Your search resulted in 679 documents. Displaying 25 entries per page.
Recycling of treated timber by copper smelter
1994 - IRG/WP 94-50030
A preliminary trial was carried out to see whether copper smelting process is able to recycle CCA treated timber. As a result of the first trial almost a full recovery of both copper and arsenic was achieved. Recovered metals were utilized in manufacturing CCA preservatives. The energy bound in wood is utilized in the flash smelting process and the burning gases are fed to the sulphuric acid plant...
A J Nurmi, L Lindroos
Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman
Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi
Oxalic acid quantification, oxaloacetase assay and ESI localization of P, C, and Fe from the brown rot fungus Postia placenta
1994 - IRG/WP 94-10063
The mechanism by which brown-rot fungi initiate depolymerization of holocellulose in wood remains unknown. Recently, oxalic acid (OA) has received considerable attention in cellulose breakdown by brown-rot fungi. The OA could serve as a proton donor for hydrolytic or an electron donor for oxidative (Fenton's reaction-H2O2/Fe2+) cleavages of cellulose. The acid may originate via oxaloaceta...
C R Jordan, W V Dashek, T L Highley
Environmental fate of copper-based wood preservatives in different soil substrates - Part 2: Study of the metal sorption and migration potential under simulated rainfall
1998 - IRG/WP 98-50101-21 b
In order to examine the potential environmental impact of spillages of the saltborne wood preservative CCA in treatment plants, four large scale experiments are set-up so as to follow the water transport and ion mobility in various field soils.
A plastic container is filled with a sand, silt, clay and potting soil, made up at their respective bulk density and wetted to a given moisture content. U...
G M F Van Eetvelde, R Hartmann, J M Mwangi, H S Öztürk, M Stevens
The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren
Marine trial progress report
1980 - IRG/WP 453
In May 1977 and May 1978, tests of new chemical formulations for the protection of timber in the sea were installed in Mt. Maunganui Harbour. Investigation into new preservatives for such usage was urgently required since it had been found that there was progressive leaching of copper from copper-chrome-arsenate treated marine piles which could lead to a reduction in their service life. Hochmann (...
A F Preston, C M Chittenden
Respiratory response of the wood boring teredinid, Lyrodus pedicellatus (Quatrefages) to copper stress
2004 - IRG/WP 04-10528
Wood boring teredinid molluscs engulf most of the wooden particles scrapped by them while actively boring into wood, obtaining nourishment for their metabolic activities. In order to protect the wooden structures from the biodeteriorating activity of such organisms, the wood is treated with different chemical formulations to prolong their service life. Copper chrome arsenic (CCA) is one such woo...
V Kuppusamy, M Balaji, M V Rao, K S Rao
IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 21: Report of eighth inspection (7 years) in Australia
1985 - IRG/WP 4119
This report tabulates the seven year (86 month) inspection results, obtained on 28 Fabruary l985, of the IRG/COIPM International Marine Test at Goat Island, Australia. This test was installed in December 1977. The results are given in Tables 1-6. Table 7 lists the number of marine borers identified from blocks (2 cm and 6 cm long respectively) cut from the ends of specimens removed at the previous...
L J Cookson, J E Barnacle
Microbial decomposition of salt treated wood
1993 - IRG/WP 93-50001-22
Specialized microorganisms which are able to convert fixed inorganic preservatives from treated wood into water soluble components are investigated. A number of brown rot fungi like Antrodia vaillantii have been isolated from cases of damage and examined under unsterile conditions with CCA-, CCB-, CCF- and CC-treated wood at retention levels of at least 50% higher than recommended for wood in grou...
R-D Peek, I Stephan, H Leithoff
Degradation of lignin model compounds with coordinated copper in the presence of peroxide
1998 - IRG/WP 98-10282
A novel diffusible system capable of decomposing lignin model compounds with copper, coordinators and peroxides has been proposed. When pyridine was used as a copper coordinator, two synthetic dyes, Poly-R and RBBR were intensively decolorized with Cu(II) and H2O2 in aqueous solutions at room temperature. Although reactions with Cu(II) and H2O2 produce a strong oxidant, hydroxyl radical, via a Fen...
