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Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi


Effect of different ASAs (alkenyl succinic anhydrides) on the treatment of biological protection of wood in use class 4
2008 - IRG/WP 08-40440
The alkenyl suscinic anhydrides (ASAs) used in this work are adducts resulting from the maleinization reaction of fatty acid alkyl esters. Various products with different alkyl groups were synthesized from rapeseed (Brassica napus) oil esters, rich in oleic acid. The liquids obtained showed a viscosity similar to that of vegetable oils and a brown color. When applied into wood, a thermal treatment...
C Vaca-Garcia, O Pignolet


Mechanical and chemical properties of blue stained wood
2009 - IRG/WP 09-10686
Discoloration of wood is frequently caused by blue-staining fungi. In the previous researches there was general opinion that blue-stain fungi do not influence mechanical properties. On the other hand, there were some opposite results reported as well. In order to elucidate this issue, specimens made of Pinus sylvestris sapwood were exposed to two the most frequent and important blue stain fungi Au...
M Humar, V Vek, B Bučar


Use of biological and low toxicity products against subterranean termites
2009 - IRG/WP 09-20410
The climatology of Mediterranean countries is favourable to the development of termites that cause important damage to wood structures in both furniture and buildings. Until a few years ago the treatment for this type of insect was based on the impregnation of the wood with chemical products. The use of these chemicals is now being restricted in Europe since the publication and harmonization of n...
M T Troya, M J Prieto, F Rubio


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


Wettability and bonding strength of wood thermally-treated with different combinations of soy oil and chemical additives
2009 - IRG/WP 09-40454
Thermal treatment is a method which has gained wider acceptability as an alternative to the chemical treatment in wood preservation. In order to maximize the benefits of this technique several options have been adopted including the use of soy oil in transferring the heat to the wood. Available information on thermal treatment in general and the oil method in particular show that there are still n...
L Awoyemi, P A Cooper, T Ung


Investigation of chemical changes in acetylated beech wood during weathering
2009 - IRG/WP 09-40460
In this study Beech wood (Fagus orientalis) acetylated and has been subjected to a variety of artificial weathering conditions (water only, light only, water and light together)in difference times (0,50,150 and 300 h), then wood surface analyzed using Fourier Transform Infrared spectroscopy (FTIR).Results shown that weathering process affected the functional groups on the wood surface. Light and w...
M Akhtari, M Arefkhani


Wood properties influencing the penetration of Scots pine (Pinus sylvestris) sapwood with the wood modification agent furfuryl alcohol
2009 - IRG/WP 09-40470
The European standard EN 350-2 classifies Scots pine sapwood as class 1 (easy to treat). However large variations in sapwood penetration exist which affect a homogenous distribution of preservatives. Hence individual penetration schemes have to be developed and adjusted to the material most difficult to treat in order to provide adequate sapwood penetration. To ensure better economic process con...
K Zimmer, E Larnøy, G Koch


The effect of chemical changes on the wood-moisture relationships in thermally-modified wood
2009 - IRG/WP 09-40473
Small specimens of three wood species were thermally modified following twenty schedules in the 190-245°C temperature range for treatment times between 0.3 and 16 h. Five wood-moisture relations were subsequently determined, namely: anti-swelling efficiency (ASE), movement, hygroscopicity (adsorption and desorption), transversal swelling (radial and tangential directions), and equilibrium moistur...
M M González-Peña, M D C Hale


The natural durability and preservative treatability of 11 bamboo species
2010 - IRG/WP 10-10708
Tests on the natural durability and preservative treatability of 11 common bamboo species were conducted. The results showed that there was a linear relation between bamboo density and its preservative retention by mass, and the preservative retention of bamboo reduced while its density increased. The test also showed that there were significant differences in the natural durability of bamboos, bu...
Chen Lifang, Su Haitao, Zhang Yanjun, Wang Yuxia, He Xuexiang, Ma Hongxia, Xie Guijun


Chemical mediated depolymerization of cotton cellulose for the understanding of non-enzymatic fungal decay
2010 - IRG/WP 10-10731
Small, low molecular weight non-enzymatic compounds have been linked to the early stages of brown rot decay as the enzymes involved with holocellulose degradation are found to be too large to penetrate the S3 layer of intact wood cells. The most pronounced of these which were analyzed in this study are hydrogen peroxide, iron, and oxalic. The compounds related to the Fenton reaction: the combinati...
A C Steenkjær Hastrup, B Jensen, F Green III


Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas


Field trials of wood preservatives in UC3 retention. Part 1. Durability results after 13 years in and above ground
2010 - IRG/WP 10-30548
In 1996 an extensive field trial program was set up in order to obtain more data on wood treated with chromium and arsenic free preservatives in Use Class 3 retention. Apart from durability in and above ground, other features were also assessed, e.g. discoloration by staining fungi, depletion of active ingredients, weathering and corrosion of fasteners in con¬tact with the treated wood. Wood spec...
M Westin, J Jermer, M-L Edlund, P Larsson Brelid, I Johansson


Chemical protection of historic timber structures: Results and future needs
2010 - IRG/WP 10-40487
The paper concentrates on the analysis of the effectiveness of chemical protection for timber structures in the Russian State Museums “Kizhi” (Karelia) and “Vitoslavlitsy” (Novgorod). The condition of historic timber was tested at the monuments treated with PCP, borax, potassium carbonate, boric acid, Pinotex chemicals in the 1970-80. Long-term analysis revealed that in many cases the...
M Kisternaya, V Kozlov


Study on the thickness swelling of mould-resistant chemical treated bamboo strand woven outdoor flooring
2010 - IRG/WP 10-40489
To prevent bamboo strand woven flooring from mould, several preservatives were chosen to treat bamboo strand before dipping into adhesives and pressing. The thickness swelling and mould resistant effect of the finished board were studied. Results showed that different preservatives had different influences on the thickness swelling of BSWF, and in order to reduce the thickness swelling of the fini...
Fangli Sun, Binfu Bao, Shenyuan Fu, Anliang Chen


Preservative Treatment of simul (Bombax ceiba) Veneers with Hot and Cold Water Solution of borax-boric acid by Soaking Process
2010 - IRG/WP 10-40528
Veneers of simul (Bombax ceiba) were treated with different concentrations of water- borne preservatives borax-boric acid (BB) by soaking process for different time periods. In the case of hot water treatment, it was found that the average retention of preservative chemicals increased gradually with the increasing treatment period from 20 minutes to 60 minutes. Similar trend was observed in the ca...
K Akhter, Md Abul Hashem, S Akhter


Chapter 7 - Treatment processes of bamboo
2010 - IRG/WP 07-10635-07
For adequate penetration and retention of preservatives in woody bamboos at green, dry, solid and sliced conditions different possible and applied treatment processes have been described along with their classifications. The treated bamboo can be used as building materials; the sufficient treatability ensures its long-term best utilization at ground contact and indoor. All the processes descr...
A K Lahiry


Chapter 14 - Accelerated fixation of CCA-treated bamboo
2007 - IRG/WP 07-10635-14
Chromated copper arsenate type C (CCA-C) fixation study on impregnated (with adequate w/v 6% CCA solution) then boiled, oven-dried, normal, air-dried and steamed bamboo slices of airdried borakbamboo (Bambusa balcooa Roxb.) of Bangladesh, revealed almost complete fixation in steamed (accelerated fixation) and air-dried (3 weeks, slow fixation) bamboo slices compared to moderate to low fixati...
A K Lahiry


Multilayer hot-press drying and chemical modifying of poplar wood with urea-formaldehyde prepolymer
2011 - IRG/WP 10-40539
The objective of this study was to determine the technology of chemical modifying and multilayer hot-press drying on poplar wood. The chemicals were impregnated into cell lumen space by pulse-dipping machine to improve the dimension stability and mechanical property of timber. The timbers were compressed and dried by the multilayer hot-press drying to increase the density of timber. Results indica...
Guofeng Wu, Yifei Jiang, Sheng Yao, Junwen


Comparative investigations between thermal and microwave assisted digestion as a novel tool for the chemical analysis of inorganic wood preservative components
2011 - IRG/WP 11-20461
The correct chemical impregnation of wood requires an internal as well as external quality control of the treated wood. The active is located in a solid matrix, therefore it is often difficult to analyse such material since most analytical procedures are based on liquid systems. Because of this quite a number of methods – like extraction or thermal digestion - were developed in order to transfer...
H Ahl, J Fromm, E Melcher


A comparative study and evaluation of methodologies used for determining wood preservative penetration
2011 - IRG/WP 11-20475
A series of methods for determining penetration of wood preservatives into the wood structure have been developed for either quality control (QC) or research and development purposes. QC methods range from monitoring the solution uptake, applying colour indicators or sampling specific wood samples followed by wood acid digestion/atomic absorption spectroscopy (AAS) or solvent extraction/chromatogr...
R Craciun, R Moeller, J Wittenzellner, T Jakob, J Habicht


Slice - Cut and Analyze Laser Microdissection (LMD): A method to produce sample material from modified wood for chemical quality analysis
2011 - IRG/WP 11-20478
Wood modification with its various systems is an established way to enhance a wood products’ service life in outdoor applications. Per definition, selected material properties are enhanced by means of modification without producing toxic substances or residues during service life and combustion afterwards. The systems of impregnation modification include a physical and often chemical alteration ...
K Zimmer, E Larnøy, A Treu, M Fongen


Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives
2011 - IRG/WP 11-30556
Copper ethanolamine based preservatives are currently the most important solutions for impregnation of wood in ground contact in Europe. One of the issues related to those and similar water based solutions is insufficient penetration to refractory wood species like Norway spruce. In order to elucidate this issue, commercial copper ethanolamine based solution was supplemented with five different wo...
M Humar, N Thaler, B Lesar


Phytosanitary standards and the potential for acceptance of chemical treatments as a phytosanitary measure
2011 - IRG/WP 11-30558
Regulations governing international trade in forest products must balance the economic and social benefits of trade with the potential risks of transporting invasive species. The International Plant Protection Convention (IPPC) is an international agreement intended to manage this process. It develops international phytosanitary standards (ISPMs) that are recognised by the World Trade Organisation...
A Uzunovic, R Stirling, J J Morrell, P I Morris, C F Schauwecker


The potential of silicone-based formulations to enhance wood properties through industrial treatment for outdoor use
2011 - IRG/WP 11-30578
High hygroscopicity is one of the main weaknesses of wood as far as its susceptibility to biodegradation, and specifically to fungal decay. New wood preservation technologies are constantly entering the wood protection market, competing with traditional, biocide-based preservation. Silicones are commercially used as hydrophobic agents on stones and concrete. They belong to the restricted number of...
F Simon, F Marchal, F Pochon, M Kutnik, I Le Bayon


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