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Uptake by grape plants of preservatives from pressure-treated posts not detected
1975 - IRG/WP 350
Leaf and stem tissue and fruit of grape plants (Vitis rotundifolia Michx. cv. Magnolia) were analyzed for copper, chromium, and arsenic, 1, 2, and 3 years after planting 3 inches from copper-chrome-arsenate or fluor-chrome-arsenate-dinitrophenol-treated southern pine posts. Quantities of copper in leaf and stem tissue and fruit of plants next to posts treated with copper-containing preservatives r...
M P Levi, D Huisingh, W B Nesbitt


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Long-Term Release of Arsenic, Chromium, and Copper from CCA-Treated Wood and Ash
2005 - IRG/WP 05-50227
In this study, laboratory long-term leaching studies were conducted to characterize the leaching behavior of arsenic, chromium, and copper from CCA-treated wood samples (block, chip, and sawdust) and CCA-wood ash and to determine the rate of release of the metals from the CCA wood products. The leaching solutions were periodically collected and analyzed for the concentrations of arsenic, chromium,...
Hyunmyung Yoon, Heeseok Kang, Yong-Chul Jang


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


Interactions between soft rot fungi and CCA preservatives in Betula verrucosa
1988 - IRG/WP 1367
Ultrastructural investigations were carried out to obtain information on the cell wall distribution of CCA elements during soft rot decay of 4% K33 CCA preservative treated birch (Betula verrucosa) wood. TEM observations on fibres at various stages of S2 cavity formation by mutabilis showed a distinct pattern of electron dense materials to occur within the S2 cell wall region. These materials (gra...
G F Daniel, T Nilsson


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


The influence of cement and calcium compounds on the performance of CCA preservatives
1983 - IRG/WP 3221
The influence of cement and calcium compounds on the durability of untreated and CCA treated wood is considered. Calcium compounds were found to reduce the toxicity of a CCA preservative to a soft rot fungus at copper to calcium ratios of 1:1 and 1:10 using a cellulose filter paper technique. Further studies are outlined and some possible mechanisms by which cement and calcium compounds may affect...
R J Murphy


Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard


Is Field Test Data from 20 x 20mm Stakes Reliable? Effects of Decay Hazard, Decay Type and Preservative Depletion Hazard
2006 - IRG/WP 06-20327
Effects of decay hazard, decay type and preservative depletion hazard on the performance of variously preservative treated 20 x 20 x 500 mm Radiata pine and Fagus sylvatica test stakes across 13 field test sites in New Zealand and Queensland Australia were determined. Radiata pine treated with an ammoniacal copper quaternary preservative (ACQ) (1.56% m/m a.i.) and copper chrome arsenate (CCA) (...
R Wakeling


Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


CCB Preservative treatment of split muli (Melocanna baccifera ) bamboo by soaking process
2006 - IRG/WP 06-40336
This study was carried out in order to investigate the retention of chemicals inside the split muli ( Melocanna baccifera ) bamboo after preservative treatment by soaking process. Treatment with 10% aqueous solution of CCB (copper-chrome-boron) was applied in split bamboo of two sizes (1/4 part and 1/8 part) at three different moisture contents and five time periods (24, 48, 72, 96, 120 hours). It...
K Akhter, M H Chowdhury


Leaching of CCA from Paraserianthus falcataria panels exposed to field conditions at Krishnapatnam harbour, Andhra Pradesh
2006 - IRG/WP 06-50241
This study assessed the leaching of copper, chrome and arsenic (CCA) from Paraserianthus falcataria (=Albizia falcataria) panels exposed to marine condition at Krishnapatnam harbour on the east coast of India. Metal loss was assessed in test panels after 6, 12, 24 and 36 months of exposure using Atomic Absorption spectrophotometer (AAS). The metal loss was found slightly higher in panels treated ...
B Tarakanadha, K S Rao


Preservative treatment of Golla cane (Daemonorops jenkinsiana) by pressure process
2007 - IRG/WP 07-40379
The feasibility of preservative treatment of golla cane (Daemonorops jenkinsiana (Griff) Mart). by pressure process has been studied using water borne preservatives CCB (copper-chrome-boron). Cane samples of three different lengths 1m, 2m and 3 m. were treated at different pressure and time period to evaluate the extent of penetration and retention of preservative chemicals. It was observed that t...
K Akhter, M Hoque Chowdhury


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Durability of timber from exotic species against termite attack in Indian conditions
2007 - IRG/WP 07-10629
Exotic trees species, Acacia mangium Willd. and A. auriculiformis A. Cunn. ex Benth. and their hybrid are widely grown in India for multiple uses including use as timber. It is essential to know the natural durability of timbers against termites for predicting the service life of the timber and deciding on the application of preservatives to enhance the durability. Studies were conducted to test t...
O K Remadevi, R Muthukrishnan


Effects of acetic acid and nitric acid pre-treatment on copper content of spruce wood treated with CBA-A and CCA
2008 - IRG/WP 08-40406
This work investigates the effects of nitric acid and acetic acid on compression strength values and copper retention contents of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper azole, (CBA-A, Tanalith-E 3492) and copper / chrom / arsenic (CCA). Before the CBA-A and CCA treatment, the samples were immersed in 500 ml of nitric and acetic acid solutions for...
S Yildiz, E Dizman, Ü C Yildiz


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Australian trials on the efficacy of micronized copper
2008 - IRG/WP 08-30480
Alkaline copper quat (ACQ) is an established wood preservative that is formulated with solubilised copper in amine solvent. This paper describes three separate trials in Australia that investigated whether substituting soluble copper with micronized copper affects performance. ACQ and micronized copper quat (MCQ) gave similar performance in Pinus radiata against four brown-rotting fungi in a soil-...
L J Cookson, J W Creffield, K J McCarthy, D K Scown


Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol
2009 - IRG/WP 09-50261
Leaching results for Cu, Cr and As (CCA) and Cu (ACQ and MCQ) from southern pine are compared for laboratory tests (AWPA E11, and draft OECD methods I and II) and natural weathering of horizontally and vertically oriented lumber samples over two seasons. This paper expands on results and comparison of results presented at the IRG regional meeting in Costa Rica in Dec 2008 (Cooper and Ung 2008) a...
P A Cooper, Y T Ung


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Inhibition of Basidiospore Germination by Copper from MCQ, ACQ and CCA Leachates
2012 - IRG/WP 12-10778
The long-term decay resistance of refractory wood shell-treated with chromated copper arsenate (CCA) in above-ground exposures has been attributed to mobile copper that migrates into checks and inhibits the germination of basidiospores. Copper from micronized copper quat (MCQ) has also been shown to migrate into checks suggesting similar performance as a shell treatment, but questions have been ra...
R Stirling, J Drummond, P I Morris


Performance of Wood Protection Systems at Multiple Field Test Sites Using the Ground Proximity Test Method
2012 - IRG/WP 12-20499
A series of preservative systems were used to treat southern pine ground proximity test samples which were then exposed at a range of test sites located throughout the world. The sites were chosen on the basis of having vastly different Scheffer Climate decay indices. After almost 14 years exposure, distinct differences are apparent in how different preservative systems perform at the different ...
A Zahora, A Preston, L Jin


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