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Copper based water-borne preservatives: The use of a thin section technique to compare the protection of wood by copper based preservatives against soft-rot and bacterial decay
1987 - IRG/WP 2286
This paper describes the techniques developed and gives examples of results obtained for the performance of copper based wood preservatives against both the bacterial and fungal hazards....
A M Wyles, D J Dickinson


Lignin-copper, a new wood preservative without arsenic and chromium
1992 - IRG/WP 92-3702
A more environmentally sound treatment for wood with preservatives containing no arsenic or chromium, has been developed and studied on a laboratory scale. The method involves a first step impregnation with an aqueous solution containing modified, water-soluble kraft lignin followed by a second step involving impregnation with a copper salt solution to give fixation of the lignin into a water-inso...
B Ohlsson, R Simonson


A field test with anti-sapstain chemicals on sawn pine timber in Finland
1986 - IRG/WP 3368
Fourteen formulations, each in two concentrations, were tested for effectiveness against sapstain, mould and decay on Scots pine (Pinus sylvestris L.) in a field test in South-Finland. The trial was commenced in June 1985 and finished in October 1985. During the test the boards were infected mainly by mould fungi. In kiln dried boards the protective effects of nine and in green boards of four trea...
L Paajanen


The use of chlorothalonil for protection against mold and sapstain fungi. Part 1: Laboratory evaluation
1989 - IRG/WP 3515
Laboratory screening of chlorothalonil alone and in combination with other fungicides was conducted against six mold and sapstain fungi. The most promising treatments appear to be chlorothalonil supplemented with CCA or copper-8-quinolinolate. Field tests have been implemented....
J A Micales, T L Highley, A L Richter


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


The effective control of moulds on freshly impregnated wood
2004 - IRG/WP 04-30352
Beside natural timber it is known, that moulds can also groth at the surface of impregnated wood. This material shows “defects” like resistant dark spots or color changes and causes complaints. During the last years, the problem by moulds seems to increase. Laboratory studies were carried out to show the effect of impregnations against moulds. Wood samples (Pinus sylvestris L.) were impregn...
G Cofta, K Lutomski, P Jüngel


Germination of basidiospores on preservative treated wood after leaching or natural weathering
1981 - IRG/WP 2150
In tests of residual toxic efficacy after leaching or natural weathering, spore germination with Gloeophyllum trabeum has proved to be a less reliable criterion of attack than when used with unaged preservative treatments. Since spores sometimes prove more tolerant than their parent mycelium, their use should be continued....
J K Carey


Leaching of CCA from Pinus patula during marine trials in the southern hemisphere
1991 - IRG/WP 4167
Pinus patula stakes were treated with CCA to retentions of 31 kg/m³ salts, and were sited in the sea of Port Alfred, South Africa, for two years. Samples were then removed to the laboratory and analysed as before for copper and arsenic. Prelimiary data showing CAA losses from these stakes in the marine environment showed that CCA was longitudinally leached from them, and was also transversly redi...
G D Shelver, C D McQuaid, A W W Baecker


Oxalic acid production of fifteen brown-rot fungi in copper citrate- treated southern yellow pine
2001 - IRG/WP 01-10388
Non-arsenical copper-based wood preservatives have grown in number since the 1980's as a response to environmental concerns posed by arsenicals. Interest in copper tolerant decay fungi has increased accordingly. Oxalic acid (OA) production by brown-rot fungi has been proposed as one mechanism of copper tolerance. Fifteen brown-rot fungi representing the genera Postia, Wolfiporia, Serpula,...
F Green III, C A Clausen


How to determine what is a realistic emission from treated wood - basic reflections
1998 - IRG/WP 98-50105
Emissions from treated wood occur by evaporation and by leaching. Up to date by far more experience exists on leaching tests than on evaporation test. The methods applied will be of interest to give answers to the questions about the quantity of possible emissions. Standardisation on leaching started very early. One of the first attempts to quantify the effect of leaching on the remaining efficacy...
H Willeitner, R-D Peek


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


The potential for accelerated ageing to determine the persistence of active ingredients in timber
2006 - IRG/WP 06-20323
Fast screening methods for evaluating the persistence of active ingredients in timber are proposed. This is an outline proposal which is intended to provoke discussion and further development of the methods. Reliable and accurate analytical methods are key to these tests....
L D A Saunders, M R Powell


