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A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


Stake test with ammoniacal copper in combination with different agents started in 1962
1997 - IRG/WP 97-30130
In 1962 a stake test was started with ammoniacal copper in combination with chromium, arsenic, pentachlorophenol, boron, salicylic acid, benzoic acid, sorbic acid, pyridine and tannin. Different concentrations of the copper component were used as well as the added agents. For each concentration and test site, ten stakes of Pinus sylvestris L. sapwood were treated. The stakes were set out at two te...
B Häger, Ö Bergman


The content and mobility of copper, chromium and arsenic in the soil of a wood preserving plant using CCA
1998 - IRG/WP 98-50122
Analyses were carried out on soil and water samples obtained from a wood preserving plant using CCA-type preservatives. The plant has been in operation since 1969. The soil samples were obtained on 8 points from 4 different depths. The estimation of the type of soil was followed by investigations of copper, chromium and arsenic contents, and the mobility of these elements. The soil samples were al...
N Erdin, S N Kartal, A Dilek Dogu, M O Engür


Performance of groundline bandage remedial treatments in western US species transmission poles
1993 - IRG/WP 93-30019
Groundline bandages are an important element in remedial treatment strategies for utility poles in the United States. Several bandages containing new or reformulated components have recently been developed but have not been adequately tested. This paper reports on the degree of diffusion of copper naphthenate, boron, and sodium fluoride from groundline bandages into pressuretreated Douglas-fir, po...
P G Forsyth, J J Morrell


Comments on leaching in view of accelerated testing
1977 - IRG/WP 294
We developed an accelerated test for leaching at elevated temperatures (75-85°C). This test was used for the examination of 11 preservative formulations containing Cu, Zn and As. The data obtained from these experiments were compared with data on some formulations tested by ASTM standard leaching test. The method consists in making a large surface to volume ratio of wood from a treated block by c...
J Rak


A comparison of analytical techniques
1995 - IRG/WP 95-20061
This paper compares carefully-controlled weight retentions and analysis by XRF, ICP, combustion methods and a new extraction procedure for the new preservative, Copper(II) Dimethyldithiocarbamate (CDDC). Various experimental parameters such as particle size and drying conditions were investigated. In general, the correlations between and among the procedures are very high. The extraction-colorimet...
A C Gallacher, C R McIntyre, M H Freeman, D K Stokes, W B Smith


Preservative treatment of green timber by soaking in ammoniacal copper borate
1984 - IRG/WP 3292
Freshly sawn boards of radiata pine sapwood were preservative treated by soaking in ammoniacal copper borate. Optimum schedules were obtained by partially seasoning the boards for one week prior to treatment. This aided the absorption of preservative and reduced the required soaking time to approximately 2 hours. Complete boron penetration was obtained after one week of block storage under cover a...
P Vinden, A J McQuire


Microdistribution of Copper in Copper-Ethanolamine (Cu-EA) Treated Southern Yellow Pine (Pinus spp.) related to density distribution
2004 - IRG/WP 04-40270
The relationship between copper absorption and density distribution in wood cell walls was investigated in this study. The density distribution on layer level was obtained from two approaches: (1) calculation by using data obtained from literature; (2) microdistribution of carbon and oxygen atoms in the wood cell. The microdistribution of carbon and oxygen in untreated southern yellow pine (Pinus ...
Jinzhen Cao, D P Kamdem, E Pasek


Effect of treatment process on performance of copper-chrome-arsenate. Part 1: Fungus cellar tests
1995 - IRG/WP 95-40045
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation, fungus cellar stakelets, 5 x 10 x 180 mm³ were cut from treated material and after leaching were exposed in unsterile soil beds in ...
M E Hedley, J Anderson, J B Foster, B E Patterson


Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Management strategies for the disposal of CCA-treated wood
2000 - IRG/WP 00-50155
A two-fold management strategy is presented for the disposal of wood treated with chromated copper arsenate (CCA). The first part focuses on the use of alternative wood treatment preservatives. The second part of the management strategy addresses short-term disposal issues (less than 25 years) by developing new methods to handle the waste. A set of seven alternative wood preservatives were evaluat...
H M Solo-Gabriele, T G Townsend


