IRG Documents Database and Compendium


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Accumulation of copper in parenchyma cells in southern pine wood treated with micronized and amine-copper preservatives
2019 - IRG/WP 19-20657
Our previous research used X-ray micro-computed tomography to examine the micro-distribution of copper in southern pine wood treated with a micronized wood preservative (MCA) and an amine-copper preservative (ACQ). We found that copper in wood treated with MCA was mainly concentrated in fusiform rays (rays containing resin canals), and in vertical (axial) resin canals. A similar, although not iden...
D Feng, M L Turner, A Limaye, M A Knackstedt, P D Evans


COPPER NAPHTHENATE: A Product for All Seasons: Protecting the Americas’ Infrastructure for Over 100 Years and Potential for Expanded Usage in Europe
2019 - IRG/WP 19-30738
This paper is a brief review of the history and use of the wood preservative Copper Naphthenate, with a focus on use patterns within the USA and opportunities for expansion in Europe and Canada. This paper reviews how copper naphthenate has performed to preserve and protect cellulosic and wooden items essential to critical infrastructure, and why it is the ideal choice for use in the replacement o...
M H Freeman, J A Brient, M Manning


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Relative efficacy of various oxine copper formulations against brown-rot fungi
2019 - IRG/WP 19-30741
This paper investigates the relative resistance of three different oxine copper formulations (oil-borne, water-borne, water-borne with pH-adjustment) as a preservative treatment for wood against brown-rot fungi. Impregnated southern pine sapwood cubes were exposed to R. placenta and G. trabeum cultures in a soil-block test. After eight weeks, the weight losses of the cubes were examined in relatio...
M Petruch, J Lloyd, A Taylor


Effect ofNano-Copper Oxide on Decay Resistance of Pistachio Twig-Plastic Composite
2019 - IRG/WP 19-30750
The goal of our study was to investigate the decay resistance of pistachio twig-plastic composite treated with nano-copper oxide against the white rot fungus Trametes versicoloer and the brown rot fungus Coniophora puteana. For this purpose, wood–polypropylene composites (WPCs) containing different loadings of nano-copper oxide, namely 0, 1, 2 and 3 percent (W/W), were made from pistachio (Pista...
M R M Farahani,S Pourabdollah


Economic and Alternative Preservative Research with an Overview of its Impact on the Dynamics of Wood Tie Markets and Railroads
2019 - IRG/WP 19-30751
This presentation will discuss the Railway Tie Association’s (RTA) efforts in economic research for the North American wood tie industry, along with decades-long research into improving wood preservation processes and its resulting economic impact for railroads. Ongoing research is continuing to expand the knowledge-base by comparing existing standard creosote (C) and borate-creosote (B-C) dual...
J C Gauntt


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Effect of pretreatment of wood surfaces with a copper monoethanolamine solution on the natural weathering performance of semitransparent stains
2019 - IRG/WP 19-40881
Semitransparent stains for wood products are favored for outdoor applications in Japan because these finishes do not hide the wood grain. However, the photoprotective effects of wood surfaces are low, therefor there is a need to improve the weathering performance. We examined the natural weathering performance of semitransparent stains on wood pretreated with a copper monoethanolamine solution (Cu...
S Isaji, H Shibui, Y Hirabayashi


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Treatability of South African-grown Eucalyptus grandis with water-borne copper azole and disodium octaborate tetrahydrate wood preservatives
2021 - IRG/WP 21-40920
This study investigated the treatability of the sapwood and heartwood of sawn Eucalyptus grandis with copper-azole (CuAz) and disodium octaborate tetrahydrate (DOT) water-borne preservatives towards improving its durability for enhanced use in structural solid wood applications. The results obtained showed that, at a moisture content of 12 ± 1%, sawn E. grandis sapwood can be impregnated to a mea...
A A Alade, Z Naghizadeh, C B Wessels


Evaluation of Decay Resistance of Copper-based Preservatives Treated-Wood exposed to different field test sites in Korea
2022 - IRG/WP 22-20679
In Korea, preservative treated wood is required to have a stamp on the surface which contains information such as wood species, use categories, and the company that treated the wood. Such stamping is necessary to safely and appropriately use the treated wood. Since majority of treated wood is being used outdoor environment, the treated wood must have efficacy against wood decay fungi or termite. I...
W-J Hwang, S-M Yoon, Y Park, Y-S Choi, H-M Lee, J-W Kim


Measurement of copper concentration in Cu-HDO treating solutions by handheld XRF
2022 - IRG/WP 22-20685
Copper based preservatives diluted in water dominate the wood preservative industry around the world. Periodically measurements and adjustments of the concentration of treating solutions must be performed as a part of the quality control at the treatment plant to achieve desired quality of the preservative treated wood. Many analytical methods are time consuming and must be performed under laborat...
P O Flaete


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


Analysis of wooden shingles after seven years of exposure
2022 - IRG/WP 22-20690
Wood is a traditional roofing material in the Alpine regions. In the 17th century, wooden roofing was typically used on more important buildings. Still, today it is predominately used on huts and houses in the hilly regions of northern and north-western Slovenia. Because wooden roofing is expensive, we investigated the possibility of extending the service life of the roofing through impregnation a...
M Humar, B Lesar, D Kržišnik, E Keržič, B Jemec


