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Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 3: Report of first inspection of samples at Lae, Papua New Guinea
1978 - IRG/WP 446
Samples for the international marine test were placed on frames numbered I to VII. Frames numbered VII of both CCA and CCB trials are being stored dry in the laboratory at F.P.R. & D.C. Frames I to VI of both trials were suspended in the sea at Lae Harbour (Morobe Province, Papua New Guinea) on 6th December 1977. The first inspection of the CCA trial was carried out on 8th June 1978, at which ...
S M Cragg, C R Levy


Fundamentals on steam fixation of chromated wood preservatives
1988 - IRG/WP 3483
Weathering of treated wood directly after impregnation leaches up to 2% of copper-chromate-containing wood preservatives. Almost total fixation of Cr+6 is achieved by steaming the treated wood at 100°C to 120°C, preferably 110°C. To initiate such spontaneous fixation 85°C to 90°C inside the wood are essential, which requires heating times ranging from 20 to 80 min, depending on timber species...
R-D Peek, H Willeitner


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Performance of preservative-treated wood not in ground contact
1975 - IRG/WP 254
Experimental sash units of Pinus strobus L. and Pinus resinosa Ait. wood were removed from a test fence at Ottawa, Canada after outdoor exposure of over 20 years. The units were superficially treated, prior to painting, with preservatives containing either copper naphthenate, pentachlorophenol or a combination of zinc naphthenate and pentachlorophenol. Results indicated that all treatments were ef...
J K Shields, J Krzyzewski


Field evaluation of the above-ground susceptibility of Pinus heartwood and untreated or treated sapwood to two species of Australian subterranean termites
1996 - IRG/WP 96-10147
Plantation-grown Pinus elliottii, Pinus caribaea and Pinus radiata specimens containing heartwood and untreated or preservative-treated sapwood were exposed above ground to the subterranean termites Coptotermes acinaciformis or Mastotermes darwiniensis near Sydney (NSW), Brisbane and Townsville (Qld), and Darwin (NT), using a variety of exposure techniques. Heartwood of Pinus elliottii and Pinus c...
M J Kennedy, J W Creffield, R H Eldridge, B C Peters


Determination of boron levels in solution and in treated wood
1994 - IRG/WP 94-20041
Four methods of measuring boron levels in solutions were investigated. The methods compared included the azomethine-H method which is commonly used in soils and plant tissues, the methods outlined in the Australian Standard AS 1605 (1974) and in Wilson (1958), and the atomic absorption spectrophotometry method. Defect-free radiata pine (Pinus radiata D. Don) sapwood and wood flakes were treated to...
F J Romero, P Vinden, P Kho


Leachabilty and efficacy of fatty acid derived boron esters as wood preservatives - leachability and efficacy of fatty acid derived boron esters as wood preservatives
2004 - IRG/WP 04-30351
Borates have many advantages as wood preservatives. However, boron is susceptible to depletion under humid conditions and this restricts its outdoor use. In order to reduce boron leachability in treated wood, one of the anticipative approaches is to use organic fixed boron-based preservatives. This study investigated the leachability of six boron ester compounds as potential preservatives. Scots p...
A Mohareb, J Van Acker, M Stevens


Laboratory evaluation of the termiticidal effectiveness of TanalithÒ 3485
1995 - IRG/WP 95-10109
The termiticidal effectiveness of the copper azole TANALITH 3485 was evaluated with the benchmark preservative TANALITH C in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Retentions of TANALITH 3485 tested were 0.15, 0.24, 0.285 and 0.40% m/m Cu and for TANALITH C 0.025, 0.05, 0.08 and 0.095% m/m Cu. Un...
J W Creffield, J A Drysdale, N Chew, N-K Nguyen


Soil treatment tests with the three products of boric acid for the prevention of the hyphal growth of Serpula lacrymans
1992 - IRG/WP 92-3693
Laboratory soil treatment tests were conducted for the evaluation of fungicidal or fungistatic effect of boric acid products against Serpula lacrymans. Boric acid products tested were the following three: a thickened boric acid solution in triethanolamine, boric acid-silica gel complex granules, and a nonwoven fabric laminated with a polypropylene film and coated with boric acid granules on one si...
S Doi, A Yamada, Y Mineki, M Mori


