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Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Surface chemical wood densification through in situ electron beam polymerization: description and dose study
2022 - IRG/WP 22-40933
Traditional wood chemical densification processes can be used to improve wood mechanical properties by increasing density of the material throughout its thickness. While mechanical surface densification has heavily been investigated, surface treatments involving impregnation of monomers remain unexplored. This study describes a new material, surface densified through lateral impregnation of acryla...
J Triquet, P Blanchet, V Landry


Chemical modification of cellulose nanofibrils for tailoring properties of composites
2022 - IRG/WP 22-40934
Due to its natural abundance, complete biodegradability and excellent properties, cellulose is one of the most promising materials for the production of bio composites, as well as one of the most promising fillers for biodegradable polymer composites. This is also true for nanocellulose. A large number of hydroxyl groups on the surface of fibers or fibrils enables a whole series of chemical reacti...
I Poljanšek, J Levanič, V Ž Bogataj, V Vek, P Oven


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


The influence of chemical and thermal modification on homogeneity between sapwood, heartwood, and transition wood of short rotation teak
2023 - IRG/WP 23-40961
Short rotation teak wood has low quality especially in durability. Heartwood presents sufficient natural durability and poor impregnability; meanwhile, most sapwood requires special treatment to increase its durability. The objective of this work was to investigate the effect of thermal or chemical treatment on homogenization between sapwood, heartwood, and transition wood for some selected proper...
R Martha, B George, W Darmawan, P Gerardin


The impact of pre-drying on treatment level variations of esterified solid wood analysed by X-ray densitometry
2023 - IRG/WP 23-40977
Wood modification requires homogenous treatment levels within the wood matrix to prevent insufficiently treated areas being subject to biodeterioration. Esterification of wood by citric acid and sorbitol can show differences in density caused by uneven chemical distribution during the curing phase and can be detected by x-ray densitometry. This study used density profiling to investigate the influ...
A Treu, S O Amiandamhem, E Larnoy


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


Studies on the treatability of selected pine species and corresponding efficacies of a new non-biocidal treatment
2024 - IRG/WP 24-20721
Wood decay caused by fungi may reduce the service life of wood in outdoor applications. Since moisture conditions in wood occur as one of the most crucial parameters for fungal decay, chemical modifications, which affect the latter, may increase the resistance of wood against such organisms. Usually, pine sapwood is easier to chemically treat than heartwood, as the former generally shows good perm...
T R da Silva Lins, L Emmerich, H Militz, P H Gonzales de Cademartoni, R J Klizke, M Pereira da Rocha


Physical, durability and chemical characterization of Gmelina arborea (Roxb.) wood treated with lactic acid
2024 - IRG/WP 24-30803
The increase in demand for durable wood has drawn attention to the use of fast-grown plantation species across the globe. Chemical modification was used to treat Gmelina arborea wood with lactic acid for property enhancement. The treated samples were obtained from two different ages of 15 and 10 years and sawn into (20 x 20 x 60) mm and (20 x 20 x 20) mm for physical, durability and chemical chara...
T O Akinwamide, J M Owoyemib, E A Iyiolac


Shelling of flat and profiled western larch deck-boards exposed to natural weathering
2024 - IRG/WP 24-40997
Shelling is a severe type of raised grain that occurs at the surface of deck-boards made from wood species that have growth rings with pronounced differences in density between earlywood and latewood, for example southern pine (Pinus spp.). Shelling is more severe in deck-boards fixed with their growth rings oriented pith-side-up (concave) rather than bark-side-up (convex). Far less is known about...
L H Leung, P D Evans


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


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