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Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Bending Properties of Southern Pine Treated with Micronized Preservative Systems
2008 - IRG/WP 08-40414
This study indicates that treatment of southern pine with micronized copper systems have no deleterious effect on the residual strength property values. No statistical differences between wood treated with micronized systems and water-treated controls were noted when means were compared using either Tukey’s test or S-N-K mean comparison tests. Using the more discriminating Least Squares anal...
H M Barnes, G B Lindsey, J Hill, M Pompeo, R Hodge


Effects of planning and sanding on penetration and retention properties of some softwood species treated with copper azole
2008 - IRG/WP 08-40410
This work investigates the effect of some woodworking treatments on penetration and retention properties of four different (scotch pine—SP, Siberian scotch pine—SSP, Siberian larch—SL, and oriental spruce—OS) heartwood species with the waterborne preservative copper azole (CBA-A). A 2.4% active ingredient solution of CBA-A was applied for use in vacuum/pressure treatment of the heartwood s...
Ü C Yildiz, S Yildiz


The effects of zinc borate treatment of wood strands on some technological properties of oriented strandboard (OSB)
2008 - IRG/WP 08-40419
In this study, influences of zinc borate treatment on some technological properties of oriented strandboard (OSB), from aspen wood (Populus euroamericana cv.) were evaluated. Therefore, a total of nine panels with dimensions of 40 cm by 40 cm by 1.8 cm and with an average target density of 0.65 g/cm3 were manufactured under the laboratory conditions. Experimental panels were manufactured at two di...
A D Çavdar, H Kalaycioglu, G Nemli


Variations of Furfuryl alcohol and Wolmanit CX-8 treatability of pine sapwood within and between trees
2008 - IRG/WP 08-40421
The variations on the ratio of filling (RoF) were investigated on Norwegian grown Scots pine (Pinus sylvestris). The samples were taken from 10 different stands in south-east Norway, and treated with furfuryl alcohol and a copper-containing wood preservative. Both within tree variations, between tree variations and variations between stands were investigated for significant differences. Factors li...
E Larnøy, S Lande, G I Vestøl


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Biological efficacy of micronized copper systems
2008 - IRG/WP 08-30485
Soil block, fungal cellar and field stake test data will be presented for micronized copper systems. The copper portion of the formulations is present as a fine dispersion of "micro" particulates while the co-biocide is present as either a soluble quat or an azole containing emulsion. This testing generally used the amine based counterpart as the control preservative system and the micronized fo...
C R McIntyre, M H Freeman


A Comprehensive Review of Copper as a Biocide, with a Focus on Micronized Copper
2008 - IRG/WP 08-30486
This paper reviews the wood preservative biocide active ingredient copper and delvers into new and previously unpublished data regarding the new micronized formulations which are now in vogue and widespread use in N. America in all residential treated lumber markets. Included in this review is the overall discussion of copper containing formulations used for pressure treated wood used over the las...
M H Freeman, C R McIntyre


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes


Biological Performance of micronized copper wood preservative formulations in field and laboratory tests
2008 - IRG/WP 08-30488
Micronized Copper wood preservative formulations with different co-biocides were exposed to brown rot fungi in an 8-week AWPA E10 soil block decay test and two AWPA E7 ground-contact decay tests in Hawaii. The micronized copper formulations performed well against decay at or above the AWPA UC3 and UC4 retentions stipulated by the ICC-ES. Micronized copper preservatives performed comparably to a ...
G M Larkin, J Zhang, D L Richter, R J Ziobro, P E Laks


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Alkaline copper treated wood for use in residential decking
2008 - IRG/WP 08-30490
Alkaline copper quaternary ammonium compound (ACQ) treated decking was exposed in a field experiment and the mobile copper assessed based on that collected in the leachate. The amount of copper which leached was modeled after 4 years. The results showed that boards which leached most chemical initially provided the greatest loss over four years. The reduction in the mobility of copper with time wa...
J N R Ruddick


Field Stake Performance of Parallel Strand Lumber Treated with Waterborne Copper Naphthenate
2008 - IRG/WP 08-40435
Wood and wood products have been considered a premium building material for residential and industrial structures for many centuries. More recently, structural composite lumber (SCL) products have played an increasing role in satisfying the needs of the building industry. However, both wood and wood composites are naturally biodegradable materials which require enhanced durability when used in ce...
G P Merrick, M H Freeman, J A Brient


