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Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Preservative treatment of Golla cane (Daemonorops jenkinsiana) by pressure process
2007 - IRG/WP 07-40379
The feasibility of preservative treatment of golla cane (Daemonorops jenkinsiana (Griff) Mart). by pressure process has been studied using water borne preservatives CCB (copper-chrome-boron). Cane samples of three different lengths 1m, 2m and 3 m. were treated at different pressure and time period to evaluate the extent of penetration and retention of preservative chemicals. It was observed that t...
K Akhter, M Hoque Chowdhury


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Eucalyptus saligna and Acacia mearnsii
2007 - IRG/WP 07-40383
Penetration, retention, and leaching of CCA (C) in relation to grain orientation were tested in small (50mm x 50mm x 200mm) sapwood and heartwood samples of Eucalyptus saligna and Acacia mearnsii. In both sapwood and heartwood of the two species, the results showed a consistent pattern: Transverse > Radial > Tangential. Whereas penetration, retention, and leaching were significantly high i...
R Venkatasamy


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Cupressus lusitanica and Pinus patula
2007 - IRG/WP 07-40384
The influence of grain orientation on penetration, retention, and leaching of CCA (C) was tested on small samples of sapwood and heartwood of Cupressus lusitanica and Pinus patula. Samples measuring 50mm x 50mm, and 200mm in the longitudinal axis were sealed to expose only transverse, or radial, or tangential faces, pressure treated with 6% CCA (C), and penetration, retention and leaching of the ...
R Venkatasamy


Copper fixation in ACQ-D treated Chinese fir at various temperature and relative humidity conditions
2007 - IRG/WP 07-30436
In this study, the effect of different conditions of temperature, relative humidity, and duration of post-treatments on accelerating copper fixation in ACQ-D treated Chinese fir wood blocks was investigated. The conditions include the combination of three temperatures (21, 50, and 70?) and two relative humidity levels (20% and 80%), also include four temperatures (50, 70, 90, and 110?) without con...
Jinzhen Cao, Lili Yu


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


Effect of barriers on moisture content of treated and non-treated utility poles
2007 - IRG/WP 07-40369
The potential for non-biocidal barriers to slow moisture sorption was investigated using butt treated western redcedar poles immersed in either water or moist soil over a 2 year period. Moisture sorption was initially slowed by the barriers, but openings at the bottoms of the barriers eventually allowed moisture to migrate upward. Moisture levels in wrapped poles eventually reached those found in...
C S Love, J J Morrell


The Role of Moisture Content in Above-ground Leaching
2007 - IRG/WP 07-50245
This paper reviews previous reports on the moisture content of wood exposed above ground and compares those values to moisture contents obtained using simulated rainfall and immersion methods. Laboratory leaching trials with CCA-treated specimens were also conducted and the results compared to published values for leaching of CCA-treated specimens exposed above ground outdoors. Previous researcher...
S Lebow, P Lebow


Durability of timber from exotic species against termite attack in Indian conditions
2007 - IRG/WP 07-10629
Exotic trees species, Acacia mangium Willd. and A. auriculiformis A. Cunn. ex Benth. and their hybrid are widely grown in India for multiple uses including use as timber. It is essential to know the natural durability of timbers against termites for predicting the service life of the timber and deciding on the application of preservatives to enhance the durability. Studies were conducted to test t...
O K Remadevi, R Muthukrishnan


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai


Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating. Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi


Relationship between coating properties and their performance on treated wooden decks
2008 - IRG/WP 08-30454
Preservative treated wood benefits from the application of a surface coating to protect it from weathering (UV and rain). Different preservative formulations may affect surface properties of treated wood differently; therefore compatibility of coatings with different preservative treated wood types should be considered. This paper examines coatings characteristics and their weathering performance ...
M Ahmadinejad, P A Cooper


