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Microbial decomposition of salt treated wood
1993 - IRG/WP 93-50001-22
Specialized microorganisms which are able to convert fixed inorganic preservatives from treated wood into water soluble components are investigated. A number of brown rot fungi like Antrodia vaillantii have been isolated from cases of damage and examined under unsterile conditions with CCA-, CCB-, CCF- and CC-treated wood at retention levels of at least 50% higher than recommended for wood in grou...
R-D Peek, I Stephan, H Leithoff


Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


Copper storage in the digestive caecae of Limnoria tripunctata and Limnoria quadripunctata (Crustacea: Isopoda) tunnelling in CCA treated and untreated wood in laboratory cultures
1998 - IRG/WP 98-10257
Digestive tract tissues of Limnoria quadripunctata Holthuis and Limnoria tripunctata Menzies, tunnelling untreated and CCA treated Scot's pine sapwood under laboratory conditions were examined using X-ray microanalysis and transmission electron microscopy. Populations of both Limnoria species tunnelling treated and untreated wood stored copper within their digestive caecae in the form of ...
C Wykes, A J Pitman, S M Cragg


Biological detoxification of wood treated with salt preservatives
1992 - IRG/WP 92-3717
The use of microorganisms that are capable to convert chemically fixed inorganic preservative complexes from impregnated wood waste into watersoluble components is investigated. A number of fungi were isolated from deteriorated and initially well-treated wood. They revealed an exceptionally high production of organic acids (pH 2). The fungi were identified and used together with others of the same...
I Stephan, R-D Peek


Studies on the resistance of DMDHEU treated wood against white-rot and brown-rot fungi
2005 - IRG/WP 05-10566
Beech wood (Fagus sylvatica) modified with the textile finishing agent 1,3 dimethylol-4,5-dihydroxyethylen urea (DMDHEU) has shown to improve durability against the white-rot fungus Trametes versicolor. In a mini-block test, the weight loss over eight weeks of incubation decreased with increasing weight percent gain (WPG) of DMDHEU. At 25% WPG, no significant weight loss was observed, while untrea...
P Verma, C Mai, A Krause, H Militz


X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell


Environmental risk assessment of treated wood - A mesocosm study
2005 - IRG/WP 05-50224-8
In order to evaluate the environmental impact of treated poles, we have developed physical models (mesocosms) containing around 250 kg of natural soil and a treated pole. On the top of each mesocosm, a spraying mechanism, which can distribute ultrapure water through several nozzles, was built. On the lower part of each mesocosm, a small tank, which can contain some litres of leachate, was placed...
P Marchal, F Poly


Why did Japan replace CCA by alternatives?
2004 - IRG/WP 04-50215
Since chromated copper arsenate (CCA) was technically introduced into Japan in 1963, CCA was used for extending service life of various wood commodities, especially sill plates (dodai) in Japanese houses. However, the problem on the disposal of CCA-treated wood waste became public and related industry concern, and questionnaire survey conducted by Japan Wood Preservers’ Industry Association ind...
H Ishida, T Ito, M Yamai, H Matsusaka, K Tsunoda


Combustion properties of Alder wood treated with some new environment friendly natural extractives. Part 1. Effect of Natural Tannins on the Combustion Properties
2002 - IRG/WP 02-40234
Powders of the brutia pine bark, sumach leaves, acorn, gall-nut and boric acid and borax which are known as potential environment friendly wood preservatives were impregnated according to ASTM D 1413-88 in order to determine their combustion properties. A commercial treatment compound, Tanalith-CBC, was also used for comparison. The results indicated that the natural extractives did not have an...
Ü C Yildiz, A Temiz, E D Gezer, S Yildiz


Metal Leaching from Pressure Treated Wood in Sanitary Landfill Leachate
2004 - IRG/WP 04-50220
Pressure treated wood products contain heavy metals to prevent biological decay. Scrap treated wood from construction activities and demolished structures containing treated wood are typically disposed in landfills. To examine the potential mobility of metals from pressure-treated wood disposed in landfills, wood samples were leached using leachate from lined landfills and the concentrations of ar...
B Dubey, T G Townsend, H M Solo-Gabriele


Ecotoxicological behaviour of leachates from superficially treated timber as an approach for a test strategy of environmental risk assessment in wood preservation
1998 - IRG/WP 98-50101-09
At present for wood preservatives, which in Germany are subject to the quality mark of the RAL-Gütegemeinschaft Holzschutzmittel, health and safety as well as environmental aspects are evaluated by official authorities, as BgVV (Federal Institute for Consumer Health Protection and Veterinary Medicine) and the UBA (Federal Environmental Agency). From the environmental point of view to day there a...
H W Wegen, U J Lucks


Applications of the shower test. Part A: Results from CCA type C treated wood: influence of fixation process
1993 - IRG/WP 93-50009
This report outlines the results of shower tests conducted on CCA type C treated wood. The results indicate the inherent good fixation of CCA type C, as judged by the leaching limits within the Environmental Regulations. The shower test has proven to be a useful quality control and research test. It determines reasonably accurately the leaching under simulated conditions and, admittedly from a lim...
W J Homan, H Militz, D A Lewis


