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Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Cyclic delamination analysis of preservative-treated wood/FRP interfaces
2002 - IRG/WP 02-40244
Wood preservative chemicals can interfere with adhesive properties when bonding wood laminates or wood/FRP (Fiber Reinforced Polymer) laminate composites. In this work we studied the effects of various wood preservative treatments, and pre- and post-treatment on wood/wood and wood/FRP bond durability using a severe cyclic delamination test (ASTM D-2559). Pre-treatment of individual laminates with ...
C Tascioglu, B Goodell, R Lopez-Anido


Silicon tetrachloride: A potential wood preservative
1980 - IRG/WP 3133
In its present form, this paper is a preliminary draft of a paper that will eventually be submitted for publication in the Forest Products Journal. We are continuing the work on the effects of silicon tetrachloride on wood and expect to have additional data for the meeting in May 1980. Specifically we are measuring the penetration rate and depth of SiCl4, and we are chemically analyzing the treate...
C W Owens, W T Shortle, A L Shigo


Leaching from CCA-treated wood submerged in seawater: Effect of high loadings, and a comparison between laboratory and marine conditions
1996 - IRG/WP 96-50080
This study of leaching examined the following variables: CCA loading; marine versus laboratory exposure and length of submergence. Blocks of Pinus sylvestris were treated to a range of nominal retentions from 15 to 50 kg/m³. Each block was then divided into three cubes and all transverse faces were sealed. All cubes were allowed to fix at ambient temperature for a minimum of one week. One set of ...
R M Albuquerque, S M Cragg, J D Icely


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Wood preservative potential of fractions of wood pyrolysis tar made from Japanese larch
1996 - IRG/WP 96-30102
Wood pyrolysis tar, which was discharged as a waste by-product in the production of charcoal from Japanese larch (Larix leptolepis), was separated into several fractions by solvent extraction using tetrahydrofuran, benzene and aqueous alkali. The fractions obtained were physico-chemically characterized and examined for wood preservative potential. This separation method compared favorably with fra...
T Suzuki, S Doi, M Yamakawa, K Yamamoto, T Watanabe, M Funaki


The treatability of five Indonesian wood species with BFCA preservative
1987 - IRG/WP 3428
This paper deals with a preliminary study on the treatability of five Indonesian wood species, i.e. Altingia excelsa (AE), Rhodoleria teysmanii (CA), Litsea odorivera (LO), Schima wallichii (SW) and Cratoxylon arborescens (CA). Wood samples measuring 4 x 4 x 100 cm³ were dipped into BFCA preservative solution for about 30 seconds. Preservative penetration and the surface area of treated zone were...
Nana Supriana, T K Waluyo


Remedial wood preservative efficacy of BORA-CARE against the Formosan subterranean termite and eastern subterranean termite (Isoptera: Rhinotermitidae)
1991 - IRG/WP 1504
When a spruce board (3.8 cm x 8.8 cm x 2.4 m) was surface-sprayed with BORA-CARETM solution (containing 23% disodium octaborate tetrahydrate) and stored in an air-conditioned room (24 ± 2°C and 60 ± 5% RH) for eight months, ca. 40% of the wood (measured by the cross section surface proportion) contained borates at the rate of >2,500 ppm BAE (boric acid equivalent). In a choice bioassay, term...
N-Y Su, R H Scheffrahn


Fungicidal properties of wood tar being a side product of pyrolysis of previously treated wood with preservatives
2004 - IRG/WP 04-30340
The objective of the paper was to estimate the limit of the fungicidal value of wood tar being a product of pyrolysis of wood previously treated with creosote oil or salt preservative of the CCB type. The effectiveness of wood tar in wood protection against fungi causing brown rot and soft rot was compared to the effectiveness of creosote oil (type WEI-B). Wood was impregnated with alcohol solutio...
B Mazela, M Kielczewski, W Grzeskowiak


The efficacy of polymer/preservative treatments in soil-bed exposure
1992 - IRG/WP 92-3729
Southern pine was treated with CCA, CCB, sodium borax/boric acid, or disodiumoctaborate, alone or in combination with an acrylic polymer system containing a water repellent. Treated samples were subjected to an unsterile soil burial test. The addition of polymer reduced the weight loss in borontreated samples at the lower retentions but not at the higher retention. Results with borates indicate th...
R J Murphy, H M Barnes, S M Gray


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Soft rot decay in CCA treated eucalypts in Queensland - A comment
1986 - IRG/WP 1301
A survey has been completed concerned with the distribution and severity of groundline soft rot decay in the CCA treated sapwood of eucalypt poles in Queensland. The survey encountered some 1000 poles of which 55% were slightly, 28% moderately and 17% severely decayed. Soft rot decay was more severe in urban than rural locations. Embedment of poles in concrete resulted in severe soft rot. No signi...
L E Leightley


Weathering of copper-amine treated wood
2000 - IRG/WP 00-40155
Copper ethanolamine (Cu-EA) treated southern pine (SP) were artificially weathered with a QUV Weathering Tester. The weathering regime was composed of a continuous UV-light irradiation for 2 hours followed by a water spray for 18 minutes for a total time of 1200 hours. The changes on the surface of the weathered samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis,...
J Zhang, D P Kamdem


A possible role of unique TCA cycles in wood-rotting basidiomycetes
2003 - IRG/WP 03-10461
The copper tolerant brown-rot fungus, Fomitopsis palustris, acquires metabolic energy by use of the constitutively-occurring Kornberg’s glyoxylate cycle coordinating with oxalate biosynthesis and glucose oxidation (Erman Munir et al. Proc. Natl. Acad. Sci. USA, (2001) 98, 11126-11130). Furthermore, this fungus does not have the normal TCA cycle, lacking 2-oxoglutarate dehydrogenase which is a ke...
E Munir, T Hattori, M Shimada


Mobility of zinc borate wood composite preservative
1997 - IRG/WP 97-30153
Zinc borate (ZB) is being used as an antifungal and insecticidal wood preservative for flake/strand-based composites. Data is reported on the laboratory and field leaching behavior of ZB when contained in apen flake composites. In general, the performance results correlate with leaching hazard. Although the boron in ZB is more resistant to depletion than in sodium borates, the ZB boron will deplet...
P E Laks, M J Manning


Remedial ground-line treatment of CCA poles in service. A progress report after 28 months' testing
1988 - IRG/WP 3481
Remedial treatments of CCA-treated poles in service with incipient soft rot were carried out with boron rods, boron/glycol solution, boric acid paste, copper/creosote paste and a commercial product (DFCK paste) respectively. The micro-flora before remedial treatment and 6 months after as well as the spread of chemicals in the poles were reported in Document No: IRG/WP/3388. In this progress report...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Effectiveness of wood preservatives by IUFRO's method
1984 - IRG/WP 3305
Pinus elliottii and Eucalyptus saligna stakes treated with 4.9; 6.9; 9.6 and 13.5 kg/m³ of CCA-A, CCA-C and CCB and with 30-50; 60-80; 90-110 and 120-140 kg/m³ of Benzotar and CNSL (cashew-nut shell liquid) were exposed in seven test sites in Sao Paulo State, Brazil. After 4 years it was concluded that the mean useful life of untreated Pinus elliottii stakes was 8 months and of untreated Eucalyp...
G A C Lopez, E S Lepage, O B Neto


Oxidation of wood components during CCA-C fixation
1993 - IRG/WP 93-30024
Pre-extracted radial sections of southern yellow pine sapwood were treated with CCA-C and analyzed by X-ray photoelectron spectroscopy (XPS). The ratio of C1 (carbon bonded to carbon and/or hydrogen) to C2 (carbon bonded to one oxygen) in XPS Cls spectra was taken as a measure of the progress of oxidation of wood components during CCA fixation. This ratio was 0.82 before CCA treatment and increase...
M Kaldas, P A Cooper


Preliminary testing of an improvised wood preservative mixture applied against dry wood beetles
1986 - IRG/WP 1308
An improvised wood preservative mixture was preliminarily tested in situ against some dry wood beetles which had infested structural timbers in a semi-finished building. The results obtained should encourage further research towards mobilizing/improvising locally available resources in the face of scarce standard wood preservatives, against the background of a dilemma in wood utilization in the de...
M O Akanbi, E M Bayode, A A Alabi, J Gbadebo


Special seminar on screening techniques for potential wood preservative chemicals
1978 - IRG/WP 2113
This paper continues following issues: I. SCREENING INSECTICIDES 1) R W Berry (BRE/PRL, UK): Screen testing of insecticides for use in remedial wood preservatives. 2) D J Cross (FRI, New Zealand): Rapid screening of contact insecticides for use on forest products. 3) C R Coggins; A Forsyth; A E Glaser (Rentokil, UK): Experience in the use of indicative screening techniques for termiticides. ...
Anonymous


Microwave treatment to Accelerated fixation of copper-ethanolamine (Cu-EA) treated wood
2004 - IRG/WP 04-40271
This study evaluated the use of microwave post-treatment to accelerate fixation of copper-ethanolamine (Cu-EA) treated 19 mm southern yellow pine sapwood cubes. Cubes were pressure treated at 3.2 and 6.4 kg/m3 Cu retention target, after which they were microwave post treated during different duration periods. An accelerated AWPA leaching test was conducted during 300 hours to determine the amount...
Jinzhen Cao, D P Kamdem


Mobility and bioavailability of wood preservation chemicals in soil - actual field measurements
1998 - IRG/WP 98-50101-11
Wood material intended for outdoor use is often impregnated with chemicals to withstand attack from fungi and bacteria. Both inorganic and organic substances are used to protect the wood, and they are used in a toxic and bioavailable form. At wood preservation facilities severe soil contamination can be encountered due to spills and deposition of sludge, especially at old sites. Two sites, one whe...
S Andersen, G Rasmussen


Preservative treatment of wood-based composites with a mixture formulation of IPBC-silafluofen using supercritical carbon dioxide as a carrier gas
2003 - IRG/WP 03-40251
Wood-based composites treated with a mixture formulation of a fungicide, 3-iodo-2-propynyl butylcarbamate (IPBC) and a termiticide, silafluofen using supercritical carbon dioxide (SC-CO2) as a carrier solvent were tested for their resistance to decay and termite attack in the laboratory. The treatment solution was prepared by mixing both biocides (IPBC 10 + silafluofen 1) with a co-solvent, ethano...
K Tsunoda, M Muin


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


The quantitative determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using TD-GC-MS
2001 - IRG/WP 01-20223
Last year we presented the paper (IRG/WP/00-20201) "Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS". Based on the intensive discussion at the meeting, the first experiences made with the calibration of the system for this application will be reported. For the quantitative determination of N-cyclohexyl-diazeniumdioxide in treated wood, milled m...
P Jüngel, J Wittenzellner, E Melcher


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