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Microscopical analysis of formaldehyde-acid modified wood
1981 - IRG/WP 3182
Cross-linking of wood with gaseous formaldehyde improves its hygroscopic and dimensional behaviour, and its resistance against micro-organisms. However, formaldehyde cross-linking reactions take place only in the presence of an acid catalyst, which results in losses in mechanical By optimization of a formaldehyde-sulfur dioxide vapour phase process the reaction conditions were established to limit...
M Stevens, N Parameswaran


The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Improving the weather resistance of glue-laminated jarrah and karri
1994 - IRG/WP 94-40017
Surface modification and dimensional stabilisation significantly increased the dry and wet shear strength of karri and jarrah lap-shear specimens (laminates) bonded with resorcinol formaldehyde. The combination of surface modification (sanding/sodium hydroxide treatment), and furfurylation produced the highest dry and wet shear strengths. Acetylated laminates had the lowest dry bond strength, but ...
J Balfas, P D Evans


CCA treatability of 100 timbers of Bangladesh
1996 - IRG/WP 96-40069
CCA treatabilities of 100 timber species grown in Bangladesh have been compared with the treatability of Pole pine (Pinus caribaea) grown in Bangladesh which revealed new five treatability grades. Sapwood of 48% species and heartwood of 9% species was found to be treatable with CCA under grade (++++) having 100% penetration. Like softwood where CCA penetrates completely in cell lumens and cell wal...
A K Lahiry


Paper for discussion - Incising of spruce to improve preservative penetration
1973 - IRG/WP 318
Large quantities of whitewood or Norway spruce (Picea abies) are regularly imported into the United Kingdom from continental Europe. In addition, increasing amounts of Sitka spruce (Picea sitchensis) are likely to become available over the next decade from the Forestry Commission. In many ways spruce is a good structural timber, eg it is relatively cheap and easily available, it has adequate stren...
W B Banks


An evaluation of chemical treatments for the protection of radiata pine logs from fungal degrade
1986 - IRG/WP 3377
Busan 30, Busan 1009, Mitrol PQ375. and sodium pentachlorophenoxide (NaPCP) plus have been evaluated as antisapstain treatments for the long-term protection of debarked radiata pine logs. After 3 months' winter-spring storage, treated debarked logs had less surface and internal sapstain than 'control' logs. After 6 months' storage all logs had internal sapstain ...
J A Drysdale, M E Hedley, J A Butcher


Service life of pressure treated deckings of spruce in direct contact with the ground
1988 - IRG/WP 3463
For decking outdoors in Sweden, pressure treated Scots pine (Pinus sylvestris L.) is used, on account of its treatability. The feasibility of using instead the refractory Norway spruce (Picea abies Karst.) is tested in a field trial. The spruce decks were treated together with pine decks with an ordinary Bethell process. As yet, after more than four years of exposure, neither in the battens nor in...
J B Boutelje, T Sebring


Treatability problems - Relationships between anatomy, chemical composition and treatability
2001 - IRG/WP 01-40213
This report documents the results of phase 1 and 2 of a 3-phase research program. In phase 1, two hundred and fifty-six (256) Southern pine (pinus spp.) nominal 2 x 6's (38 mm x 140 mm) from a single mill in Georgia (southeastern US) were evaluated for treatability with CCA preservative. After treatment, 128 pieces representing a broad range of treatment characteristics were selected and ...
J E Winandy, F Green III, D Keefe


Correlation between changes in colour and chemical composition during photo-degradation of wood surfaces
2005 - IRG/WP 05-40301
Changes in colour of wood (yellowing) during photo degradation or weathering reflect chemical changes in wood. Therefore, the relationship between changes in chemical composition and CIELAB colour parameters is very important to characterize photodegradation of lignocellulosic surfaces. In this study, the changes in chemical composition and yellowing due to photo-degradation was studied by expos...
K K Pandey


Threshold levels for dip treatments of chlorpyrifos for borer control
1995 - IRG/WP 95-10137
Chlorpyrifos has been used in non-pressure treatments of freshly sawn lumber and millwork for ten years or longer to control wood boring beetles. Since chlorpyrifos provides a quick kill of existing beetle larvae at the time of the treatment in solution concentrations as low as 0.05%, treaters tend to use less than recommended rates as a cost saving measure. However, laboratory studies conducted i...
R D Fears, J L Leca


Improvement of some technological and biological properties of poplar wood by impregnation with aqueous macromolecular compounds
1992 - IRG/WP 92-3721
Poplars (Populus spp) belong to the most important tree species in afforestation programs of the Netherlands. Due to their rapid growth, the wood quality is usually low. Therefore, studies were performed to elucidate whether some technological properties and the resistance against fungal attack could be improved by impregnation with water-soluble resins. The results showed that swelling and shrink...
R D Peek, H Militz, J J Kettenis


A suggestion for the improvement of the chemical protection of wooden poles
1987 - IRG/WP 3445
Insufficient drying of white poles in Sweden causes inadequate penetration of the impregnation compounds, CCA salts and creosote, in a varying proportion of the treated poles, and with pretreatment decay present, sooner or later, internal fungal attack in the ground-line zone of the standing poles is the result. The application of a diffusing fungicide in the ground-line zone in connection with th...
H Friis-Hansen


The multi-phase pressure (MPP) process. One stage CCA treatment and accelerated fixation process - Concepts proved by repetitive pilot plant treatments
1997 - IRG/WP 97-40079
Twenty-four charges of radiate pine roundwood or sawn timber were treated using the MPP Process and hot CCA solution. Treated timber met the CCA retention and penetration requirements of the NZ Timber Preservation Council for Hazard Classes H3 to H5. The objectives of the trials were: (1) To "stress" CCA solution by repetitive heating, treating and cooling to determine its stability in the process...
A J Pendlebury, J A Drysdale, K Nasheri, H Pearson, M E Hedley


