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FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


Recent findings clarifying the mechanism of brown-rot decay protection in acetylated wood
2018 - IRG/WP 18-40827
This paper summarizes the findings obtained during my PhD research over the past three years. The results provide insights which help to understand the enhanced brown-rot decay resistance of acetylated wood with particular emphasis on the role of water. The protection acetylation provides is derived from moisture exclusion within the acetylated cell wall, but the exact mechanism by which water is ...
G Beck


A Conceptual Review of Young People’s Perceptions about Wood
2018 - IRG/WP 18-40836
This article was adapted from the previous study “Young People’s Perceptions about Wood” prepared by Usta (2017), and extended through the development and evaluation of the initial data in terms of the conceptual framework regarding the descriptions of wood by young people. Because it was highlighted by previous study that the university students as the full members of society have the aware...
I Usta


Chemical defense of trees and wood natural durability: from protection to valorization
2019 - IRG/WP 19-10943
Natural durability of wood is defined as “the inherent resistance of wood against various wood-destroying organisms” (European standard EN 350-1). This property is due in particular to heartwood extractives. However, the wood natural durability is included in a wider defense system, and other organs such as bark and roots also host protective compounds. Studying the mechanisms on which global ...
E Houel, D Stien, N Amusant


Determining the natural durability on xylarium samples: mini-block test, wood powder and chemical profiling
2019 - IRG/WP 19-10944
Xylaria, or wood collections, can be considered sleeping beauties in terms of wood technological and biological output. In this study we focus on determining the natural durability of xylarium specimens from the Federal Xylarium in the Royal Museum for Central Africa. The Federal Xylarium contains over 80,000 specimens, covering more than 13,000 species, mainly from Central Africa. These specimens...
V Deklerck, L De Ligne, J Van den Bulcke, E Espinoza, H Beeckman, J Van Acker


Coula edulis baill an unknown wood species as an alternative to the main durable wood species used in Gabon
2019 - IRG/WP 19-10945
The Congo Basin hosts an exceptional biodiversity of trees, flora and fauna. However, the immense natural heritage of the forests in this area is increasingly threatened by many anthropogenic factors, due to selective exploitation of certain wood species. In Gabon, whose ecosystem is representative of this area, the forest represents nearly 80% of the national territory. Only a minority of wood sp...
C S A Bopenga Bopenga, S Dumarçay, P Edou Engonga, P Gerardin


Quantifying the effect of microclimatic parameters on the moisture-induced decay risk of wooden structures
2019 - IRG/WP 19-20649
Wood exposed outdoors is prone to fungal degradation. Besides its material-inherent resistance, numerous factors are impacting on its service life with both, climate and design having a major effect. In addition, topography, shading, wind barriers, and other local parameters have an effect on the microclimatic conditions at site and therefore need to be quantified for service life prediction of wo...
L Emmerich, C Brischke


Chemical composition, antitermite and antifungal activity of Dacryodes edulis oleoresin
2019 - IRG/WP 19-20653
Damages to wood structures and other cellulosic materials caused by wood destroying insects and fungi are estimated to several billions of dollars each year in the world. Among these, termites are considered as one of the most economically important pests for wooden structures. In the past, several wood protection chemicals like CCA, creosote, lindane or pentachlorophenol have been used. However, ...
W F Bedounguindzi, K Candelier, P E Engonga, Se Dumarcay, M-F Thevenon, P Gerardin


Impact of water holding capacity and moisture content of soil substrates on the moisture content of wood in terrestrial microcosms
2019 - IRG/WP 19-20662
Terrestrial microcosms (TMC) are frequently used for testing the durability of wood and wood-based materials as well as the protective effectiveness of wood preservatives. In contrary to experiments in soil ecology sciences, the experimental set-up is usually rather simple. However, for service life prediction of wood exposed in ground, it is of immanent interest to better understand the different...
C Brischke, F L Wegener