Corrosion of fastener and connector in contact with alkaline copper treated wood – it is a problem
2008 - IRG/WP 08-40437
For many decades, chromated copper arsenate (CCA) was the most common wood preservative used in North America for residential and industrial applications. Since December 31, 2003, the use of CCA for residential application was voluntarily terminated. One of the most widely accepted alternative wood preservatives in Western Canada is Alkaline Copper Quaternary Compound (ACQ). This paper will compar...
J N R Ruddick


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Durability and fungal colonisation patterns in wood samples after six years in soil contact evaluated with qPCR, microscopy, TGA, chitin- and ergosterol assays
2009 - IRG/WP 09-20402
There is a need to establish new objective and sensitive methods for early detection and quantification of decay fungi in wood materials. Molecular methods have proven to be a useful tool within wood protection issues, however, this field is still poorly explored and so far relatively few have used these methods within the field of wood deterioration. Among the techniques used in the indirect quan...
A Pilgård, G Alfredsen, I Børja, C Björdal


Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites
2009 - IRG/WP 09-30493
Wood modification by sol-gel treatments shows many positive features, like antimicrobial properties. Wood was also successfully modified with alkoxysilanes enhancing its resistance against soil micro-organisms. Silver, copper, zinc compounds, boric acid or organic biocides such as alkylammonium compounds may be added to the sol-gel to enhance its biocidal properties. Nevertheless, if some of these...
E Feci, L Nunes, S Palanti, S Duarte, G Predieri, F Vignali


Copper to quat ratio in alkaline copper quat (ACQ) wood preservative - Effects on fixation and leaching of preservative components in red pine
2009 - IRG/WP 09-30496
This study investigates the effect of the relative proportion of copper oxide (CuO) to didecy dimethyl ammonium carbonate (DDACb) in an alkaline copper quat (ACQ) formulation on the rate of copper fixation or stabilization and the resistance of treated wood to leaching of copper and quat (DDACb). Red pine samples were treated with ACQ, having CuO to DDACb ratios of 2:1 (the normal ratio for ACQ-D...
S Pankras, P A Cooper, T Ung, L Awoyemi


Laboratory and field evaluation of Laminated Strand Lumber treated with Borogard® ZB against termites
2009 - IRG/WP 09-30498
A laboratory bioassay and subsequent field trial was undertaken to determine the termiticidal effectiveness of a Laminated Strand Lumber (LSL) composite when treated with Borogard® ZB. The bioassay and field trial were conducted against two of Australia’s most economically important species of termite, Mastotermes darwiniensis and Coptotermes acinaciformis. Against both species of termite, LSL ...
D K Scown and J W Creffield


A theoretical-industrial correlation and perspective on copper-based wood preservatives - a review of thermodynamic and kinetic aspects on copper-wood fixation mechanism
2009 - IRG/WP 09-30499
Copper was and it will continue to remain one of the key active component in wood protection industry. Over the past decades, a significant effort from R&D teams in industry, academia and research institutes was directed toward understanding the copper-wood fixation mechanism, optimising the copper retentions in the wood and reduce leaching in order to maximized performance, prolong the lifetime o...
R Craciun, M Maier, J Habicht


Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril


Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat
2009 - IRG/WP 09-30506
Wood treated with copper-based preservatives to be used in ground contact may fail to inhibit soft rot fungi if penetration of copper into the cell wall is insufficient. Preservatives containing soluble copper are known to penetrate the cell wall; however, it is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control so...
R Stirling, J Drummond


Leaching properties of copper and triazole
2009 - IRG/WP 09-30509
The leaching rate of copper and triazole (such as tebuconazole and propiconazole) in different preservative formulations was determined according to AWPA E11-06. Of all copper triazole and ACQ formulations, copper fixation rate of ammonia based was higher than that of ethanolamine based and the mixture of them. Copper fixation rate at relatively higher retention was slight higher than that at lowe...
Zhiqiang Li, Xiaowen Li, Ying Zhang, Mingliang Jiang


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