Brief introduction to a research project on preparations of various paste formulations from boron, fluoride and copper for supplemental treatments
2022 - IRG/WP 22-30759
Wood preservatives to be used for supplemental purposes are present in various forms such as powders, liquids, rods, pastes, or gels. Boron compounds have been receiving a lot of attention in supplemental treatments since they have good mobility in wood. Application of boron compounds via internal treatments is vital to stop decay to be occurred inside the wood since large wood elements are too th...
E E Soytürk, D Bakır, E Terzi, C Köse, S N Kartal


Copper Naphthenate – A Data and Capability Update
2022 - IRG/WP 22-30771
The efficacy of copper naphthenate against wood decay fungi and wood destroying organisms has been well documented from international field tests as well as decades of commercial service. The use of copper naphthenate has been dramatically expanded due to its proven performance, non-restricted use, minimal environmental impact, and superior end of life options. Extensive demand and interest has al...
J-W Kim, J D Lloyd


Comparative study of the properties of silicate coatings with different mineral pigments (titanium dioxide, iron (III) oxide, copper (II) oxide) on the surface of wood
2022 - IRG/WP 22-40936
Silicate coatings are attractive alternatives to conventional organic-based coatings for wood protection. In this work, silicate coatings were prepared with a potassium silicate binder modified with a methyl siliconate solution, and three types of mineral pigments titanium dioxide, iron (III) oxide and copper (II) oxide. The coatings were applied on beech wood and cured under ambient conditions. T...
A M Cheumani Yona, M Petrič


Long-term Performance of Treated Timbers in a Sub-tropical Marine Exposure
2023 - IRG/WP 23-11015
The long-term performance of preservative-treated and modified wood in marine exposures was assessed in Brisbane, Queensland, Australia. This report describes the final destructive assessment of the surviving Australian panels after 11 years of exposure. This site presents the potential for attack by shipworms (likely Bankia spp.), pholads (Martesia striata), Limnoria and Sphaeroma terebrans. Mos...
E L Galore, J Norton, A Zahora


Virtual Reality of Wood Protection
2023 - IRG/WP 23-20698
Virtual reality (VR) is a technology that allows people to explore and interact with computer generated environments using devices that stimulate different senses (sight, sound and touch). VR is mainly used for education, training and entertainment, but it also has the potential to provide new insights into scientific phenomena. In this paper we describe the evolution of VR and its many uses, focu...
D Feng, Y Liu, M Turner, A Limaye, P D Evans


Sensitivity of copper indicators for detecting preservative penetration
2023 - IRG/WP 23-20701
Chrome azurol S (CAS), 1-(2-pyridylazo)-2-naphthol (PAN), and rubeanic acid (RA) are the three copper indicators currently used by the timber industry to assess preservative penetration. Although only the American Wood Protection Association (AWPA) standards specify indicator sensitivity, it is unclear how those limits were developed. The sensitivity of each copper indicator was determined in solu...
T Yi, J Norton, S Meldrum, J J Morrell


A six-year ground proximity trial of TRU-CORE treatments at Innisfail, Queensland
2023 - IRG/WP 23-30775
This article describes an H3 (above ground outdoor) ground proximity field trial that compares the performance against decay fungi of TRU-CORE (also known as the Buffered Amine Oxide Enhancement System) Copper Quat (CQ) with CCA and commodity Alkaline Copper Quat (commodity-CQ) treatments, all in Pinus radiata. The retentions achieved reflected commercial practice, where higher mean retentions are...
L Cookson


Challenges in managing very long-term field tests
2023 - IRG/WP 23-30779
Field testing of wood preservatives has been on-going in Petawawa, Ontario, Canada since at least 1937. Many of the treated roundwood posts from these early experiments are still in test, and include preservatives still used today, including creosote, copper naphthenate, pentachlorophenol and CCA. Performance data from selected experiments more than 50 years old are reported and we discuss some of...
R Stirling, D Wong


Establishing the minimum effective penetration of wood preservatives in the refractory heartwood of E. nitens
2023 - IRG/WP 23-30780
Conventional pressure treatment of many Australian hardwoods results in little to no penetration of heartwood and a non-uniform envelope treatment of <5 mm surrounding a mostly untreated core. This is a major issue for many of the low durability plantation hardwood timbers that are grown in Tasmania, which contain high percentages of heartwood. Long term studies on softwoods such as spruce decking...
J R Vargas, J J Morrell, L Yermán, K C Wood


Through-boring to improve the performance of low durability Eucalyptus species for utility poles: 10-year field test results of pole stubs exposed in Southeast Queensland
2023 - IRG/WP 23-40972
An impending shortage of naturally durable hardwood electricity pole timbers in Australia has encouraged investigation of alternatives containing less durable, untreatable heartwood. Through-boring or drilling holes perpendicular to the long axis before treatment, has been used successfully on refractory softwood poles in North America and might have application in Australia. The use of through-bo...
J Norton, L P Francis, J J Morrell


X-ray fluorescence microscopy of copper ion distribution in decay of copper-treated wood by Fibroporia radiculosa
2024 - IRG/WP 24-11047
Copper is an essential metal ion for eukaryotic life and must strictly be regulated as excess levels can cause oxidative damage, enzyme inhibition and denaturation, interruptions in nutrient transport and even cellular death. Copper-based wood treatments have efficacy against a wide range of biological organisms including decay fungi and are used in the majority of preservative formulations for ou...
K M Ohno, J Jakes, A B Bishell, L Li, Q Jin, E Maxey


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