Improvement of wood decay resistance by tannin impregnation
1991 - IRG/WP 2380
The fungical effect of tannins is appraised after exposure of treated woods samples to wood rotting fungi. A screening-test is carried out with several solutions containing extracts of two kinds of tannins; a condensed tannin derived from Quebracho heartwood (Schinopsis sp.) and a hydrolyzable one extracted from chestnut heartwood (Castanea sativa Mill). If a fungicidal action was indeed found it ...
D Dirol, A Scalbert


Test of N-tritylmorpholine in combination with synthetic pyrethroids against marine borers in tropical Australia and Panama
1991 - IRG/WP 4168
Test blocks ol Pinus sylvestris sapwood were pressure impregnated with white spirit solutions of N-tritylmorpholine, either alone or in combination with permethrin, deltamethrin or cypermethrin. They were exposed in the intertidal zone at Mourilyan Harbour, North Queensland, Australia and subtidally at either end of the Panama Canal. After 5 months' exposure at Naos Island at the Pacific ...
S M Cragg, J D Bultman


The influence of soil pH on leaching of CCA elements from pressure-treated Eucalyptus saligna sapwood: environmental implication
2003 - IRG/WP 03-50203
Evidence is accumulating as to poor distribution and fixation of CCA in tropical hardwoods, and there is therefore a necessity to investigate the permanency of CCA in tropical hardwoods. The relationship between soil pH and leaching of Cu, Cr and As from CCA pressure-treated sapwood of Kenyan-grown Eucalyptus saligna was tested under laboratory conditions. Small sapwood samples were pressure-tre...
R Venkatasamy, D N Okwara


Properties of hot oil treated wood and the possible chemical reactions between wood and soybean oil during heat treatment
2005 - IRG/WP 05-40304
Thermal treatment with hot oil as the heating media based on the original idea from oil-heat treatment in Germany was investigated. The treatment was mainly carried out at 200ºC and 220ºC for 2 hours and 4 hours, and the wood species were mainly spruce and fir. This paper focuses on the difference between soybean oil and palm oil and the possible chemical reactions between wood and soybean oil. ...
Jieying Wang, P A Cooper


Internal pressure monitoring during the treatment of Pinus radiata (D. Don)
1995 - IRG/WP 95-40049
The use of micro-transducers to monitor the internal pressure of wood during treatment is investigated. The rates of pressure transfer in radiata pine sapwood and heartwood are compared during Bethell treatment with copper chrome and arsenic preservative. The effect of pre-conditioning treatments are also evaluated using micro-transducer monitoring. It is anticipated that knowledge of the changes ...
P R S Cobham, P Vinden


Probing red maple pit membrane pore size at FSP and OD using polystyrene macromolecules
2001 - IRG/WP 01-40217
A modified solute exclusion technique was used to pressure impregnate a polystyrene molecular weight (MW) series dissolved in styrene into red maple samples at approximately the fiber saturation point (FSP) and oven dry (OD). Radial penetration was less than tangential and FSP less than OD. There was a marked penetration change with MW in the tangential direction, although there appeared to be a ...
A Omidvar, M H Schneider, A R P Van Heiningen


Commercial potential of the four-cycle method for the impregnation of green beech sleepers in Yugoslavia
1975 - IRG/WP 347
This paper was presented to the Conference on Wood Protection held in Sarajevo (Yugoslavia) in 1973. The paper was based partially on the report prepared by J. Struhar and G. F. Franciosi, who were appointed in 1972 as FAO consultants to demonstrate the new impregnation process for green beech sleepers in Yugoslavia. The so-called 4-cycle method was developed at the State Forest Research Institute...
N Vidovic


Influencia de la impregnación con soluciones tánicas en la estabilidad dimensional de la madera de Pinus pinaster Ait. procedente de España
1992 - IRG/WP 92-3686
En virtud de la importancia que presenta la madera de Pinus pinaster Ait. en el sector constructivo español, se ha sometido a esta a tratamientos en autoclave con distintas soluciones tánicas naturales y artificiales a fin de estudiar su incidencia en la estabilidad dimensional frente a exposiciones exteriores. En el estudio se pone de manifiesto el efecto creado por el tratamiento protector en ...
J A Rodríguez Barreal, J Cubillo Jordan de Urries, L Garcia Esteban


Application of roller-pressing method to the novel liquid impregnation treatment of green timber
2001 - IRG/WP 01-40198
A transverse compression technique enabled us to impregnate liquid into green timber through replacement of the free water in the timber with a treatment liquid without any critical physical damage to the timber by the roller-pressing method. The roller-pressing is supposed to remove free water the cell cavities and to concurrently introduce the treatment solution into green timber in the treatmen...
M Inoue, K Adachi, K Tsunoda, Y Imamura, S Kawai


Improvements of stability and durability of beechwood (Fagus sylvatica) by means of treatment with acetic anhydride
1991 - IRG/WP 3645
In the present investigations, beechwood (Fagus sylvatica) was treated with non-catalysed acetic anhydrid at 120°C and some physical- and biological parameters of the treated wood were compared with those of non-treated wood. The radial and tangential shrinkage and swelling, respectively, and the absorption capacity of the acetylated wood against moisture is considerably lower. The durability aga...
H Militz


Preliminary results of the treatment of wood with chlorosilanes
1981 - IRG/WP 3172
It is clear from the initial data reported here that the treatment of pine sapwood with chlorosilanes under the reaction conditions employed did not significantly reduce the decay by both white rot and brown rot fungi. Only the dichlorosilane compounds showed to possess some protective action against fungal attack. Before drawing conclusions on the application of organosilicon compounds as potenti...
M Stevens


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