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Some textile auxiliaries as wood protective agents
2007 - IRG/WP 07-30417
This study evaluated some textile auxiliaries applicable for wood protection. Commercial alkoxysilane quarternary ammonium formulation and fluorocarbon based water-oil repellent were tested for their ability to provide hydrophobicity and antifungal effect to solid wood samples. Scots pine (Pinus sylvestris L.) sapwood samples were impregnated with 25, 50 and 100 % concentrations of the above menti...
E Dizman, A Temiz, N Terziev, Ü C Yildiz


Influence of ethanolamine on lignin depolymerization and copper leaching from treated Norway spruce and beech wood
2007 - IRG/WP 07-30423
Copper-ethanolamine based wood preservatives are replacing several classical copper-chromium based solutions, due to foreseen ban of chromium. Fixation of copper-ethanolamine based wood preservatives is not as good as fixation of copper-chromium ones. The main object of this manuscript was to prove, that ethanolamine is the prime reason for insufficient fixation of copper-ethanolamine formulations...
M Humar, B Bucar, M Zupancic, D Žlindra, F Pohleven


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


The effect of brighteners on wood surface aesthetics – exploring the use of various organo-phosphonates based precursors
2007 - IRG/WP 07-30441
Freshly cut hardwood lumber such as white oak, red oak, beech, or redwood are rich in mineral stain (mostly iron and calcium), which provides a strong discoloration of the wood surface significantly influencing the aesthetic of the wood surface and strongly affecting the cost of this lumber. The influence of mineral stain on soft wood discoloration (Southern Yellow Pine, Douglas fir, etc.) is les...
R Craciun, P Mitchell


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


Refinement of emission values for preserved wood in the ‘Storage Scenario’, for use in the environmental risk assessment of Wood Preservatives under the Biocidal Products Directive
2007 - IRG/WP 07-50244
The evaluation of an active substance or a biocidal product under the Biocidal Products Directive (BPD) requires that an environmental risk assessment is carried out. The risk assessment for wood preservatives includes a scenario for the treated wood in storage after treatment, in which the predicted environmental concentration (PEC) in soil, surface water and groundwater is calculated, using emis...
E F Baines


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Evaluatiang the potency of cinnamaldehyde as a natural wood preservatives
2007 - IRG/WP 07-30444
Since cinnamaldehyde, the major constituent of leaf essential oil from Cinnamomum osmophloeum, has significant antifungal and antitermitic activities, it is worthy of understanding whether cinnamaldehyde has potential to be used as a natural preservative for improving the durability of wood. In this study, the fungi and termite resistance of cinnamaldehyde-treated wood (CTW) were evaluated accordi...
Chun-Ya Lin, Chi-Lin Wu, Shang-Tzen Chang


Validity of above ground testing according to ENV 12037
2008 - IRG/WP 08-20379
The standard ENV 12037 for testing of treated and untreated wood (lap-joint) exposed above ground was issued in 1996 by The European Committee for Standardization. A draft for the development of the standard was presented by CEN-TC 38/WG 25/DOC N 076 in 2002. For a test to become valid the median rating of decay for untreated control replicates (Scots pine sapwood) must be equal or greater than ...
Ö Bergman, U Råberg, N Terziev


Development of a Weatherometer to Accelerate the Surface Checking of Wood
2008 - IRG/WP 08-20388
There is significant interest in developing preservatives that are better at preventing wood from checking. Currently, however, there is no accepted test methodology for accelerating the development of checks in wood samples so information on the effectiveness of treatments at restricting checking can be obtained more quickly. This paper describes the development of a new type of weatherometer (Ac...
R Ratu, P D Evans


Influence of Polyvinyl acetate emulsion (PVA) on boron leaching and fungicidal properties
2008 - IRG/WP 08-30451
Boron compounds are very effective fungicides, but unfortunately they leach from wood. In order to improve boron fixation, boric acid, borax were combined with polyvinyl acetate emulsion (PVA). For comparison copper salts were included into this research as well. Selected preservative solutions were chosen for impregnation of Norway spruce wood specimens (Picea abies). Wood blocks were exposed to ...
M Humar, B Lesar, P Kralj


Preliminary evaluation of efficacy of copper in combination with boron and NHA (N'-N-(1, 8-naphthalyl) hydroxylamine) against wood decay
2008 - IRG/WP 08-30452
In this study, efficacy of various combinations of copper sulfate with either boric acid or calcium precipitating agent, NHA-Na (N'-N-(1, 8-naphthalyl) hydroxylamine) was evaluated. Wood specimens were treated with either 1%, 0.5%, or 0.1% concentrations of copper sulfate, boric acid, NHA-Na, copper sulfate + boric acid, or copper sulfate + NHA-Na mixtures. Treated specimens were subjecte...
E Terzi, C Köse, S N Kartal


Effect of amphiphilic antioxidant alkyl ammonium ascorbate on inhibition of fungal growth: Application to wood preservatives formulation
2008 - IRG/WP 08-30466
Amphiphilic surfactants were synthesized from ascorbic acid and different fatty amines and evaluated for formulation of wood preservation products. Characterization of physicochemical properties of the new compounds indicated classical behavior of cationic surfactants. Antioxidant properties, estimated using methyl linoleate oxidation inhibition method, were similar to that of ascorbic acid teste...
C Gérardin , T Koumbi Mounanga, P Gérardin


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


The Comparison of Fixation and Leachability of Bark, Fruit and Leaf Tannin Extracts with Boron Minerals
2008 - IRG/WP 08-30473
Tannins extracted from several plants have natural durability properties. Due to these properties, some of the researchers have studied them for protecting wood. In this study, Scots pine (Pinus sylvestris) and beech (Fagus orientalis) wood samples were treated with bark, fruit, and leaf extracts as well as water-based wood preservative salts at various concentrations to increase fixation. The pen...
S Sen, C Tascioglu, K Tirak


Performance of wood-based composites in a protected aboveground test in southern Japan
2008 - IRG/WP 08-40391
Five kinds of untreated wood-based composites (medium density fiberboard, hardwood plywood=HP, softwood plywood, particleboard and aspen oriented strand board, hereinafter abbreviated as MDF, HP, SP, PB and OSB, respectively) were exposed to subterranean termites and microbial (decay) attack under protected aboveground conditions in a southern part of Japan (Kagoshima Prefecture) for six years. An...
K Tsunoda


Effects of Murgul Copper Process flue gases (SO2) on compression strength parallel to the grain of Beech (Fagus orientalis Lipsky.) wood
2008 - IRG/WP 08-40404
In this study was investigated the effect on the compression strength parallel to the grain as mechanical properties of Fagus orientalis Lipsky. wood exposed to SO2 gas and non-exposed. In the experiments the two of four (total) were obtained from Artvin-Ortaköy region and the other two from Artvin-Murgul region. The compression strength parallel to the grain was calculated at the compare of ...
N Ay, E Topaloglu, A Uncu


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Near infrared spectroscopy for the quantification of wood preservatives
2008 - IRG/WP 08-20391
Near infrared (NIR) spectroscopy is a rapid, flexible, inexpensive and non-destructive technology that has many applications, including the evaluation of many wood properties. Initial studies have indicated the potential to apply NIRS for the quantification of wood preservatives. However, further evaluation with borate and azole preservative systems has revealed that NIRS technology is challenged ...
A M Taylor, Seung H Baek, Myong K Jeong, J D Lloyd, J J Morrell


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