and decay resistance against brown rot fungus (Postia placenta) and white rot fungus (Coriolus versicolor). Results indicated that the copper in treated wood is less s...
A Temiz, T Nilsson, I Deemirtas, Ü C Yildiz


Bioefficacy of boric acid grafted onto wood
1999 - IRG/WP 99-30202
The use of borate treated wood in outdoor is limited because of the migration of borate. The objective of this study is to investigate the fixation of boric acid in wood using polyethylene glycol (PEG-400) to form polyester borate and isocyanato group as coupling agent. FT-IR was used to monitor the reaction between boric acid and PEG. Elemental analysis was conducted to evaluate the C, H, and N v...
Weining Cui, D P Kamdem


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Treatment of wood-based panel products with volatile borate
1990 - IRG/WP 3616
The paper presents recent developments in the use of volatile borate esters for the preservative treatment of wood based board materials. Several advances on previous reports are discussed. In laboratory studies, treatment times of approximately ten minutes at 20°C on boards at equilibrium moisture content provided full penetration and retentions of 1% wt/wt boric acid. Biological tests have been...
P Turner, R J Murphy, D J Dickinson


Soil-bed studies. Part 2: The efficacy of wood preservative
1983 - IRG/WP 2205
Various methods of decay assessment were investigated. Three stages or phases of decay were identified which could be used to describe the efficacy of a preservative system or virulence of a soil-bed testing medium. These included the lag, decay, and senescent phase. Premature senescence could arise if wood samples became waterlogged. It was concluded that time to failure was unsuitable as a metho...
P Vinden, J F Levy, D J Dickinson


Anatomical Characteristics to the Distribution of Water-borne Copper Wood Preservatives in Wood
2004 - IRG/WP 04-40277
The objective of this study was to understand the micro-distribution of a copper-based preservative in wood in connection with anatomical morphology and to consider the fixation of copper in wood. Bulk specimens and semi-ultra thin sections (0.5µm) obtained from Japanese cedar were treated with a CuAz preservative solution. After fixation, SEM-EDXA was used to investigate the micro-distribution...
H Matsunaga, J Matsumura, K Oda


Leaching Characteristics of Copper in Copper Treated Wood
2003 - IRG/WP 03-30316
The leaching characteristics of copper in copper treated bamboo and other wood species such as slash pine and poplar has been conducted in this paper according to AWPA M11-87 standard, the result indicates that: --Copper fixation rate of salts from organic acids such as citrate and oxalate and malate is less than other non-organic acid formulations. --Copper fixation rate of oven-dried bamboo sa...
Mingliang Jiang, Junliang Liu, Daochun Qin, Yamei Wang, Zehui Jiang


Determination of fixation properties by bioassays - A proposal for the assessment of safety indexes in wood protection
1990 - IRG/WP 3566
In the determination of environmental effects of chemicals tests with fishes, daphnia and algae have proved to be practicable. With respect to wood protection such bioassays are suitable to control effects of treated timber against aquatic organisms. By using the fish-acute-toxicity-test the development of a laboratory test method is described for the checking of the fixation rate of a copper-chro...
H-W Wegen


A study of decay type variability in variously treated Fagus sylvatica and Pinus radiata field test stakes exposed at a vineyard for 30 - 45 months
1998 - IRG/WP 98-10271
Pinus radiata test stakes were treated with 10 kg/m3 of CCA plus 4 lower retentions in a geometric series of 1.5. Fagus sylvatica was treated with 15 kg/m3 and 2 lower retentions. Both timber species were also treated with equivalent retentions of various new generation preservatives (P. radiata was also treated with creosote). Whilst these stakes were exposed at 11 sites in New Zealand (NZ) and 2...
R N Wakeling, A P Singh


Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


Performance of copper-based wood preservatives in above ground and ground contact tests
1994 - IRG/WP 94-30057
The relative performance of a range of copper-based wood preservatives was compared using above ground and ground contact procedures. The data, accumulated after several years' testing, show that on an equivalent active ingredient basis, differences in performance of the preservative systems tested can vary quite markedly. The contribution of co-biocides to the overall performance of thes...
A F Preston, K J Archer, L Jin, W Metzner, D Seepe


Copper naphthenate: An analysis of the materials found in the worldwide marketplace using a new analytical technique
2000 - IRG/WP 00-30224
Naphthenic acid has been recovered from products of petroleum refining for well over 100 years. The metal soaps, specifically copper and zinc naphthenate, have been evaluated and used as commercial wood preservatives for in excess of 60 years. Most of the early data supporting the continued use of copper naphthenate as a wood preservative was based on materials manufactured from naturally occurrin...
J A Brient, R E Moyer, M H Freeman, H Jiang


Fungus cellar testing as an evaluation method for performance of treated timber in ground contact
2001 - IRG/WP 01-20227
A fungus cellar method for the accelerated evaluation of performance of treated wood in ground contact is described. The test soil comprised of sandy loam, vermiculite and Japanese horticulture soil "Kanumatsuchi" in a ratio of 6:2:2 by volume. The soil was inoculated with the dominant test fungus isolated with selective medium from decayed wood samples. Pairs of treated and untreated wood specime...
Y Nagano


Wood Preservatives Science Issues: US EPA’s Perspective
2005 - IRG/WP 05-50224-2
The USEPA Office of Pesticide Programs (OPP), Antimicrobials Division (AD), regulates the use of chemicals registered as wood preservatives in the United States. An overview of the registration and re-registration process is presented. The wood preservatives data requirements include toxicological, human exposure, ecological, and environmental fate data. A detailed discussion of wood preservati...
N Elkassabany


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


CCA modifications and their effect on soft rot in hardwoods. Part 2
1983 - IRG/WP 3244
The work outlined in this document is a continuation of that presented in Document No: IRG/WP/3201. The findings described in the previous paper are summarised below: a double treatment of CCB followed by arsenic (CCB+A) is more effective than a double treatment of boron followed by CCA (B+CCA) or a single treatment of CCA, CCB or CCAB in controlling soft-rot due to Chaetomium globosum in birch. C...
S M Gray, D J Dickinson


Corrosion of zinc-coated nails used with preservative-treated western red cedar shakes in service
1982 - IRG/WP 3197
The corrosion of metal fasteners used with certain wood species and with preservative-treated woods can be a serious problem. The chemical reactivity of western red cedar (Thuja plicata Donn) extractives to iron and copper is well documented and wood preservative treatments containing copper, chromium, and/or ammonium hydroxide can be expected to similarly attack some metals. This problem is compo...
R S Smith, E L Johnson, A J Cserjesi


The efficacy of remedial treatments for controlling fungal decay in window millwork used in the United States
1987 - IRG/WP 3432
Conventional window millwork was subjected to basidiomycete decay by inoculation and sampled for active growth of the decay fungus before and eight months after remedial preservative treatment with fused disodium octaborate rods (IMPEL) at boric acid levels of 1.5 and 4.0 kg/m³ or liquid bifluoride injections (IMPROSOL) at 1 kg/m³. The elimination of decay fungus after remedial treatment was nea...
M G Dietz, E L Schmidt


Effectiveness of a newly registered antisapstain preservative in preventing stain of Eucalypt timber in Australia
2000 - IRG/WP 00-30229
An antisapstain trial was conducted on two sites (Alexandra and Trentham) in order to establish the concentration of a newly registered antisapstain preservative (consisting of benzalkonium chloride (BAC) & 3-iodo-2-propynyl butyl carbamate (IPBC) & disodium octoborate (boron)) needed to prevent stain of Eucalypt timber. After 20 weeks of exposure at the Trentham site, the water treated bo...
J Snow, P R S Cobham, N Ryan


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