The Effect of Heat on the Retention of Ammoniacal Copper Quat (ACQ-AB) onto Scots Pine (Pinus Sylvestris L.) Wood
2008 - IRG/WP 08-40390
In this study, the sapwood of Scots pine (Pinus sylvestris L.) were treated with ammonical copper quat type (ACQ-AB), which is one of the environmentally friendly wood preservatives, by using soaking method as a functions of various temperatures and time. The results indicated that the retention behaviour of ACQ onto the wood was considerably affected by temperature of ACQ solution and treatment t...
M Hakki Alma, A Mukremin Kara


The Effect of Soil pH on the pH of Treated Southern Pine in Ground Contact after 12 Months
2011 - IRG/WP 11-50281
Southern pine samples treated with soluble and particulate copper solutions were subjected to three soils that had been amended to provide acidic, neutral and alkaline conditions. Wood pH was measured prior to, and after 6 and 12 months after being placed in the soil to determine the effect of soil pH on wood pH....
L Jin, C Schauwecker, C Vidrine, P Walcheski, A Preston


The use of zirconium as an inert fixative for borates in preservation
2001 - IRG/WP 01-30256
Stand-alone borates have been used in internal protected situations as wood preservatives for about 60 years. They have not been deemed acceptable for external situations because of their leaching characteristics. Work carried out to reduce the leachability of borates has been reviewed briefly here, and a specific fixation agent based on zirconium has been tested in standard leaching and decay tes...
J D Lloyd, J L Fogel, A Vizel


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Treatability of Siberian larch and spruce with chromated copper arsenate
1996 - IRG/WP 96-40060
Heartwood of Siberian larch (Larix gmelini) and spruce (Picea jezoensis) was pressure treated with chromated copper arsenate (CCA) Type B using a full cell process. Larch heartwood was somewhat difficult to treat than the spruce, although both species did not meet a minimum requirements of penetration and retention specified by the American Wood Preservers' Association (AWPA) for difficul...
Gyu-Hyeok Kim, Woo-Gue Jee, Jae-Jin Kim


Leaching of chromium and other cca components from wood-cement composites made with spent CCA treated wood
2000 - IRG/WP 00-50153
Wood cement composites are an attractive option for recycling spent treated wood, since the CCA treatment enhances the physical, mechanical and biological resistance properties of the composite. However, we have noted a higher than normal leaching of chromium from these products and this appears to result from conversion of some of the trivalent chromium to the more leachable and toxic hexavalent ...
D Qi, P A Cooper


The leachability and specificity of the biological protection of timber using Scytalidium sp. and Trichoderma spp
1986 - IRG/WP 1302
The results of field experiments, using biological control against internal decay of creosoted poles, are briefly reviewed and the evidence concerning the leachability of the antibiotics produced by these species is presented. A pure culture miniblock decay test on biological control treated pine sapwood is described and the results compared to previously published data. The protection against Len...
P I Morris, N A Summers, D J Dickinson


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


Antifungal properties of new quaternary ammonium and imidazolium salts against wood decay, staining and mould fungi
2004 - IRG/WP 04-30347
The biological activity of twenty-four potential wood preservatives – imidazolium and quaternary ammonium salts with a modified anion structure was determined employing screening agar-plate and agar-block methods. Experiments were carried out on Scots pine (Pinus sylvestris L.) wood. The aim of the performed studies was to investigate the effect of structure modification of IC and QAC with organ...
J Zabielska-Matejuk, W Wieczorek


The influence of age on retention and fixation of CCA in pressure-treated Kenyan-grown Eycalyptus saligna: Summary of findings
2002 - IRG/WP 02-30296
The present study investigates the influence of age on retention and fixation of copper-chrome-arsenate (CCA) in Kenyan-grown Eucalyptus saligna. Samples for the study were obtained from sound trees aged 4, 8, 12, 16, 20 and 24 years. Test samples were radially cut from round material to represent total sapwood and heartwood for each age class, and measured 50mm in thickness, 100mm long, with wi...
R Venkatasamy


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