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Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Field Stake Tests with Copper-based Preservatives
2008 - IRG/WP 08-30459
The performance of field test stakes derived from commercially produced ground contact retention copper quat preservatives based on either soluble copper complexed with ethanolamine, or from a water-based suspension of particulate micronized copper compounds, as well as untreated southern yellow pine controls, is compared at two decay test sites. After less than one year in field test some of t...
A Preston, L Jin, D Nicholas, A Zahora, P Walcheski, K Archer, T Schultz


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Physical and Mechanical Properties of Bamboo Oriented Strand Board Treated with Copper-based Preservatives
2009 - IRG/WP 09-40482
Oriented strand board (OSB) has been gradually accepted, used and developed in China. Bamboo is a renewable and potential non-wood fibre resource for making OSB. But the nature of bamboo makes its products including bamboo OSB (BOSB) more prone to decay and mold. Protection BOSB from biodegradation is the key both to efficiently using bamboo resource and to improving the durability of the final pr...
Juwan Jin, Daochun Qin


Microscopy evaluation of microbial decay patterns in wood stakes after 6 years in soil contact
2010 - IRG/WP 10-10715
Most studies on wood modification have so far been concerned with service life predictions rather than investigating the decay protection mechanism. Very little is known about the mode of action of these new treatments and about the strategies used by wood degraders in order to utilize the wood material despite a treatment. Access to such knowledge would allow further modification and improvement ...
A Pilgård, C G Björdal


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


A Comparison of the Performance of Related Copper Based Preservatives against Soft Rot
2010 - IRG/WP 10-30540
The performance of pine and beech wood treated with either a soluble copper + quat (ACQ type D) preservative system or a particulate copper + quat system was evaluated in unsterile soil using the European standard ENV 807 soft rot decay test procedure. In addition, to compare soft rot performance of soluble and particulate copper directly without the influence of co-biocides, beech and pine test...
M Ray, D Dickinson, K Archer


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


Sample Origin Influencing the Leachability of Wood Preservatives
2011 - IRG/WP 11-20474
The aim of this study is to see if the raw material influences fixation and leachability of wood preservatives. Moving towards more eco-friendly and –concious society, the wood industries must adjust itself to new rules and regulations. Greener solutions in wood protection are being tested and introduced, older systems are being improved, but questions still arise concerning some elements curren...
K Kängsepp. E Larnøy, P Meier


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


Scale-up of a chemical process for copper-based preservative-treated wood wastes recycling
2012 - IRG/WP 12-50286
In recent years, the development of appropriate wood waste disposal options has been encouraged by severe regulations and expensive fees associated with wastes landfilling or burning. An efficient and economically attractive leaching process was developed at laboratory scale (200 mL) for CCA-, ACQ- and CA-treated wood wastes recycling. This leaching process consisted of three leaching steps of 2 h...
L Coudert, L Gastonguay, J F Blais, G Mercier, P Cooper, P Morris, A Janin, N Reynier


Micronized Copper Wood Preservatives: Strong Indications of the Reservoir Effect
2013 - IRG/WP 13-30609
Micronized copper wood preservative systems were launched commercially in May 2006. Now, over 75% of the residential lumber produced in the USA is treated with micronized wood preservative formulations. Although considered controversial at first, the mode of action of micronized copper has been clearly defined by multiple authors over the years, as well as a need for a co-biocide in water-borne sy...
M H Freeman, C R McIntyre


Performance of untreated wood and wood impregnated with copper-ethanolamine based preservative solutions in Northern Adriatic Sea
2013 - IRG/WP 13-30623
Sea water applications of wood are among the most challenging ones. Impregnated wood is exposed to leaching and to variety of marine borers, Limnoria sp. and Teredo sp. being the most important. In the present research, durability of pine wood impregnated with copper-amine based preservative solution (Silvanolin) of different concentrations, exposed to the sea water, was investigated according to ...
M Humar, M Petrič, J Adamek, B Lesar


Performance of Coatings on Wood Treated with Carbon-Based Preservatives
2013 - IRG/WP 13-40638
Wood treated with carbon-based preservatives is often used in applications where coatings are required, yet few studies have examined the effect of such treatment on coating performance. Users need to be confident that coatings on carbon-based preservative-treated wood will perform as well as or better than those on untreated wood. The present study examines the performance of three coatings on un...
R Stirling, P I Morris


Copper and chromium leaching from wood impregnated with chromium-copper containing preservatives: Results of different studies
2014 - IRG/WP 14-50300
Copper and chromium based wood preservatives remained one of the most important ingredients for wood protection solutions for protection of wood in demanding applications all-over the world. Leaching of heavy metals from treated wood is important from two different aspects; firstly from performance point of view, and secondly from environmental issues. However, the importance of these studies is i...
M Humar, N Thaler, E Melcher


Factors Affecting Performance of Preserved Wood Decking Against Decay Fungi
2015 - IRG/WP 15-30663
Decking is the largest market for residential preserved wood in the United States. Preserved decking must be resistant to colonization by decay fungi initiating from spores, and occasionally from mycelia due to elevated soil levels or adjacent untreated wood. The most vulnerable parts of a preserved wood deck are untreated, or under-treated, wood that becomes exposed by field cuts and checking. Fi...
R Stirling, P I Morris


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 a...
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe


Performance of copper treated poles and posts after three to fifteen years of exposure
2016 - IRG/WP 16-20595
Copper based wood preservatives are one of the most important wood preservatives for heavy-duty applications. Wood treated with copper-based preservatives performs excellent if applied according to preservative specifications. If used improperly premature failures might appear. In order to elucidate properties of copper treated wood in use, utility poles and posts treated with copper-based preserv...
M Humar, N Thaler


Moisture monitoring in WW2 partisan hospital Franja
2016 - IRG/WP 16-20596
Material climate of wood used for construction of WW2 Partisan hospital Franja was monitored for approximately one year. Partisan hospital is located in the bottom of tiny gorge Pasice in Slovenia. Hence, wood moisture content on eight respective location and wood temperature was determined twice per day with Scanntronik equipment Gigamodul and Thermofox. The results clearly showed that despite of...
M Humar, N Thaler, B Lesar, A Žagar


A non-VOC approach of solvent-based wood preservatives for remedial treatment
2016 - IRG/WP 16-30681
Solvent-based wood preservatives are the workhorses in the field of remedial treatment. Due to new European regulations on the indoor air quality there is an increasing pressure on the VOC-content on these solvent-based product types. The transfer of these European regulations into national law is left up to each European member state and handled in different ways. E.g. France has introduced a VO...
M Pallaske, S Hellkamp, P Jüngel


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