Your search resulted in 143 documents. Displaying 25 entries per page.
SEM-EDXA of CCA-treated Rubberwood (Hevea brasiliensis)
2009 - IRG/WP 09-20399
The microdistribution of chromated copper arsenate (CCA) preservative in rubberwood was studied using scanning electron microscope in conjunction with energy dispersive X-ray analyzer (SEM-EDXA). Bulk X-ray analysis showed that there was a high accumulation of chromium, copper, and arsenic in the vessels and lower concentration of the three preservative elements in fibres. Chromium appeared to rec...
I Jusoh, D P Kamdem
Effects of concentration and temperature of CCA and CCB on wood strength of Turkish fir (Abies bornmulleriana Mattf.)
2009 - IRG/WP 09-40450
The purpose of this study was to present evidence for the effects of concentration and temperature of solutions of water-borne preservatives (chromated copper arsenate, CCA and chromated copper boron, CCB) on the static bending properties (modulus of elasticity, MOE and modulus of rupture, MOR) of Turkish fir (Abies bornmulleriana Mattf.). Wood samples were mechanically tested after a mild full ce...
I Usta, M Hale
New insights from NMR, FTIR, X-ray diffraction and physical chemistry into digestive processes in the wood-boring marine crustacean Limnoria quadripunctata
2010 - IRG/WP 10-10732
This paper summarises preliminary findings of a multi-technique exploration of the degradation of lignocellulose in the marine isopod Limnoria quadripunctata. Scanning electron microscopy revealed connections between the digestive gland and the hindgut that would permit the exchange of fluids between the two organs while the food mass is retained in place within the hindgut. This enables enzymes t...
G P Malyon, S LaBarre, N Kervarec, P Carey, J McGeehan, X Xie, A Klüppel, S M Cragg
A comparison of the chemistry of alkaline copper and micronized copper treated wood
2010 - IRG/WP 10-30528
This paper discusses the chemistry of the reaction of alkaline copper and micronized copper with wood. The objective of this study is to examine the copper species produced in wood during the fixation reaction using electron paramagnetic resonance (EPR) spectroscopy. The initial experiments (phases 1 to 2) were designed to confirm the effect of time of treatment and solution concentration on the s...
Wei Xue, P Kennepohl, J N R Ruddick
Effects of nano-wollastonite impregnation on fire resistance and dimensional stability of Poplar wood
2012 - IRG/WP 12-40595
The fire-retardant properties of Nano-Wollastonite (NW) in poplar wood (Populus nigra) were determined in this study. Some physical properties such as water absorption, volumetric swelling and Anti-Swelling Efficiency (ASE) were also measured. Specimens were prepared according to the ISO 11925 standard for the fire-retarding properties, and ASTM D4446-2002 standard for the physical properties. Imp...
A Karimi, A Haghighi Poshtir, H Reza Taghiyari, Y Hamzeh, A Akbar Enayati
The chemistry of wood degradation by Basidiomycetes studied in a van Krevelen diagram
2013 - IRG/WP 13-10805
The atomic composition ratios of decayed wood by Basidiomycetes are mapped in a van Krevelen diagram. It is shown that the wood residue after decay is chemically reduced, rather than oxidized. A previously developed and verified theoretical model for thermal wood modification, relating atomic composition ratios to moisture sorption and fungal resistance properties has tentatively been applied to w...
W Willems, H Militz
Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden
The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison
Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master
Chemistry of copper preservative treated wood
2014 - IRG/WP 14-30651
The reaction chemistry of micronized copper wood preservatives is fundamentally different from any previous inorganic preservative system. In order to study the chemistry, analytical procedures had to be developed which allowed the determination of the total copper as well as the copper which reacted with the wood forming copper-wood complexes. With the success of this approach it also became poss...
Wei Xue, P Kennepohl, J N R Ruddick
The potential of 2D NIR imaging for wood protection research
2015 - IRG/WP 15-20566
Investigating wood and wood-based materials using infrared spectroscopy has since long been explored. Recently, image-based systems have been developed that are used in food and pharmaceutical industries for rapid screening. Such hyperspectral cameras are able to collect spatial and spectral information simultaneously, resulting in a volume with a spectral profile for each pixel of the image. We p...
J Van den Bulcke, N Defoirdt, W Li, J Van Acker
Evidence for a role for precipitated copper on the chemistry of micronized copper treatments
2016 - IRG/WP 16-30690
Micronized copper preservative treatments of softwoods, result in mobile copper being formed by reaction of the basic copper carbonate (BCC) with the carboxylic acid functional groups in hemicellulose and pectic substances present in wood. Typically, the amount of reacted copper formed is approximately 0.3% Cu m/m. In this paper, two examples are discussed where remaining unreacted basic copper ca...
Wei Xue, P Kennepohl, J N R Ruddick
Enhancing Our Understanding of Brown Rot Mechanisms through Catalytic Pretreatment and Cellulase Cocktail
2018 - IRG/WP 18-10909
A catalytic mechanism, described as the “chelator-mediated Fenton” (CMF) mechanism, is proposed to mimic the non-enzymatic action of brown rot fungi. A CMF treatment was used together with an enzymatic cocktail to study how wood was deconstructed and solubilized. This was done in-part to determine if the treatment mimicked the action of brown rot fungi, but also to explore improved treatment p...
S Tabor, L Orjuela, D Contreras, G Alfredsen, J Jellison, S Renneckar, B Goodell
Wood chemistry completes natural durability as criteria for shorting best provenances in the improvement of teakwood quality: case of five provenances from Ivorian Séguié’s trial
2018 - IRG/WP 18-10920
In order to determine the best provenance for continuing breeding program in Côte d’Ivoire, five provenances of teak planted in 1970 at Séguié’s trial (Agboville, in the south of Côte d’Ivoire), were compared. Fifteen trees (three trees per provenance) composed the sample. Decay resistance and the chemical content especially, non-structural carbohydrates, total phenolics and quinone comp...
F B Niamke, N Amusant, A A Adima, A A Kadio, G Chaix, C Jay-Allemand
Hydrolytic stabilization of chemically modified Bambusa vulgaris Shrad ex JC Wendl
2018 - IRG/WP 18-40830
The main drawback which greatly limit the utilisation of bamboos is their high moisture intake, biodegradation and physical properties changes with environmental variations. To prevent excessive dimensional changes and improve moisture properties of bamboo, Bambusa vulgaris was chemically treated with acetic-anhydride without co-solvent. To evaluate the influence of acetylation on the moisture pro...
N A Sadiku, S M Akintayo
Thermal performance and fire safety properties of traditional circumferential log-cabin walls
2019 - IRG/WP 19-40872
The paper describes the experiment of fire resistance of a circumferential log-cabin wall fragment using various structural modification of the gap between two log members. The influence of the gap structural modification on the criterion of fire resistance E (envelop integrity) and I (insulation) is evaluated. The evaluating criteria are represented by the development of temperatures measured in ...
S Jochim, L Makovicka Osvaldova, M Zachar, Z Danihelova
Performance of bio-based building materials – durability and moisture dynamics
2020 - IRG/WP 20-20666
When exposed to conditions favourable for decay, bio-based building materials can be susceptible to degradation. Their ability to withstand deterioration over time (performance) depends on the intrinsic or enhanced durability of the material as well as its wetting and drying behaviour. The effect of fungicidal components in wood is known since long. Other material characteristics, such as the mate...
L De Ligne, J Caes, S Omar, J Van den Bulcke, J M Baetens, B De Baets, J Van Acker
Investigating moisture dynamics and fungal decay risk: integrating X-ray CT visualization and simulation benchmarks through a Fungal Control Unit
2024 - IRG/WP 24-11045
Wood is susceptible to fungal attack and over time the structural integrity can be compromised. This risk is of course strongly related to moisture dynamics, as moisture is needed for fungal growth. While existing methodologies, such as lab and field tests, provide valuable insights into wood decay, they often fall short in replicating real-life conditions, particularly within the intricacies of t...
J Van den Bulcke, J Van Acker, M Delbeke, A Blommaert, N Van Den Bossche, M Steeman, L De Ligne