Your search resulted in 722 documents. Displaying 25 entries per page.
Environmental Fate of Micronized Copper
2015 - IRG/WP 15-50310
The environmental fate of wood preservatives is an important aspect to estimate the health and environmental impact. Although biocides from treated wood may be released into the soil, water or air, the latter pathway is frequently neglected in favour of leaching studies. Nonetheless, wood dust is well known to cause a variety of adverse health effects, in particular diseases to the respiratory tra...
C Civardi, L Schlagenhauf, J Benz, C Hirsch, J Van den Bulcke, M Schubert, J Van Acker, P Wick,
Recycling of used railroad ties via two-staged pyrolysis for fractionation of wood preservatives and bio-oil: pyrolytic characterization by TGA and Py-GC/MS
2015 - IRG/WP 15-50311
Creosote and copper naphthenate (CuNap) (in an oil carrier) treated railroad tie materials (crossties or sleepers) were initially heat-treated at 200 – 300 oC and subsequently pyrolyzed via thermogravimetric analysis (TGA) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) to recover wood preservatives and produce a higher quality bio-oil. Preservative-desorptive temperatures at 200 a...
Pyoungchung Kim, J Lloyd, Jae-Woo Kim, N Labbe
Effect of exposure site on metal migration from copper azole, alkaline copper quat or chromated copper arsenate treated southern pine decking
2015 - IRG/WP 15-50313
Metal migration from chromated copper arsenate, copper azole or alkaline copper quaternary compound treated southern pine lumber was assessed at sites in Mississippi and Oregon. Metal levels tended to be consistently higher in decks exposed in Mississippi. Rainfall characteristics did differ slightly at the two sites, but the levels did not appear to be of a magnitude that might affect metal mobi...
J J Morrell, H M Barnes
The copper-transporting ATPase pump and its potential role in copper-tolerance
2016 - IRG/WP 16-10859
Copper-tolerant brown-rot decay fungi exploit intricate mechanisms to neutralize the efficacy of copper-containing preservative formulations. The production and accumulation of oxalate is the most widely recognized theory regarding the mechanism of copper-tolerance in these fungi. The role of oxalate, however, may be only one part of a series of necessary components required for this complex mecha...
K M Ohno, C A Clausen, F Green III, G Stanosz
Release of Copper from Pressure Treated Wood
2016 - IRG/WP 16-20584
Micronized copper based wood preservatives including micronized copper quat (MCQ) and micronized copper azole (MCA) have been introduced commercially to the North American market since 2006 as alternatives to alkaline copper quat (ACQ) or soluble copper azole (CA) preservatives. Unlike ACQ or CA, MCQ and MCA use dispersed particulate copper particles rather than soluble ionic copper to make treat...
Jun Zhang, J Horton
Distribution and penetration of the tung oil in wood studied by high-resolution magnetic resonance imaging
2016 - IRG/WP 16-20593
Water repellents as environment-friendly treatments are gaining their popularity as non-biocidal solutions for wood protection. One of the most important water repellents for wood besides waxes and organosilicon compounds are drying oils. Tung oil is one of the best performing oil. However, tung oil, similarly as other oils, does not penetrate deeply into wood, due to its high viscosity. In order...
M Žlahtič, U Mikac, I Serša, M Merela, M Humar
Performance of copper treated poles and posts after three to fifteen years of exposure
2016 - IRG/WP 16-20595
Copper based wood preservatives are one of the most important wood preservatives for heavy-duty applications. Wood treated with copper-based preservatives performs excellent if applied according to preservative specifications. If used improperly premature failures might appear. In order to elucidate properties of copper treated wood in use, utility poles and posts treated with copper-based preserv...
M Humar, N Thaler
Moisture monitoring in WW2 partisan hospital Franja
2016 - IRG/WP 16-20596
Material climate of wood used for construction of WW2 Partisan hospital Franja was monitored for approximately one year. Partisan hospital is located in the bottom of tiny gorge Pasice in Slovenia. Hence, wood moisture content on eight respective location and wood temperature was determined twice per day with Scanntronik equipment Gigamodul and Thermofox. The results clearly showed that despite of...
M Humar, N Thaler, B Lesar, A Žagar
Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick
A Comparison on Penetration of Silica Sol in Scots pine and Southern pine wood
2016 - IRG/WP 16-40722
Penetration is one of the most important issues to be considered in wood impregnation with various kinds of chemicals in liquid form. Scots pine (Pinus sylvestris) and Southern pine (Pinus spp.) are two frequently used wood species for treatment, such as preservative treatment. With the development of treating systems, some micro- or nano-sized aqueous modifiers are emerging in the market, which p...
