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Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Uncertainty in life cycle assessment of preservative treated wood – copper and freshwater ecotoxicity
2017 - IRG/WP 17-50331
Life cycle assessment (LCA) is a method for quantifying the environmental impacts of a product over the life cycle. In the last years, there have been a growing application of LCA in developments of environmental product declaration (EPD), which is utilised by professional procurement of materials for buildings. For legislative issues, LCA have also been used to assess application of creosote to t...
L G F Tellnes


CCA wood preservative: Trust with destiny
2019 - IRG/WP 19-30731
This paper traces the history of Copper-Chrome-Arsenic (CCA) and its current status in India and worldwide. CCA was invented as ASCU at the Forest Research Institute, Dehra Dun in 1933 by Dr. Sonti Kamesam. Although its efficacy was doubted by the British colonial rulers resulting in several hiccups at home, the patent rights were purchased by US Bell Telephone Co. and it was adopted by the US woo...
S Kumar


Relative efficacy of various oxine copper formulations against brown-rot fungi
2019 - IRG/WP 19-30741
This paper investigates the relative resistance of three different oxine copper formulations (oil-borne, water-borne, water-borne with pH-adjustment) as a preservative treatment for wood against brown-rot fungi. Impregnated southern pine sapwood cubes were exposed to R. placenta and G. trabeum cultures in a soil-block test. After eight weeks, the weight losses of the cubes were examined in relatio...
M Petruch, J Lloyd, A Taylor


Economic and Alternative Preservative Research with an Overview of its Impact on the Dynamics of Wood Tie Markets and Railroads
2019 - IRG/WP 19-30751
This presentation will discuss the Railway Tie Association’s (RTA) efforts in economic research for the North American wood tie industry, along with decades-long research into improving wood preservation processes and its resulting economic impact for railroads. Ongoing research is continuing to expand the knowledge-base by comparing existing standard creosote (C) and borate-creosote (B-C) dual...
J C Gauntt


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Treatability of South African-grown Eucalyptus grandis with water-borne copper azole and disodium octaborate tetrahydrate wood preservatives
2021 - IRG/WP 21-40920
This study investigated the treatability of the sapwood and heartwood of sawn Eucalyptus grandis with copper-azole (CuAz) and disodium octaborate tetrahydrate (DOT) water-borne preservatives towards improving its durability for enhanced use in structural solid wood applications. The results obtained showed that, at a moisture content of 12 ± 1%, sawn E. grandis sapwood can be impregnated to a mea...
A A Alade, Z Naghizadeh, C B Wessels


Copper-octanoate - a potential reference preservative replacement for CCA in field test standards?
2022 - IRG/WP 22-20688
Finding a CCA reference replacement for use in standardised test methods is of high priority since this chemical is being phased out and may in the near future be banned also for experimental and approval purposes. In this paper we assess the possibility to replace CCA reference preservative with an historical copper octanoate product. There is a huge amount of lab and field test data available fo...
R Ringman, M Westin, M Klamer, A Christof, F Friese


Through-boring to improve the performance of low durability Eucalyptus species for utility poles: 10-year field test results of pole stubs exposed in Southeast Queensland
2023 - IRG/WP 23-40972
An impending shortage of naturally durable hardwood electricity pole timbers in Australia has encouraged investigation of alternatives containing less durable, untreatable heartwood. Through-boring or drilling holes perpendicular to the long axis before treatment, has been used successfully on refractory softwood poles in North America and might have application in Australia. The use of through-bo...
J Norton, L P Francis, J J Morrell


Comparison of copper leaching from alkaline copper quat and copper compound nanosol-based wood preservative treated wood
2024 - IRG/WP 24-20726
To improve the leaching resistance of copper ion-based wood preservatives, copper compound nanosol-based wood preservatives were developed and its copper leaching characteristics were evaluated. Three types of preservatives (DC1, DC2, DC3) were prepared with different crystallinity and dispersant types of copper compound nanosol, and the copper concentration was adjusted to be the same as that of ...
Y-S Choi, S-M Yoon, J O Kim, J-G Kang, J-G Park


A new wood preservative system based on basic copper compound nanosols
2024 - IRG/WP 24-20728
A bottom-up process was established to synthesize insoluble basic copper compound nanoparticles and simultaneously form a stable nanosol by dropping a neutralizing agent solution into an aqueous solution of a copper compound to which an appropriate dispersant system was added. The main ingredient of MCA (Micronized Copper Azole), the leading copper-based wood preservative in the current world mark...
J O Kim, J-G Kang, Y-S Choi, S-M Yoon, H-M Lee, J-G Park


