IRG Documents Database and Compendium


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New Method for Pretreatment of Railroad Crossties
2014 - IRG/WP 14-40675
Creosote has been successfully utilized for nearly 150 years for the protection of railroad crossties (sleepers) in the USA and remains today as the most widely used wood preservative for this application. One of the few shortcomings of creosote as a preservative is its inability to penetrate many of the refractory hardwood species which make up the majority of crossties in the USA. Lack of full...
A S Ross, R W Clawson Jr


Buffered Amine Oxide Treatment Systems for Ammonical Copper Wood Preservatives
2014 - IRG/WP 14-40685
Wood is the most versatile, practical and sustainable building material in the world. In modern countries, wood is a well-managed renewable resource that has a small carbon footprint. Wood does suffer from a lack of durability against invasive organisms such as insects and fungi. Steel, aluminum and composites have emerged as viable alternative building materials. These sectors market the defi...
R W Clawson Jr


Buffered Amine Oxide Treatment Systems for Imparting Water Based Azoles/Insecticides in Douglas Fir and Eucalyptus
2015 - IRG/WP 15-40707
In today’s world, wood remains the most versatile, practical and sustainable building material. In contemporary countries, wood is a well-managed renewable resource that has a remarkably small carbon footprint compared to those of steel, aluminium, composites, and concrete. These alternative materials have continued to emerge as viable building materials given the durability issues of untreate...
R W Clawson Jr


A Treatability Study of Western Wood Species with Water Based Azoles and Insecticides Using Buffered Amine Oxides
2016 - IRG/WP 16-40766
The use of Western U.S. Wood Species remains small in today’s global wood product market when compared to the use of other commercially available softwoods. One reason that other fiber sources, those that may be less naturally durable or exhibit slightly inferior mechanical properties, are utilized is ease of treatment. In an attempt to ensure adequate penetration in commercially important an...
R W Clawson Jr, C N Cheeks, K A Cutler


Amine Oxides for Use in Wood Protection: I. A Formulation Adjuvant and Performance Enhancer for Wood
2007 - IRG/WP 07-30425
Amine oxides have great potential for use in the area of wood protection. This paper highlights the advantages of using amine oxides as a formulation adjuvant and performance enhancer for different azoles. It was found that azoles are readily soluble in aqueous amine oxide solutions and form soluble concentrates. These azole/amine oxide concentrates have excellent storage stability and can be dilu...
Xiao Jiang, L Walker


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Amine Oxides for Use in Wood Protection: III. Penetration Aids for Wood
2008 - IRG/WP 08-30461
This paper highlights the advantages of using amine oxides as penetration aids for quaternary ammonium compounds (quats) and azoles in the area of wood protection. It was found that the use of amine oxide effectively enhanced the penetration and distribution of quats and azoles. For both southern yellow pine (SYP) and Douglas fir wood samples, the addition of cocodimethylamine oxide (Barlox® 12) ...
Xiao Jiang


Borate Redistribution in Glulam in an Above Ground Field Test
2014 - IRG/WP 14-30652
Researchers have refocused on the use of boratesin the wood protection industry in the last two decades due to their broad spectrum effectiveness against fungi and insects, and favourable environmental characteristics. This study was designed to determine borate distribution in a limited number of samples from a large field test of composites protected by a combination of coating and borate treatm...
P I Morris, A Temiz, J Ingram


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Above-ground performance of a buffered amine oxide treatment system against Mastotermes darwiniensis
2016 - IRG/WP 16-10855
Above-ground H2 field tests against Mastotermes darwiniensis were conducted in far north Queensland to assess the efficacy of buffered amine oxide treatments in the softwoods Pinus sylvestris and P. radiata, and the hardwoods Eucalyptus regnans and E. diversicolor. Untreated hardwoods and slash pine bait wood (P. elliottii) were severely attacked or destroyed, while untreated P. sylvestris was mod...
L J Cookson, R W Clawson Jr


Wood Protection Through Diffusion: Dimensional Stabilisation with Amine Oxides
2019 - IRG/WP 19-30747
Wood is a phenomenal construction material. In addition to its great physical properties and its beautiful appearance, it possesses many environmental-friendly virtues like the sequestration of carbon dioxide. It is however subject to dimension changes when submitted to fluctuating moistures levels, which can lead to warps, cracks and the peeling of paints. Many water repellents can slow down the ...
S Pepin, P Blanchet, V Landry


Testing of alkylammonium compounds
1981 - IRG/WP 2152
Following laboratory soil block tests which showed that Bardac 20 possessed a fungicidal threshold similar to that of chromated copper arsenate, treated ponderosa pine sapwood stakes were installed in a field test site near Vancouver, Canada. Two years after installation all the stakes show signs of fungal degradation. Seven stakes have been removed from the test due to total loss of strength afte...
J N R Ruddick


Effectiveness and synergistic effects between copper and polymer betaine
1996 - IRG/WP 96-30097
Different formulations of "Copper Amine" and Polymer Betaine were studied. During laboratory tests a synergism between both active ingredients against soft rot and dry rot has been found. The efficacy against soft rot according to the "BAM method" and the European Standard ENV 807 depends only on the amount of copper. Long term tests in a fungus cellar for determining the relative protective effec...
H Härtner, V Barth


Oxalate production and calcium oxalate accumulation by Gloeophyllum trabeum in buffered cultures
1994 - IRG/WP 94-10075
Most basidiomycetous fungi produce oxalic acid as a result of their metabolic activities and nutrient procurement. There is currently a renewed interest in the role that oxalic acid may play in the decomposition of wood by basidiomycete fungi. It has been observed that although most wood degrading fungi have the capacity to produce oxalic acid, not all of these organisms express this capacity equa...
J H Connolly, J Jellison


Contribution of wood components on the absorption of copper amine
2000 - IRG/WP 00-30216
The contribution of wood components on the absorption of copper amine was investigated. Holocellulose, lignin and xylan absorbed significant amount of copper. The amount of copper absorbed by cellulose was almost negligible. The removal of extractive also decreased the amount of copper absorption. This study clearly indicates the importance of lignin, hemicellulose in the absorption of copper amin...
D P Kamdem, Jun Zhang


Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston


Preservative-efficacy of boric acid-triethanol amine solution against wood-decay fungi
1994 - IRG/WP 94-30050
Laboratory preservative-efficacy tests were conducted using boric acid-triethanol amine (BTEA) solution in accordance with the JIS A 9201 (1991) test method excluding the standard weathering process. Sapwood specimens of Picea jezoensis or Fagus crenata to achieve nominal retentions of 0.40-41.2 kg/m³ of boric acid were exposed to Tyromyces palustris, Coriolus versicolor, Serpula lacrymans or Cha...
S Doi, M Mori, Y Mineki


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick


Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman


Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick


Weathering of copper-amine treated wood
2000 - IRG/WP 00-40155
Copper ethanolamine (Cu-EA) treated southern pine (SP) were artificially weathered with a QUV Weathering Tester. The weathering regime was composed of a continuous UV-light irradiation for 2 hours followed by a water spray for 18 minutes for a total time of 1200 hours. The changes on the surface of the weathered samples were characterized by Fourier transform infrared spectroscopy (FTIR) analysis,...
J Zhang, D P Kamdem


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


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