Field Trial of Copper Treated Moso Bamboo in Southern China
2008 - IRG/WP 08-30455
The field trial of moso bamboo treated by 9 copper preservatives for 5 years in Guangzhou was conducted in the paper. The result shown that: two ammonia based copper azole formulations F17/F18 and 1 amine copper formulation with boron F10, as well as 2 ammonia based ACQ, at the copper retention of 3.2 kg/m3 or above, have good resistant for decay and fine resistant for termites after 5 year field ...
Mingliang Jiang


Preliminary evaluation of efficacy of copper in combination with boron and NHA (N'-N-(1, 8-naphthalyl) hydroxylamine) against wood decay
2008 - IRG/WP 08-30452
In this study, efficacy of various combinations of copper sulfate with either boric acid or calcium precipitating agent, NHA-Na (N'-N-(1, 8-naphthalyl) hydroxylamine) was evaluated. Wood specimens were treated with either 1%, 0.5%, or 0.1% concentrations of copper sulfate, boric acid, NHA-Na, copper sulfate + boric acid, or copper sulfate + NHA-Na mixtures. Treated specimens were subjecte...
E Terzi, C Köse, S N Kartal


Field Stake Tests with Copper-based Preservatives
2008 - IRG/WP 08-30459
The performance of field test stakes derived from commercially produced ground contact retention copper quat preservatives based on either soluble copper complexed with ethanolamine, or from a water-based suspension of particulate micronized copper compounds, as well as untreated southern yellow pine controls, is compared at two decay test sites. After less than one year in field test some of t...
A Preston, L Jin, D Nicholas, A Zahora, P Walcheski, K Archer, T Schultz


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Depletion and Redistribution of Boron in Bundles of Commercially Treated Lumber Exposed to Artificial and Natural Rainfall
2008 - IRG/WP 08-30474
The depletion and redistribution of boron from stacks of Southern Yellow Pine lumber pressure treated with disodium octaborate tetrahydrate (DOT) and exposed to artificial and natural rainfall was examined. When the lumber was exposed to periodic simulated rainfall, 5.7-8.1% of the measured boron present leached from the lumber after exposure to over 300 mm of rainfall. In tests which exposed bo...
M E Mankowski, M J Manning


Micro-Distribution of Micronized Copper in Southern Pine
2008 - IRG/WP 08-30479
For copper-based preservatives to be used in ground contact, penetration of copper into the cell wall is believed to be important to protect the wood from soft rot fungi. Preservatives containing soluble copper are known to do this. It is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control soft rot decay. An AWPA st...
R Stirling, J Drummond, Jun Zhang, R J Ziobro


Accelerated fixation of ACQ-D treated Chinese fir with different post-treatments
2008 - IRG/WP 08-40400
With the enhanced focus on the environmental impact of the preservative-treated wood in recent years, it is necessary to perform some post treatments to prevent contamination of soil and ground water and reduce copper losses from ACQ treated wood in service. In this study, the potential of hot air, hot water, steaming and microwave post treatments to accelerate the fixation of copper in ACQ-D trea...
Lili Yu, Jinzhen Cao, P A Cooper


Effects of Murgul Copper Process flue gases (SO2) on compression strength parallel to the grain of Beech (Fagus orientalis Lipsky.) wood
2008 - IRG/WP 08-40404
In this study was investigated the effect on the compression strength parallel to the grain as mechanical properties of Fagus orientalis Lipsky. wood exposed to SO2 gas and non-exposed. In the experiments the two of four (total) were obtained from Artvin-Ortaköy region and the other two from Artvin-Murgul region. The compression strength parallel to the grain was calculated at the compare of ...
N Ay, E Topaloglu, A Uncu


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


The effect of treatments in boron steaming medium on boron leaching and strength properties of wood
2008 - IRG/WP 08-40409
The combined effect of boric acid impregnation together with boron steaming and steaming heat treatments were evaluated in this study. Boric acid pre-treated wood samples and untreated ones subjected to steaming heat and direct steaming treatment in a close reactor at 13 bar pressure and 180 ºC for 30 minutes. Compression strength parallel to grain of wood samples, leaching test and pH measuremen...
E D Tomak, Ü C Yildiz, S Yildiz, E Pesman


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