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Chemical modification of cellulose nanofibrils for tailoring properties of composites
2022 - IRG/WP 22-40934
Due to its natural abundance, complete biodegradability and excellent properties, cellulose is one of the most promising materials for the production of bio composites, as well as one of the most promising fillers for biodegradable polymer composites. This is also true for nanocellulose. A large number of hydroxyl groups on the surface of fibers or fibrils enables a whole series of chemical reacti...
I Poljanšek, J Levanič, V Ž Bogataj, V Vek, P Oven


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Improvement of durability of Scots pine against termites by impregnation with citric acid and glycerol followed by in situ polyesterification
2023 - IRG/WP 23-30777
Scots pine (Pinus sylvestris) sapwood samples were impregnated with solution containing citric acid (CA) and glycerol (Gly) followed by heating 140 °C according to already described procedure (L'hostis et al. 2018). The resulting modified woods were then used to evaluate the effect of chemical modification on the durability against termites. Two kinds of experiments were conducted for this purpos...
M Mubarok, J Damay, E Masson, E Fredon, Y S Hadi, I W Darmawan, P Gerardin


The influence of chemical and thermal modification on homogeneity between sapwood, heartwood, and transition wood of short rotation teak
2023 - IRG/WP 23-40961
Short rotation teak wood has low quality especially in durability. Heartwood presents sufficient natural durability and poor impregnability; meanwhile, most sapwood requires special treatment to increase its durability. The objective of this work was to investigate the effect of thermal or chemical treatment on homogenization between sapwood, heartwood, and transition wood for some selected proper...
R Martha, B George, W Darmawan, P Gerardin


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


X-ray fluorescence microscopy of copper ion distribution in decay of copper-treated wood by Fibroporia radiculosa
2024 - IRG/WP 24-11047
Copper is an essential metal ion for eukaryotic life and must strictly be regulated as excess levels can cause oxidative damage, enzyme inhibition and denaturation, interruptions in nutrient transport and even cellular death. Copper-based wood treatments have efficacy against a wide range of biological organisms including decay fungi and are used in the majority of preservative formulations for ou...
K M Ohno, J Jakes, A B Bishell, L Li, Q Jin, E Maxey


X-ray micro-computed tomography of copper distribution in CA, ACQ and MCA treated wood and changes in microstructure of ACQ-treated southern pine following natural weathering
2024 - IRG/WP 24-20707
We hypothesized that X-ray micro-CT would be able to visualize: (a) the distribution of copper in CA-treated southern pine; and (b) microstructural changes in ACQ-treated southern pine exposed to natural weathering. Small blocks were removed from southern pine samples treated with CA and also southern pine treated with ACQ and MCA. Small blocks were also removed from ACQ-treated boards (flat and p...
D Feng, M Turner, P D Evans


Studies on the treatability of selected pine species and corresponding efficacies of a new non-biocidal treatment
2024 - IRG/WP 24-20721
Wood decay caused by fungi may reduce the service life of wood in outdoor applications. Since moisture conditions in wood occur as one of the most crucial parameters for fungal decay, chemical modifications, which affect the latter, may increase the resistance of wood against such organisms. Usually, pine sapwood is easier to chemically treat than heartwood, as the former generally shows good perm...
T R da Silva Lins, L Emmerich, H Militz, P H Gonzales de Cademartoni, R J Klizke, M Pereira da Rocha


Physical, durability and chemical characterization of Gmelina arborea (Roxb.) wood treated with lactic acid
2024 - IRG/WP 24-30803
The increase in demand for durable wood has drawn attention to the use of fast-grown plantation species across the globe. Chemical modification was used to treat Gmelina arborea wood with lactic acid for property enhancement. The treated samples were obtained from two different ages of 15 and 10 years and sawn into (20 x 20 x 60) mm and (20 x 20 x 20) mm for physical, durability and chemical chara...
T O Akinwamide, J M Owoyemib, E A Iyiolac


Leaching and chemical redistribution of CCA components in refractory heartwood of E. nitens
2024 - IRG/WP 24-41011
Chromated Copper Arsenate (CCA) is a wood preservative widely used to protect against fungal and insect attack. The fixation mechanism of CCA involves complex chemical reactions, including the reduction of chromium (VI) to chromium (III) and the formation of insoluble complexes. Despite fixation efforts, a portion of CCA components tends to leach from treated wood, influenced by factors like wood ...
J R Vargas, L Yermán, K C Wood, T Singh


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