Chemical Analysis of Southern Pine Pole Stubs Sixty Months Following Treatment with a Methylisothiocyanate-Based Solid Fumigant Stick
2019 - IRG/WP 19-30740
Methylisothiocyanate-based fumigants have been commercially used in the United States for over 35 years to control internal decay in utility poles and other wooden structures with little technological advancement. The most recently commercialized methylisothiocyanate-based fumigant is chemically known as dazomet. Dazomet is a free-flowing powder or granule that decomposes in the presence of mois...
D J Herdman, T Pope, R R Browning


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Monitoring of the building made of CLT in Ljubljana
2019 - IRG/WP 19-40860
Wood is one of the most important construction materials and its use in building applications has further expanded in recent decades, predominately due to development of the modern composites, like cross-laminated timber. In order to enable even more extensive and reliable use of wood in outdoor applications, factors affecting wood’s service life need to be understood. It is well known that fung...
M Humar, D Krzisnik, B Lesar, N Thaler, B Dujic


Chemical composition and performances of slow pyrolysis by-product from sugarcane bagasse for wood protection
2020 - IRG/WP 20-30752
Pyrolysis distillate or bio-oil, a by-product of biomasses’ slow pyrolysis in the char-making process, has been traditionally used as bio-pesticides by Asian farmers. Due to its large composition of bio-active chemicals, bio-oil obtained from various biomass has become of interest in many applications, including wood protectants. This study aims to characterize the chemical composition of bio-oi...
F D Boer, M-F Thévenon, J-M Commandre, M Fournier


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Evaluation of chemical densification of three hardwood species through in-situ electron beam polymerization
2020 - IRG/WP 20-40893
Hardwoods are the most suitable species for wood flooring for their appearance as well as their hardness. Yet, improving hardness can provide substantial benefit for the wood flooring market. Chemical densification of wood and in-situ polymerization through electron beam technology was chosen to increase hardness of three hardwoods (Yellow birch (YB) (Betula alleghaniensis Britt.), Sugar maple (SM...
J Triquet, P Blanchet, V Landry


Impregnation of railway sleepers - Investigation of a system-sleeper as an alternative for creosote treated sleepers
2020 - IRG/WP 20-40896
For nearly 200 years wooden railway sleepers are impregnated with creosote. After initially using vacuum pressure processes for impregnation, empty-cell processes have been developed quickly and are used until today. Because of political developments, creosote will probably be banned on the European market in the near future. The Fürstenberg-System-Sleeper, which combines for Europe innovative as...
M Starck, A Heidel, C Brischke, H Militz


Comprehensive protection of timber in seawater
2020 - IRG/WP 20-10970
The hazard of wood in seawater can be divided into two areas: Below the water level, shipworm (Teredo navalis) and gribble (Limnoria lignorum) can attack non-resistant or insufficiently protected wood; above the water level, there is a risk by wood-destroying fungi and, to a lesser extent, insects. In a national project funded by the Deutsche Bundesstiftung Umwelt (DBU, German Federal Environmenta...
E Melcher, J Müller, T Huckfeldt


The influence of chemical compounds on wood cell wall to surface cracks
2020 - IRG/WP 20-40908
Degradation due to cracking and dimensional changes caused by drying, have a significantly negative impact on the preservation and durability of wood. Therefore, the prevention of surface cracking, which tends to occur during the drying process, is vital. High temperature set drying is one of the most effective methods for preventing wood surface cracking. It begins with softening the wood at a hi...
R Suzuki, Y Mori, K Yoshihiro, K Yamashita, M Kiguchi


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


Chemical composition of agarwood of Aquilaria crassna Pierre ex. Lecomte induced by Basidiomycetes from French Guiana
2022 - IRG/WP 22-10988
Aquilaria trees subjected to stress induce the formation of a transformed wood named agarwood. The formation of agarwood is a plant defense mechanism that occur in complex interactions with environmental microorganisms. Agarwood chemical compounds are mainly chromones and oxygenated sesquiterpenes such as eudesmol, agarospirol, jinkoh-eremol and valerianol, which are valued in perfumery. Its deriv...
C Zaremski, M Ducousso, C Andary, G Michaloud, C Menut, A Zaremski, N Amusant


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