K Koller, K Messner, T Watanabe
Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher
Contribution to the knowledge of wood-rotting fungi in Brazil. Part 1: Occurrence and distribution of fungi on different substrates from the Manaus region, Amazonas State
1995 - IRG/WP 95-10096
A total of 945 spezimens of fungi were studied with regard to their distribution on ditterent substrates, abundances and economic importance. The samples came from the collection ot the Wood Pathology Laboratory of CPPF/INPA in Manaus, Brazil. Altogether, 163 spezies and 87 genera were identified. The following genera Trametes, Auricularia, Panus, Rigidoporus and Hymenochaete were represently by m...
M Aparecida de Jesus
Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg
Laboratory aquaria evaluation of CDDC (copper dimethyldithiocarbamate) against marine borers
1998 - IRG/WP 98-10262
The performance of CDDC (copper dimethyldithiocarbamate) and CCA (copper chrome arsenic) treated timber blocks was examined in a 1.5 year aquaria bioassay against the marine borers Limnoria tripunctata Menzies and Lyrodus pedicellatus (Quatrefages). Three timbers, southern yellow pine (SYP), Pinus radiata D. Don and Eucalyptus regnans F. Muell were treated with CDDC to retentions of 16, 32, 48 and...
L J Cookson, C R McIntyre, D Scown
Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek
Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund
Inadequacies in preservative retention and formulation as contributory causes of premature failure of CCA-treated vineyard posts
1984 - IRG/WP 3280
Analyses of severely decayed or failed vineyard posts and examination of stake test data on effectiveness of copper-chrome-arsenate (CCA) preservatives have suggested two contributory causes of premature failure of vineyard posts: 1. Preservative retentions in posts are such that after 15 years' exposure some decay is inevitable. 2. The high arsenic, low chrome formulations with which the...
M E Hedley
Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz
Comparative studies on the species effects of wood preservatives
1989 - IRG/WP 3521
For the examination of the resistance against fungal attack, wood blocks of 3 softwood species were treated with CCA (type 3), CFK, AAC and IF-1000 independently. The wood blocks were exposed to the fungal decay with Tyromyces palustris. The degradation of the wood blocks treated with these preservatives was quite widely different among wood species examined in this study. Hem-fir treated with CCA...
K Yamamoto, S Matsuoka
Leaching of active components from preservative-treated timber - Ongoing research: Status after approx. 4 months’ out-door exposure
2003 - IRG/WP 03-20276
The Danish Technological Institute is together with manufacturers of active ingredients and formulators of wood preservatives running a project aiming at finding realistic leaching rates from preservative treated wood in hazard class 3 (above ground). The project is focussed on developing a field trial method for investigating leaching.
According to BPD hazard assessment has to be carried out f...
N Morsing
Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung
Some recent studies on the marine wood-borers of the west coast of India
1982 - IRG/WP 486
Occurrence and distribution of marine wood-borers along the west coast of India from Mangalore to Kandla are presented together with the distribution pattern of all the molluscan and crustacean wood-borers so far reported from India coasts. The survey, conducted for the first time along this coast, revealed the presence of 14 species of Teredinidae, 2 species of Pholadidae, 3 species and one varie...
L N Santhakumaran
Tendency of the preservative use for impregnation industries in Japan
1998 - IRG/WP 98-50101-05
In Japan, since 1997, the acceptable limit of the arsenic in the waste water become to 0,1 mg/l and the additional regional severer restriction can be established. In this reason, Japanese wood preservation industries intend to use other than CCA, like DDAC, ACQ, Tanalith CuAz, copper-naphthate and zinc-naphthenate, as replacing from CCA. In Jan-June 1997, the share of CCA preservatives was less t...
K Suzuki
Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals