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A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


Surface accumulation of copper on CCA-impregnated Pinus patula stakes during marine preservative trials in the southern hemisphere
1992 - IRG/WP 92-4181
Pinus patula stakes treated with CCA to target retentions of 30 kg/m³ salts were exposed to sea water in marine and estuarine ecosystems off the coast of Southern Africa for two years. Samples were then analysed for copper and arsenic. Analysis of samples from the marine ecosystem showed (IRG/WP/4167) that arsenic was longitudinally and transversely leached from the wood, whereas the copper was r...
G D Shelver, C D McQuaid, M Tarin, A A W Baecker


The effect of composition on the effectiveness and fixation of CCA and copper/chrome preservatives. Part 1: Effectiveness. Part 2: Selective absorption and fixation
1973 - IRG/WP 324
A preliminary study of a wide range of copper-chrome-arsenic formulations indicates that the most effective are in the region, CuSO4 · 5H2O - 35 to 45 per cent; K2Cr2O7 - 40 per cent and above; As2O5 · 2H2O - 25 to 15 per cent or less. Effectiveness appears to depend more on the copper content than the copper - arsenic. Observations on selective absorption and leaching suggest that the chromium ...
D N R Smith, A I Williams


Non leachability of arsenic, copper and chromium from 15 years old CCA-C treated southern pine poles used in brackish water as jetty piles in Bangladesh
1998 - IRG/WP 98-50103
Revealed that chromated copper arsenate type C (CCA-C) treated southern pine poles used in Central Warehouse Jetty of REB, Khulna are stable and resistant to chemical and biological attack without loss of any component from outer 0-12.5 mm zone after 15y of use. Slightly reduced retention (4.44% less) was noted in above water location of piles (bottom end of tree) which would be due to continuous ...
A K Lahiry


The effect of pretreatments on the impregnation of air-dried sawn Belgian spruce
1988 - IRG/WP 3490
In general the impregnation of airdried spruce results in a variable treatment and limited penetration. This is the result of pit aspiration that occurs during drying of the spruce sapwood and heartwood. Spruce timber is becoming of greater importance in Belgium and hence research for better treatment of this vulnerable wood species is needed. Squared airdried timber of different dimensions were e...
J Van Acker, M Stevens


Water-Borne Copper Naphthenate: An Emerging Wood Preservative
2002 - IRG/WP 02-30280
Waterborne copper naphthenate (WB Cu-N) was used to treat southern yellow pine (Pinus spp) and red maple (Acer rubrum) stakes. The treated stakes were exposed in test sites located in Florida, Michigan and Mississippi for 3 to 6 years. Copper Chromium Arsenate (CCA), Ammoniacal Copper Quat (ACQ) and Oil-borne Copper Naphthenate (OB Cu-N) were also used to treat some stakes for comparison. Results...
P Nzokou, D P Kamdem, M H Freeman


Development of a model system to assess the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles
1992 - IRG/WP 92-2395
A closed model system was designed to facilitate a controlled study of the leachability and environmental fate of a remedial preservative under laboratory conditions. The elements of the model include a precipitation apparatus above a treated pole section which is positioned in a representative soil profile supporting a sward of perennial ryegrass. The model will allow detailed examination of the ...
D C R Sinclair, G M Smith, A Bruce, B King


Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter


Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


Laboratory evaluation of copper naphthenate pressure treatments against the Formosan subterranean termite
1993 - IRG/WP 93-10005
Southern pine wafers and Douglas-fir cubes pressure treated with copper naphthenate in AWPA P9 Type A oil or in toluene were evaluated for resistance to attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Wood samples were pressure treated to target copper retentions of 0.040, 0.075, 0.095, or 0.150 pcf, conditioned to simulate field exposure, a...
J K Grace, R T Yamamoto, P E Laks