Mingyang Sun, Jinzhen Cao
Impregnation of railway sleepers - Pressure gradient and transversal penetration
2016 - IRG/WP 16-40731
Based on the possible ban of creosote in the future, the need for oil based alternative products has gained in importance. Due to possible differences in impregnation properties compared to creosote the need for re-implementing former technology is given, to determine if momentarily used impregnation processes have to be modified. The here reported tests measure the pressure gradient during the im...
M Starck, A Gellerich, H Militz
Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs
Untreated and copper-treated wood soaked in sodium oxalate: Effects of decay by copper-tolerant and copper-sensitive fungi
2017 - IRG/WP 17-10888
Copper is widely used as the primary component in wood protectants because it demonstrates a broad range of biocidal properties. However, a key concern with using copper in wood preservative formulations is the possibility for brown-rot basidiomycetes to resist the toxic effect. Many brown-rot basidiomycetes have evolved mechanisms, like the production and accumulation of oxalate, which helps thes...
K M Ohno, G T Kirker, A B Bishell, C A Clausen
Evaluation of Particulate Materials as a Physical Barrier against Termites under Floor of Experiment House
2017 - IRG/WP 17-10900
In Japan, the damages by the subterranean termites (Coptotermes formosanus and Reticulitermes speratus) are more common. Recently the more attention is paid to the less- or non-chemical methods for termite control. As a non-chemical treatment, physical barriers using particles such as gravels were investigated in terms of environmental safety, cost effectiveness, and duration of performance, and t...
Y Yanase, Y Fujiwara, Y Fujii, T Mori, T Yoshimura, S Doi
Quality of the impregnated wood in the Slovenian hardware stores
2017 - IRG/WP 17-20606
Ten different samples from Slovenian hardware stores were analysed. Samples were treated with copper based wood preservatives and designed and advertised to be used in heavy duty applications in use classes 3.2 or 4. In order to determine the quality of the treatment penetration, retention and fungicidal properties were determined. Retention was determined with XRF analysis, while modified EN 113 ...
M Humar, B Lesar, N Thaler, D Kržišnik, N Kregar, S Drnovšek
Activity of Two Strobilurin Fungicides Against Three Species of Decay Fungi in Agar Plate Tests
2017 - IRG/WP 17-30704
The objective of this study was to examine the toxicity of strobilurin fungicides against wood decay fungi in order to assess their potential to act as a co-biocide for copper-based wood protection. Two strobilurin fungicides, Heritage (50% azoxystrobin active ingredient) and Insignia (20% pyraclostrobin active ingredients), and copper sulfate pentahydrate were tested against one white rot fungus...
J D Tang, T Ciaramitaro, M Tomaso-Peterson, S V Diehl
Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris
Effect of Particle Size on Wax Distribution in Paraffin Wax Emulsion Impregnated Wood
2017 - IRG/WP 17-40779
Paraffin wax emulsion impregnation has been a common eco-friendly approach for improving water repellency of wood. In this study, southern pine (Pinus spp.) and Scots pine (Pinus sylvesteris L.) samples were impregnated with paraffin wax emulsions of different solid contents and particle sizes, and then the time domain nuclear magnetic resonance (TD-NMR) was used to elucidate the influence of part...
Wang Wang, Jinzhen Cao, Yiheng Huang
Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang
Treatability of beechwood railway sleepers with potential creosote substitutes
2017 - IRG/WP 17-40790
Maintenance of an efficient railway infrastructure still requires the use of wooden railway sleepers, particularly because wooden sleepers have more favourable properties for intensified vibrations than concrete or steel sleepers. Creosote, used for decades for the impregnation of railway sleepers, will possibly no longer be available for this application due to European legislation. This reveals ...
N Pfabigan, E Habla, R Gründlinger
In-service performance of treated plywood bridge decks in Australia
2017 - IRG/WP 17-40794
Engineered wood products have a long history of use in bridge construction in Australia. The first bridges incorporating chemically protected engineered wood components were installed in the 1850’s and some survive to this day. Preservative treated plywood bridge deck panels have been employed since the 1980’s as a replacement for the more traditional hardwood plank decks. This paper report...
M A Powell
Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd
Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor
Penetration behaviour of different hydrophobic carrier substances for oily wood preservatives in Beech and Scots pine sapwood
2017 - IRG/WP 17-40804
The use of creosote as a wood preservative has a long history. Current areas of application are railway sleepers, transmission poles, timber bridges and marine applications. If the approval for creosote will not be prolonged, alternative wood preservatives will be needed. As the penetration behaviour after pressure impregnation of different alternative oily products in this fields of application i...
M Starck, A Gellerich, H Militz
A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel