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Rapid analysis - chances and limitations
1999 - IRG/WP 99-50130
The reuse of wood out of service in the particle board industry demands a proper handling and separation of assortments with differing content and nature of preservative. A pre-selection based on visual and olfactorial characteristics can be carried out for certain assortments like sleepers, poles, etc. Problems arise from diffuse and less intensive treated wood which is regularly dip-treated or b...
A Peylo, R-D Peek


Effect of wood species on decomposition efficiency of metham sodium
1992 - IRG/WP 92-3699
The effect of wood species and temperature on efficiency of metham sodium (32.1% sodium N-methyldithiocarbamate) decomposition to methylisothiocyanate (MITC) was investigated on 10 hardwoods and 9 conifers over a 144 hour period. Gas chromatographic analyses of headspace samples and ethyl acetate extracts of the wood revealed that decomposition never approached the theoretical decomposition effici...
J J Morrell


Unsuitability of the limiting dose as a criterion for assessing the toxicity of preservatives to wood-destroying fungi
1974 - IRG/WP 243
In the majority of methods for investigating preservatives for wood-destroying fungi their toxicity is assessed by determining what is called the "limiting dose". This normally denotes a range of preservative solution concentrations or retentions of dry preservative in the timber, the lower value serving to indicate the amount of preservative at which is observed the expected effect, e.g. the grow...
D A Belenkov


Effects of alkali treatment on some mechanical and chemical properties of creosote treated oaks
1991 - IRG/WP 2366
To date, there is a lack of information on the effects of chemical treatment on the performance of creosote preservative treated oak sleepers. This factorial experiment was designed to analyze three main effects: species (Quercus alba and Quercus rubra) creosote treatment (treated and untreated), and alkali (NaOH) soaking (0, 1, and 10 percent). The modulus of elasticity (MOE) and fiber stress at ...
P Chow, A J Reinschmidt, E J Barenberg, L C Chang


Analysis of D-glucose metabolism of wood decay fungi using 13C-NMR and 13C-labeled substrates
2003 - IRG/WP 03-10475
D-Glucose metabolism is thought to be important during wood decay by fungi, not only for anabolic and catabolic purposes of central metabolism, but also as a potential source of peroxide required by extracellular peroxidases. There has been some confusion in the literature as to whether this peroxide-generating activity is of the glucose 1-oxidase or pyranose 2-oxidase (glucose 2-oxidase) type wi...
T H de Koker, M D Mozuch, P J Kersten


Remedial ground-line treatment of CCA poles in service. Results of chemical and microbiological analyses 6 months after treatment
1986 - IRG/WP 3388
CCA-treated poles in service with incipient internal soft rot were remedially treated by inserting borate rods, brushing with a boron/glycol solution and injecting boric acid paste, copper/creosote paste or a commercial product (DFCK paste). The spread of active chemicals in the treated zone as well as the change in microflora have been studied with time. After six months chemicals had spread to m...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Statistical evaluation of 'micro-bending' samples for classification of wood attacking fungi
1992 - IRG/WP 92-1544
Micro-specimens from both hardwood and softwood were exposed to selected species of field isolated fungi. The strength reduction and weight loss caused by these fungi were determined. A statistical procedure was then developed to classify the fungi into brown-, white-rot, or non-decay fungal categories based on these data. The procedure reveals the extent of hazard a fungus poses to wood members. ...
B Goodell, Jing Liu, A Homola, J Jellison, J Shottafer


Analysis of water repellents in wood treated with water borne formulations using FTIR
2000 - IRG/WP 00-40176
The use of aqueous water repellent emulsion formulations has increased significantly in the wood treatment industry. These products are primarily used to enhance the weathering characteristics of wood products treated with water borne preservatives systems used in exterior above ground applications. They are also used in pole treatments to improve climbing characteristics and in low VOC millwork t...
P J Walcheski, L Jin


Copper naphthenate-treated Southern Pine pole stubs in field exposure: - Part 1: Gradient & biodeterioration analysis 12 years after treatment
2000 - IRG/WP 00-30242
Naphthenates have been used for the preservation of timber and cellulose since their original identification in Russia in the early 1880's as part of a series of petroleum characterizations. Later work in the development of copper naphthenate as a heavy-duty preservative for poles led to the development of various treating cycles similar to other oil-borne systems. Recent work concerning ...
H M Barnes, M H Freeman


Determination procedure for wood preservatives in waste wood - statistics of sampling and analysis
1998 - IRG/WP 98-50121
In a RTD research programme funded by the German Federal Environmental Agency (UBA - Report No. 126-06-010103) a standardised and validated procedure was developed for sampling and analysing wood preservative components in waste wood. For this investigation a realistic quantity of waste wood from house demolition was used and 80 components analysed. The examination of single wood pieces and woodch...
P Stolz, J Krooss, U Thurmarm, R-D Peek, H Giese


Preservative treatment and field test monitoring of spruce pole stock: Pressure and diffusible chemical treatments
1990 - IRG/WP 3605
One hundred and forty four spruce (test species) and southern yellow pine (reference species) poles were variously treated by center boring, incising, or kerfing, followed by pressure treatment with CCA and/or diffusible preservatives. The diffusible preservatives included NaF/creosote, borax and ammonium bifluoride. The poles were set at a test site and evaluated for preservative distribution and...
B Goodell, A J Pendlebury


FIPRONIL - une nouvelle molécule insecticide Rhône Poulenc pou le PCO et la protection du bois [FIPRONIL - A new insecticide from Rhône Poulenc for PCO and wood preservation]
1995 - IRG/WP 95-50040-16
We will explain here after the advantages and key points of the new insecticide "FIPRONIL" from Rhône Poulenc Agrochemicals. We will have a look from the physical and chemical properties to the possible uses in PCO and wood preservation, including toxicology, efficacy and the main beneficial impacts on the environment. FIPRONIL, a new solution against undesirable and damageable insects, from cock...
M G E J Van Maanen


Application of (n-a)-radiography for determination of boron in wood impregnated with boron-containing antispetics
1975 - IRG/WP 351
The method of (n-a)-radiography for quantitative determination of boron is based on creation of defective regions (tracks) in a polymer (the detector), which form during passage of a particles through the detector, these particles being produced in the reaction 10B(n, a)7Li when the test specimen in contact with the detector is irradiated with neutrons. Etching of the detector with an appropriate ...
N A Dubinskaya, M Ya Tsel'millere


Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz


An evaluation of chemical pre-treatments for controlling kiln brown stain in radiata pine
1997 - IRG/WP 97-30124
Clear radiata pine (Pinus radiata D. Don) is widely used for fine millwork owing to its attractive light colour. However, kiln drying of radiata pine sapwood often results in the development of a brown stain causing substantial loss in revenues in New Zealand's high-value export markets. In this study chemical pre-treatments were evaluated for their ability to control the formation of kil...
B Kreber, A McDonald


Comparative studies on the species effects of wood preservatives
1989 - IRG/WP 3521
For the examination of the resistance against fungal attack, wood blocks of 3 softwood species were treated with CCA (type 3), CFK, AAC and IF-1000 independently. The wood blocks were exposed to the fungal decay with Tyromyces palustris. The degradation of the wood blocks treated with these preservatives was quite widely different among wood species examined in this study. Hem-fir treated with CCA...
K Yamamoto, S Matsuoka


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Effectiveness of the new chemical wood preservative Borosol 9? against a house longhorn beetle Hylotrupes bajulus
2004 - IRG/WP 04-30355
Chemical wood preservative Borosol 9, consisting of boric acid - alkanolamine complex, is a new wood preservative with proven efficacy against wood decay fungi. However, we were interested in its efficacy against larvae of house longhorn beetle (Hylotrupes bajulus). Thus, experiment according to the EN 46 procedure was performed. Specimens made of Norway spruce wood (Picea abies) were ...
G Babuder, M Petric, F Cadež, M Humar, F Pohleven


Suitability of cyfluthrin in wood protection
1992 - IRG/WP 92-3735
Cyfluthrin, a well-known and in agriculture and household widely used insecticide based on synthetic pyrethroides, is evaluated now concerning its suitability as insecticide in wood protection. An overview about the physical and chemical properties is given. Test results in accordance with European standards show the high efficacy and broad-spectrum activity of Cyfluthrin against wood rotting inse...
H-U Buschhaus


Quantification of wood decay effects by HPLC analysis
1992 - IRG/WP 92-1576
The present work quantified the effects of the white rot basidiomycetes Coriolus versicolor and Phanaerochaete chrysosporium, and also those of the brown rot fungi Coniophora puteana and Lentinus lepideus, on Pinus patula and Eucalyptus grandis. Wood colonisation was quantified by Kjeldahl nitrogen determinations converted to biomass assays, and degradation was quantified by weight losses produced...
V Singh, M Tarin, G D Shelver, A A W Baecker


Analysis of contaminants in waste wood
2001 - IRG/WP 01-50179
Waste wood is increasingly used as fuel in Sweden. It is of Swedish origin as well as imported, Mainly from Germany and the Netherlands. The major chemical contaminants are surface treatments (paints etc) and wood preservatives. The surface treatments contribute in particular to contaminants of zinc and lead. In some cases zinc has been found to cause severe deposits in the furnaces. Surface treat...
J Jermer, A Ekvall, C Tullin


Laboratory evaluation of chlorothalonil against the Formosan subterannean termite
1992 - IRG/WP 92-1559
The fungicide chlorothalonil was evaluated as a wood preservative to prevent attack by the Formosan subterranean termite, Coptotermes formosanus Shiraki (Isoptera: Rhinotermitidae). Southern yellow pine wafers treated with chlorothalonil (CTL) in P9 oil, CTL + chlorpyrifos in P9 oil, or CTL in xylene were conditioned by evaporative aging at 40° C for 4 weeks and exposed to termite attack in a mod...
J K Grace, P E Laks, R T Yamamoto


Efficacy of anhydrides as wood protection chemicals
1997 - IRG/WP 97-30162
Wood samples treated with anhydrides of various compositions have been examined for their decay resistance and moisture behaviour. For this purpose two brown rot fungi (Coniophora puteana and Gloeophyllum trabeum) and two white rot fungi (Trametes versicolor and Pycnoporus sanguineus) were used in conventional and modified soil block tests. The modified soil block tests conformed to the method as ...
S C Forster, M D C Hale, G R Williams


Modèles de laboratoire et évaluation des risques. Protocole pour l'étude physiqo-chimique et toxicologique de la thermolyse de bois, de matériaux composites et de végétaux arbustifs
1995 - IRG/WP 95-50040-03
Thermolysis of samples is achieved inside an oven called "Fire model", designed to simulate fire conditions. This fire model was previously designed by the LEMD at the occasion of studies carried out for the purpose of toxicity studies on materials in the conditions occurring at the building level. This model essentially a cubic chamber takes into account the energy of radiation reflexed on the wa...
R Capron, E Leghouchi, M Guerbet, E Dittmar, J M Jouany


Pyrolysis GC-MS as a tool for lignin analysis
1987 - IRG/WP 2201
Pyrolysis-GC-MS is a rapid process for analysis of rather complex organic compounds. The method has great application to petroleum shale oil and wood lignin. Small powdered samples (several mg) are placed in silica capillary tubes and rapidly heated in an inert atmosphere such as He or N2. Breakdown products of the pyrolysis are then trapped and held for an allocated time in an injector attached t...
L Doimo


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