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How intraspecific radial variability of the European Oak’s may influence mild pyrolysis process and durability of the material
2016 - IRG/WP 16-40725
Last decades wood is promoted as building material. Unprotected wood exposed to outdoor conditions undergoes a variety of degradation induced essentially by fungi attacks. Heat treatment of wood by mild pyrolysis (180°C T 240°C under inert atmosphere) is a preservation process with a weak environmental impact, and therefore, is viewed as an interesting alternative to the chemical impregnation me...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


Development of a new method for wood hydrophobizing and fixation of copper compounds by chemical hardening of vegetable based modified oils
2016 - IRG/WP 16-40754
Wood products with ground and direct water contact, but without sufficient biological durability, have to be protected against biological degradation by fungi and other microorganisms. Due to European legislation (Biocidal Products Regulation 528/2012), the selection of possible chemical agents, which are still allowed to be used, is diminishing rapidly. The use of previously widely applied, very ...
C Swaboda, M Fischer, K Jacobs


Chemical, physical-mechanical characterization and durability of thermally modified beech and ash wood by thermo-vacuum process (Termovuoto)
2016 - IRG/WP 16-40758
The paper illustrates part of the results from the CIP Eco-innovation project “Thermo-vacuum: new process for new generation of thermally modified wood”. The project is part of the 7th Framework Programme for European Research and Technological Development, and thermo-vacuum modified wood is already on the European market. The project was selected by the European Commission, EASME Agency, as "...
M Jebrane, I Cuccui, O Allegretti, N Terziev


Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


Chemical compositions and anti-termite activities of essential oils from Gabonese Canarium schweinfurthii Engl, Dacryodes buettneri Engl and Aucoumea klaineana Pierre wood resins.
2017 - IRG/WP 17-10895
Essential oil extract from resins of Canarium schweinfurthii, Dacryodes buettneri and Aucoumea klaineana woods from Cap Esterias and Oyem areas, Gabon, were prepared by Clevenger - steam distillation. The chemical compositions of these respective essential oils were analyzed by a Gas Chromatography coupled with Mass Spectrometry (GC-MS). Although monoterpenes were the main constituents of the thre...
Chemical compositions and anti-termite activities of essential oils from Gabonese Canarium schweinfurthii Engl, Dacryodes buettneri Engl and Aucoumea klaineana Pierre wood resins.


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Controlled deposition of copper nanoparticles using wood inherent architecture as natural template
2017 - IRG/WP 17-40783
As one of the most abundant renewable biomass resources, wood can be used as templates for synthesizing functional nanoparticles with controlled shapes and sizes. In this study, copper nanoparticles were synthesized with controlled shapes and sizes using poplar wood as the natural inexpensive and renewable templates. The crystal structure and morphologies of the copper nanoparticles were character...
Youming Dong, Kaili Wang, Yutao Yan, Jianzhang Li, M Hughes, Shifeng Zhang


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


The use of new, aqueous chemical wood modifications to improve the durability of wood-plastic composites
2017 - IRG/WP 17-40787
The wood flour used in wood-plastic composites (WPCs) can biologically deteriorate and thus the overall mechanical performance of WPCs decrease when exposed to moisture and fungal decay. Protecting the wood flour by chemical modification can improve the durability of the wood in a nontoxic way so it is not harmful to the environment. WPCs were made with modified wood flour and then evaluated for m...
R E Ibach, C M Clemons, G C Chen


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Biocontrol of wood decay insects and nematodes as an alternative to traditional chemical treatments
2018 - IRG/WP 18-10914
The protection of wood has been defined until relatively recently, as the application of a chemical to increase its durability. On the other hand, society is becoming more and more demanding in terms of the use of products which have the minimum ecological impact. This has led many countries to reduce the list of biocidal products that can be used (European Biocides Regulation), therefore it is ne...
L Robertson, J F Galván, F Llinares, R Viñambres, M T de Troya


Understanding of the effect of ancestral and natural saltwater treatment on durability, fibers densification and chemical modification of palm wood
2018 - IRG/WP 18-10921
The palm-tree sector plays a very important role on both the socioeconomic and ecological levels, in Tunisia. There are three million trees in Tunisian palm plantations, ensuring a potential significant wood production, mainly in the craft and furniture industries. In the past, Date Palm wood (Phoenix dactylifera L.,) was also used as structural material. Its low natural durability and its low m...
M T Elaieb, A Namsi, M Tella, M-F Thévenon, K Chandelier


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


Chemical defense of trees and wood natural durability: from protection to valorization
2019 - IRG/WP 19-10943
Natural durability of wood is defined as “the inherent resistance of wood against various wood-destroying organisms” (European standard EN 350-1). This property is due in particular to heartwood extractives. However, the wood natural durability is included in a wider defense system, and other organs such as bark and roots also host protective compounds. Studying the mechanisms on which global ...
E Houel, D Stien, N Amusant


Determining the natural durability on xylarium samples: mini-block test, wood powder and chemical profiling
2019 - IRG/WP 19-10944
Xylaria, or wood collections, can be considered sleeping beauties in terms of wood technological and biological output. In this study we focus on determining the natural durability of xylarium specimens from the Federal Xylarium in the Royal Museum for Central Africa. The Federal Xylarium contains over 80,000 specimens, covering more than 13,000 species, mainly from Central Africa. These specimens...
V Deklerck, L De Ligne, J Van den Bulcke, E Espinoza, H Beeckman, J Van Acker


Coula edulis baill an unknown wood species as an alternative to the main durable wood species used in Gabon
2019 - IRG/WP 19-10945
The Congo Basin hosts an exceptional biodiversity of trees, flora and fauna. However, the immense natural heritage of the forests in this area is increasingly threatened by many anthropogenic factors, due to selective exploitation of certain wood species. In Gabon, whose ecosystem is representative of this area, the forest represents nearly 80% of the national territory. Only a minority of wood sp...
C S A Bopenga Bopenga, S Dumarçay, P Edou Engonga, P Gerardin


The Structural Performance of the Nail Driven into the Decayed Wood
2019 - IRG/WP 19-20652
In late years there are many actions to long-term excellent house realization. We have to consider repair or reinforcement for long-term and safety use of wooden house. There are various studies focused on structural performance of decayed wood. It is important for long-term use of wooden house that structural performance of nailed joint on decayed wood is accurately evaluated. However, there are ...
N Wada, H Isiyama


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Chemical composition and performances of slow pyrolysis by-product from sugarcane bagasse for wood protection
2020 - IRG/WP 20-30752
Pyrolysis distillate or bio-oil, a by-product of biomasses’ slow pyrolysis in the char-making process, has been traditionally used as bio-pesticides by Asian farmers. Due to its large composition of bio-active chemicals, bio-oil obtained from various biomass has become of interest in many applications, including wood protectants. This study aims to characterize the chemical composition of bio-oi...
F D Boer, M-F Thévenon, J-M Commandre, M Fournier


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