Effects of cyproconazole and copper sulphate on the length of the hyphal growth unit (HGU) of the white-rot fungus Coriolus versicolor
2003 - IRG/WP 03-10473
Wood decay basidiomycetes have been shown to produce appreciable quantities of extracellular mucilaginous materials (ECMM). The relationship between ECMM and total biomass production has been investigated in the white-rot fungus Coriolus versicolor (CTB 863 A). Differences in the amount of ECMM produced by the fungus proportionally to the total biomass, were observed under a range of physiological...
D Vesentini, D J Dickinson, R J Murphy


Laboratory termite testing of copper boron tebuconazole
2000 - IRG/WP 00-20192
The American Wood Preservers' Association laboratory choice and no choice termite test (AWPA E1-97) was performed on a formulation of copper azole, which is comprised of copper, boric acid, and tebuconazole. The formulation tested has a ratio of copper:boric acid:tebuconazole of 25:25:1. So as to examine the impact of leaching, the southern yellow pine wafers were treated with and without...
R F Fox, E A Pasek, J Patel


Wood surface pretreatments with metal tannates
1989 - IRG/WP 3552
The sequential application of aqueous solutions of tannins derived from radiata pine bark and water-soluble metal salts was examined as a means of improving the water repellency of wood surfaces. Nine metal salts were screened in combination with tannin solutions and, based on water repellency of pretreated filter paper, four were selected for further study. The two-step application of tannin solu...
D V Plackett, D R Cronshaw


Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process. In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


Fundamentals on steam fixation of chromated wood preservatives
1988 - IRG/WP 3483
Weathering of treated wood directly after impregnation leaches up to 2% of copper-chromate-containing wood preservatives. Almost total fixation of Cr+6 is achieved by steaming the treated wood at 100°C to 120°C, preferably 110°C. To initiate such spontaneous fixation 85°C to 90°C inside the wood are essential, which requires heating times ranging from 20 to 80 min, depending on timber species...
R-D Peek, H Willeitner


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski


Laboratory evaluation of the termiticidal effectiveness of TanalithÒ 3485
1995 - IRG/WP 95-10109
The termiticidal effectiveness of the copper azole TANALITH 3485 was evaluated with the benchmark preservative TANALITH C in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Retentions of TANALITH 3485 tested were 0.15, 0.24, 0.285 and 0.40% m/m Cu and for TANALITH C 0.025, 0.05, 0.08 and 0.095% m/m Cu. Un...
J W Creffield, J A Drysdale, N Chew, N-K Nguyen


Influence of acidification on decay processes of CCB treated wood
2004 - IRG/WP 04-10514
The phenomenon of copper tolerance by brown rot fungal strains has been known for a long period but the complete mechanism of copper tolerance by these fungi is not understood yet. Copper tolerance has previously been linked to oxalic acid excreted by copper tolerant brown rot fungal strains. This acid reacts with copper in the wood to form an insoluble and therefore less toxic copper oxalate. The...
M Humar, S A Amartey, M Šentjurc, F Pohleven


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Performance of copper naphthenate-treated hardwoods
2001 - IRG/WP 01-30269
Copper naphthenate (CuNap) is a historically proven, commercially produced and industry utilized preservative for many wooden commodities including poles, fence posts, lumber, timber and wood shakes/shingles. Historically, most wood preservatives are tested using the sapwood of softwood species like pine (Pinus spp.) and or Douglas-fir (Pseudosuga menziesii) and even though the railroads of the wo...
H M Barnes, T L Amburgey, H M Freeman, J A Brient


Persistance of active ingredients in treated wood
1993 - IRG/WP 93-50001-20
Disposing of chemically protected waste wood implies the distinction between surface and pressure treatment. Considering that barked round-wood merely contains, after 7 months open storage, less than 30 g per ton of bark or 25 mg per ton of sapwood, depending on the type of insecticide, the bark or sapwood shavings may be incinerated normally, according to less severe legal prescriptions than for ...
E Graf, P Manser, S Rezzonico, B Zgraggen


Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis


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