Co-incineration of CCA-treated wood and Municipal Solid Waste in MSWI plant
2005 - IRG/WP 05-50224-19
The Norwegian Association of Energy Users and Suppliers (Norsk Energi) have carried out incineration tests with addition of 10 % by weight CCA-treated wood waste to municipal solid waste in a MSWI plant. The objective with the test was to determine emissions and composition of bottom ash. The incineration test was done at the Klemetsrud plant in Oslo The main conclusions are: -No significant inc...
D Borgnes, B Rikheim


Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


Recycling CCA-treated poles with Charterm
2005 - IRG/WP 05-50224-17
After 10 years of Research and Development, the first “Chartherm” industrial unit is now operating since nearly half a year, thanks to Thermya SA, engineering company, current owner of all the “Chartherm” process Patents and Rights. In accord with the recycling contracts signed with several French major companies, the “Chartherm” plant, located near Bordeaux, recycles every day severa...
J-S Hery


An example of media response to perceived environmental problems with CCA-treated wood
1990 - IRG/WP 3564
A recent study suggested that CCA-treated wood exposed to acidic precipitation could lose significant amounts of copper chromium and arsenic resulting in loss of efficacy and possible environmental contamination. The study received wide newspaper and radio coverage in Canada, thereby heightening public concern about CCA use. Subsequent studies in our laboratory confirmed that the high losses were ...
P A Cooper


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura


Future Directions Regarding Research on the Environmental Impacts of Preservative-Treated Wood: Environmental Impacts of Preservative-Treated Wood. February 8-11, 2004, FL, USA Workshop – Research Needs
2004 - IRG/WP 04-50222
This paper presents a series of documents that focus on research needs for potential future work focusing on the environmental impacts of preservative-treated wood. These documents were developed through a conference sponsored by the Florida Center for Environmental Solutions (FCES), located in Gainesville, Florida. The conference was held in Orlando, Florida, February 8 – 11, 2004 and the tit...
H M Solo-Gabriele, J D Schert, T G Townsend


Biological resistance of wood treated with waterbased resins and drying oils in a mini-block test
1998 - IRG/WP 98-40107
In recent years it was found that the resistance of wood against fungal degradation could be increased by impregnation with an etherificated melamine formaldehyde resin. Using this resin as a reference, a waterbased fatty acid modificated alkyd-resin and two drying-oils were assessed for their biological performance in a mini-block laboratory test. Although drying-oils, like linseed-oil, are often...
M Sailer, A O Rapp, R-D Peek


Effect of humic acid on leaching of CCA from treated wood
2000 - IRG/WP 00-50151
Laboratory studies indicate that relatively high concentrations (1.000 - 10.000 ppm) of humic acids can increase the leaching of chromium and copper from CCA-C treated wood, and that copper is most affected. They also show that leaching with natural water samples can result in higher leaching of all components than leaching with distilled water. Evaluation of CCA component retentions and mass bala...
P A Cooper, D Jeremic, J L Taylor, Y T Ung


On the occurrence of Phialophora species in preservative treated wood in ground contact
1977 - IRG/WP 163
Phialophora is a fairly large genus comprising about thirty described species. They are widespread in very diverse environments, such as soil, sea water, wood and wood pulps. Some species are known as parasites on plants and animals, including man. Phialophora species were early known for their ability to produce blue stain in timber. Later it was discovered that several species were able to produ...
T Nilsson, B Henningsson


A laboratory study on effect of coating materials on leaching of copper from CCA treated wood
2001 - IRG/WP 01-50176
Components of CCA preservatives can leach into surrounding soil and water and have some effect on germination and growth of some plants. In this report, the effect of coating materials in reducing chemical concentration in the leachate were evaluated. Rubber wood blocks (Hevea brasiliensis) treated with CCA were fixed at room temperature at high humidity. After air dried, they were painted with co...
A Veenin, T Veenin


The relationship between the electrical resistance and fixation of water-borne CCA salts and pressure-treated wood
1991 - IRG/WP 3657
Two investigations at 22°C and 30°C have been carried out. The electrical resistance in the treated wood and chemical analyses of the remaining amount of unfixed copper, chromium and arsenic were investigated. Samples impregnated with water were used as references. To hold the samples moist during the investigation, each sample was wrapped in a polyethylene plastic foil immediately after impregn...
F G Evans, B Nossen


Corrosion of fasteners in treated wood
1971 - IRG/WP 303
Surveying tests for determining the corrosion rates of some metals and alloys in wood untreated as well as treated have been made. It is shown that ordinary steel corrodes faster than other common fastener metals such as copper, brass, aluminium and stainless steel do. Zinc coatings, however, will prevent the steel corrosion effectively provided that the coatings are thick sufficiently. Catalytic ...
T Wallin


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