Laboratory studies of CCA-C-leaching: influence of wood and soil properties on extent of arsenic and copper depletion
2002 - IRG/WP 02-50186
The extent which a wood preservative leaches is important for efficacy studies and environmental concerns. However, little information exists on the effect soil properties have on leaching. This study investigated leaching of stakelets which had been cut from five different southern yellow pine (SYP) sapwood boards then treated with CCA-C to a target retention of 6.4 kgm-3 (0.4 pcf). All stakel...
D Crawford, R F Fox, D P Kamden, S T Lebow, D D Nicholas, D Pettry, T Schultz, L Sites, R J Ziobro


Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Performance of copper naphthenate-treated hardwoods
2001 - IRG/WP 01-30269
Copper naphthenate (CuNap) is a historically proven, commercially produced and industry utilized preservative for many wooden commodities including poles, fence posts, lumber, timber and wood shakes/shingles. Historically, most wood preservatives are tested using the sapwood of softwood species like pine (Pinus spp.) and or Douglas-fir (Pseudosuga menziesii) and even though the railroads of the wo...
H M Barnes, T L Amburgey, H M Freeman, J A Brient


Timber preservatives and corrosion
1983 - IRG/WP 3228
A survey of preservative treated timber commodities has illustrated problems that may be caused by corrosion. After treatment, timber should be compatible with commonly used fasteners. Whilst many corrosion methods have been used in the past, no standardized method is used by workers in timber preservation. The Queensland Department of Forestry is developing laboratory test methods for assessing c...
R I Davis


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Resistance of six timber species, treated with CCA and CCB, against marine borer attack in Goa waters (India)
1991 - IRG/WP 4166
Panels of Lagerstroemia speciosa, Toona ciliata, Olea dioica, Pinus insignis, Acrocarpus fraxinifolius and Borassus flabellifer, pressure-treated with a 6.6% solution of Copper-Chrome-Arsenic (CCA) and 6% solution of Copper-Chrome-Boric (CCB), were exposed along with untreated controls, in triplicate, in Goa waters to, assess their resistance to damage by marine borers. The control panels were all...
L N Santhakumaran, R V Krishnan


Investigations of the treatability of various commercially significant Turkish timbers
1976 - IRG/WP 370 E
Timbers which naturally deteriorate quickly can only be used commercially when their life is increased by the use of chemical treatments. The treatment of the timber can only be planned on a regular basis when the treatability of the wood is known. The purpose of the experiments was therefore to determine to what extent the various types of wood could be sufficiently impregnated. The question of t...
R Ilhan


Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions. Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens


Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz


The evaluation of the effectiveness of wood preservatives by means of IUFRO's method for field tests with wooden stakes
1985 - IRG/WP 3348
Pinus elliottii and Eucalyptus saligna stakes treated with CCA-A, CCA-C, CCB, Cashew Nut Shell Oil and Benzotar solutions were exposed in seven test sites in Sao Paulo State, Brazil. After five years of exposure, between oil-borne preservatives Benzotar show better performance than CNSL (cashew nut shell liquid), and within waterborne preservatives the performance of CCB is not so good as that of ...
G A C Lopez, A M F Oliveira, E S Lepage


Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 14: Report of sixth inspection (60 months) in Australia
1983 - IRG/WP 499
The IRG/COIPM International Marine Test was installed at Goat Island, Sydney Harbour, in December, 1977. The results of inspections made at 6, 12, 24, 36 and 48 months have previously been reported. This document records the data obtained on the 16.12.82, i.e. after 60 months exposure, at which time only 4 of the test frames remained in test. The surface water temperature at the time of inspection...
L J Cookson, J E Barnacle


Sawn timber of fir (Abies alba Mill.) - Treatability and usability for the Hazard Classes 3 and 4
1999 - IRG/WP 99-40147
Within a national research project, tests on the treatability on sawn timber of fir (Abies alba Mill.) in oscillation pressure, vacuum pressure and double-vacuum processes have been worked out with 95 trunks taken from 3 different altitude levels (up to a height of 590 metres, 600 to 990 metres and over 1000 metres) and from 4 different regions of Switzerland. As the treatability of round wood can...
E Graf, T Bör


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Second update
1995 - IRG/WP 95-10117
As was agreed by members at the termite workshop at the 24th annual meeting of IRG in Orlando, USA, in May 1993 to initiate an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives (CCA and Cu-naphthen...
J R J French


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