IRG Documents Database and Compendium


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Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos


The non-uniform uptake of chromium and copper during the impregnation of wood using the example of a CCB-salt
1998 - IRG/WP 98-20137
The correct impregnation of wood requires among other things a regular control of the concentration of the treating solution as this and/or its stoichometric composition can change as a result of the impregna-tion process and the treated wood. The preferential uptake of individual wood preservative components by the wood is of particular importance in this connection. Dipping and vacuum impregnat...
P Jüngel, E Melcher, R-D Peek


Solvent extraction of CCA-C from out-of-service wood
1998 - IRG/WP 98-50107
Elimination of CCA from decommissioned wood prior to disposal is a major environmental issue. One approach is to extract CCA from treated wood, then reuse the 'clean' (may contain CCA, but below hazardous level) wood materials for manufacturing wood-based composites. In the present paper, we focus on effective leaching processes, selection of leaching agents and optimum leaching ...
K M F Kazi, P A Cooper


Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils. A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens


The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren


Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden


Isolation of soil borne bacteria and fungi from treated timber
2001 - IRG/WP 01-50174
Most research in the last few decades has focused on the development of new strategies to control biological attack and the means to quantify this. Comparatively little work has been done to examine the effect that treated timber might have on its surrounding environment. This presentation will describe a methodology that attempts to detect any changes which might occur in the soil microflora foll...
I Stephan, A Stegemann, G Heidrich


Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 21: Report of eighth inspection (7 years) in Australia
1985 - IRG/WP 4119
This report tabulates the seven year (86 month) inspection results, obtained on 28 Fabruary l985, of the IRG/COIPM International Marine Test at Goat Island, Australia. This test was installed in December 1977. The results are given in Tables 1-6. Table 7 lists the number of marine borers identified from blocks (2 cm and 6 cm long respectively) cut from the ends of specimens removed at the previous...
L J Cookson, J E Barnacle


Chlorothalonil: A new ground contact wood preservative
1992 - IRG/WP 92-3712
Extensive investigations have been conducted in recent years on the performance of chlorothalonil (tetrachloroisophthalonitrile) as a ground contact wood preservative. Efficacy information is presented on a soil block test with 11 Basidiomycetes, a fungus cellar evaluation, above-ground field testing against termites in Australia and Hawaii, and ground-contact field stakes installed in Florida (9 ...
P E Laks, T L Woods


Volatile organic compounds (VOC) measured during drying of impregnated timber
2004 - IRG/WP 04-50216
Discussion about drying of impregnated timber has taken place in the Nordic countries under eighties and nineties and goes on nowadays. The drying increase the value of production and the customer gets fewer problems when handles the timber. This introduces a positive attitude to the impregnation as a process and its products. Beside the important information about the advantages of impregnated ti...
N Terziev, V Djokic


Preservative treatment and field test monitoring of spruce pole stock: Pressure and diffusible chemical treatments
1990 - IRG/WP 3605
One hundred and forty four spruce (test species) and southern yellow pine (reference species) poles were variously treated by center boring, incising, or kerfing, followed by pressure treatment with CCA and/or diffusible preservatives. The diffusible preservatives included NaF/creosote, borax and ammonium bifluoride. The poles were set at a test site and evaluated for preservative distribution and...
B Goodell, A J Pendlebury


Microbial decomposition of salt treated wood
1993 - IRG/WP 93-50001-22
Specialized microorganisms which are able to convert fixed inorganic preservatives from treated wood into water soluble components are investigated. A number of brown rot fungi like Antrodia vaillantii have been isolated from cases of damage and examined under unsterile conditions with CCA-, CCB-, CCF- and CC-treated wood at retention levels of at least 50% higher than recommended for wood in grou...
R-D Peek, I Stephan, H Leithoff


Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe


Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg


Preservative-efficacy of boric acid-triethanol amine solution against wood-decay fungi
1994 - IRG/WP 94-30050
Laboratory preservative-efficacy tests were conducted using boric acid-triethanol amine (BTEA) solution in accordance with the JIS A 9201 (1991) test method excluding the standard weathering process. Sapwood specimens of Picea jezoensis or Fagus crenata to achieve nominal retentions of 0.40-41.2 kg/m³ of boric acid were exposed to Tyromyces palustris, Coriolus versicolor, Serpula lacrymans or Cha...
S Doi, M Mori, Y Mineki


Laboratory aquaria evaluation of CDDC (copper dimethyldithiocarbamate) against marine borers
1998 - IRG/WP 98-10262
The performance of CDDC (copper dimethyldithiocarbamate) and CCA (copper chrome arsenic) treated timber blocks was examined in a 1.5 year aquaria bioassay against the marine borers Limnoria tripunctata Menzies and Lyrodus pedicellatus (Quatrefages). Three timbers, southern yellow pine (SYP), Pinus radiata D. Don and Eucalyptus regnans F. Muell were treated with CDDC to retentions of 16, 32, 48 and...
L J Cookson, C R McIntyre, D Scown


Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek


A laboratory technique to measure the performance of preservative treated hardwoods in ground contact
1982 - IRG/WP 2172
A laboratory technique to measure the performance of preservative treated timber in ground contact is described. It uses partially sealed blocks of timber which are treated, leached and sawn into small stakelets for soil exposure in a fungal cellar. Performance is monitored by the loss of static bending strength with time, and a simple apparatus for measuring the deflection of a stakelet under a l...
E F Baines


Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz


Preservative ability of wood to be fixed hydroxyl apatite substituted for antimicrobial metals
2001 - IRG/WP 01-30272
We succeeded in forming hydroxy apatite (HAp) in wood. HAp is non-toxicity and safe. Preservative ability of the wood, which substituted one part of Ca of constituent element of this HA p for antibacterial metals was measured. When Ca was substituted for Ag or Zn, mass loss in decay by brown-rot fungus F. palustris was restrained in about 50% (Ag) ~30% (Zn) of value of control specimen. However, w...
Y Haruhiko, I Sumaru


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


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