Quantitative assessment of wood preservative emissions to waterways
2024 - IRG/WP 24-50393
The Organisation for Economic Co-operation and Development (OECD) Emission Scenario Document (ESD) for Wood Preservatives provides methods to quantify the release of active substances from treated wood for various scenarios including sheet pilings in a flowing waterway (OECD 2013). The ESD is used for environmental risk assessment of wood preservatives according to the Biocidal Products Regulation...
K J Rader, R Carbonaro, C Mackie


Confocal laser scanning microscopy of a novel decay in preservative treated radiata pine in wet acidic soils
1997 - IRG/WP 97-10215
Light microscopy of radiata pine (Pinus radiata D. Don) field test stakes (20x20x500mm3) exposed in wet acidic (pH 3-4) soil for 12 - 24 months showed predominance of an unusual type of decay characte-rised by tunnelling attack of wood cell walls. After two years decay was moderate to severe in wood treated to ground contact CCA specifications and also equivalent retentions of creosote, and a numb...
R N Wakeling, Ying Xiao, A P Singh


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


Registration and approval of wood preservatives in Australia and New Zealand
2001 - IRG/WP 01-50166-06
Wood preservatives are treated as agricultural chemicals in Australia and, at the time of writing, as pesticides in New Zealand. Antisapstain products are currently considered to be agricultural chemicals in New Zealand while wood preservatives in the future will be considered as hazardous substances under the Hazardous Substances and New Organisms Act when this Act is fully implemented. They are ...
H Greaves


Field performance of wood preservative systems in secondary timber species
1997 - IRG/WP 97-30152
The objective of this ongoing study is to evaluate the performance of new, potential, and standard wood preservative systems in secondary North American timber species. Eleven preservative systems were evaluated in this study - ACQ Type B, Copper Citrate 2: l, CDDC, chlorothalonil/chlorpyrifos, copper-8-quinolinolate, tebuconazole/chlorpyrifos, RH287, propiconazole/chlorpyrifos, copper naphthenate...
P E Laks, K W Gutting, R C De Groot


Testing of wood preservatives against marine borers (Part 1). Method of testing wood preservatives against marine borers (Part 2)
1971 - IRG/WP 37
P C Trussell, C C Walden


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


Collaborative soft rot tests: PRL tests of Cu/Cr/As preservative using method of Document No: IRG/WP/208
1973 - IRG/WP 223
These tests were undertaken as a preliminary to the next series of collaborative soft rot tests. An interim report has already been presented at Berlin in 1972 as Document No: IRG/WP/211...
J K Carey, J G Savory


Fire resistance of preservative treated fence posts
1994 - IRG/WP 94-30033
Pine fence posts were pressure treated separately with CCA-C, CCA-wax, CCA-oil and creosote. Treated posts and untreated controls were planted in the ground in a randomised block design, weathered for six months and then subjected to a controlled burning test using two fuel loads. Creosote treatment increased the time that posts were alight whereas CCA treatment had no such effect. However, CCA tr...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


Improved equipment and technique for high pressure sap displacement impregnation of natural round wood
1972 - IRG/WP 309
Hitherto the main problem in the practical application of high pressure sap displacement impregnation (HPSD) has been in devising a satisfactory cap. Such a cap must be easily fitted to different size log ends to give a leak proof seal. The present contribution describes a new type of cap and sealing system designed to meet these requirements....
C G W Mason, F B Shorland


Application of radio frequency heating to accelerate fixation of CCA in treated round-wood
1999 - IRG/WP 99-40133
The potential of radio frequency heating to accelerate the fixation of chromated copper arsenate (CCA) in treated round-wood was assessed. Pre-dried Douglas-fir and western red cedar round-wood sections were pressure treated with CCA in a pilot plant retort, after which they were placed individually in a pilot radio frequency (RF) chamber. Based upon the color reaction of chromotropic acid with he...
Fang Fang, J N R Ruddick


Protocol for evaluation and approving new wood preservative
1985 - IRG/WP 2159
M E Hedley, J A Butcher


Comparison of the agar-block and soil-block methods used for evaluation of fungitoxic value of QAC and CCA wood preservatives
1994 - IRG/WP 94-20039
The modyfied agar-block and soil-block methods were used for comparing the fungitoxic value of QAC and CCA type preservatives against Coniophora puteana and Coniophora olivacea The mass loss and moisture contents of wood were analysed....
J Wazny, L J Cookson


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