Reappraisal of some fungicides by the amended JWPA method
1992 - IRG/WP 92-3689
Organoiodine compounds which have been commercialized these years in Japan poorly performed as fungicides in the amended JWPA decay test (Standard 1, 1989) when applied to superficial treatment of timber. Because some parts of active ingredients seemed to disappear from the treated timber surface mainly due to the severe leaching cycles. This was prominently true for beech (Fagus crenata Blume) sa...
K Tsunoda


The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


Determination of bis-(N-cyclohexyl-diazeniumdioxy)-copper in different matrices by photometer, thermal energy analyzer and HPLC
1999 - IRG/WP 99-20179
For the quantitative analysis of bis (N-cyclohexyl-diazeniumdioxy)-copper (Cu-HDO) three analytical methods are used. The employment of the different methods depends on the matrices involved. For several years now, the colorimetric determination of Cu-HDO by photometer has been applied to solutions and concentrates of wood preservatives. In principle, the technique consists of a quantitative conve...
J Wittenzellner, W Hettler, M Maier


Working plan: Second international collaborative field trial
1995 - IRG/WP 95-20056
This paper describes the scope, objectives, and approaches to be used in the second international collaborative field trial approved by the Scientific Programme Committee for partial funding in 1994. The trial is designed to develop a broad data base on causal mechanisms, interactions, and factor affecting the performance of treated wood in ground contact. The trial encompasses 12 different field ...
H M Barnes, T L Amburgey


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


A comparison of the leaching resistance of copper 2-ethanolamine and copper ethylenediamine treated Scots pine
2000 - IRG/WP 00-30233
The depletion of copper from copper 2-ethanolamine and copper ethylenediamine treated Scots pine blocks was investigated. A greater leaching resistance was found for copper 2-ethanolamine, which retained ca. 86% and ca. 50% copper after water and buffer leaching, respectively. Leached amine treated blocks also contained significant residual amine. This was consistent with other observations linked...
Xiao Jiang, J N R Ruddick


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Comments on soft rot attack in timbers treated with CCA preservatives: A document for discussion
1982 - IRG/WP 1167
This paper is not based on any particular results but rather on several observations of soft-rot during many years of studies, and on a review of the existing literature. The short time available has unfortunately not permitted a detailed review of the literature. Data and knowledge of important facts are lacking for several aspects of soft-rot attack and for reactions occurring in the wood as a r...
T Nilsson


Some fundamental thoughts on the prediction of field performance from lab-testing based on comparison of lab and field test results of some copper-free materials
2003 - IRG/WP 03-20269
In the paper results from lab testing (ENV 807 and EN 113) are compared with field results (EN 252) of differently treated wood. Depending on the type of the organic biocide containing material and depending on type of soil and type of decay differences were found in suitability of the lab methods to predict field performance. The attempt is made to interpret the found differences. Furthermore it ...
A O Rapp, U Augusta


Evaluation of the protective means of some wood preservatives by means of accelerated tests
1973 - IRG/WP 232
In site conditions of the eastern site in the forest-steppe part of the Krasnovarsk region, the relative effectiveness of a series of wood preservatives was obtained by means of field tests. To obtain a more accurate evaluation of the protective qualities of these accelerated tests were carried out in laboratory conditions. In 9 boxes filled with non-sterile soil taken from the site, 72 samples of...
I A Petrenko


The effect of acid rain on CCA treated timber
1990 - IRG/WP 3579
The effect of acid precipitation on the leaching of copper, chromium and arsenic from timber treated with different CCA preservatives was studied in the presence of three types of soil under simulated field conditions. Pine sapwood, embedded in soil, was subjected to simulated rainfall at three different levels of acidity. The CCA preservative formulations tested were:- American Wood Preservers&am...
R J Murphy, D J Dickinson


Biological resistance of electrolessly plated wood (1). Preliminary report
1994 - IRG/WP 94-40024
Surface metal coating is considered to improve biological resistance of wood as some metal ions are fungitoxic. Six wood species (three softwoods: Cryptomeria japonica, Tsuga heterophylla and Larix spp; three hardwoods: Fagus crenata, Acer mono and Betula platyphylla) were electrolessly plated with nickel or copper, and those were served for laboratory evaluation of their resistance against decay ...
M Hasegawa, K Tsunoda, T Yoshimura


The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray


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