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Smart hydrogels from low molecular weight amphiphilic compounds: toward a solution to decrease leachability and increase efficacy of boron preservatives?
2012 - IRG/WP 12-30589
A new catanionic system associating amphiphilic carnosine (AlaHisC8) and lauric acid forms supramolecular hydrogel at very low concentration. This gel was investigated and we have checked the validity of the concept of hydrogels utilization to reduce boron leachability and to develop new wood protection treatments. Impregnation with 5% aqueous borax solution (w/w) and 0.3% gelator agent (...
F Obounou Akong, P Gérardin, C Gérardin-Charbonnier


The Effects of Industrial-Scale Heat Treatment and Impregnation with Boron Compounds on Water Uptake and Tangential Swelling of Some Wood Species
2012 - IRG/WP 12-40599
This study evaluated the effects of boron impregnation and heat treatment on water uptake and tangential swelling of spruce (Picea orientalis), pine (Pinus nigra), beech (Fagus orientalis) and poplar (Populus deltoides) wood species. The samples (10 x 5 x 40 - tangential x radial x longitudinal cm) were impregnated with 4 % boric acid and 4 % borax according to the ASTM D-1413 standard method. Aft...
A Can, S Yildiz, Ü C Yildiz


Hydrogels: a solution to reduce boron leachability without reduction of its biodisponibility to wood decaying fungi?
2012 - IRG/WP 12-30602
Products used today for wood protection must fulfill to more and more environmental constraints, such as being of low toxicity in answer to the Biocidal Product Directory, but also to involve waterborne treatments to limit rejection of volatile organic compounds in the atmosphere. Boron preservatives have been described as valuable alternatives for wood protection for non-ground contact applicatio...
F Obounou Akong, P Gérardin, M-F Thévenon, S Parant, C Gérardin-Charbonnier


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Potential for using boron for mitigation of Phytophthora ramorum in Douglas-fir logs
2014 - IRG/WP 14-30643
Phytophthora ramorum is a relatively newly described pathogen present in the forests of Northern California and southwest Oregon in the United States. This organism has an extremely wide host range, including a number of commercial important conifers, among them Douglas-fir (Pseudotsuga menziesii). The continuing expansion of the range of P. ramorum will result in an increasing quarantine area w...
J M Hulbert, J J Morrell E M Hansen


Potential for migration of boron from fused boron rods used as internal remedial treatments of utility poles
2014 - IRG/WP 14-50301
The distribution of boron in Douglas-fir utility poles and in the surrounding soil was assessed over a 54 month period following application of fused boron rods. Boron levels in the wood never reached the levels that might be predicted if diffusion were to produce a uniform chemical distribution, nor did levels in the soil suggest that boron was becoming more concentrated. The results suggest th...
M Konkler, C Freitag, C S Love, J J Morrell, J Renfroe


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Remedial treatment of difficult to access timber in buildings
2015 - IRG/WP 15-40691
The quest to understand remedial treatment for timber framing begun following the ‘leaky building crisis’ in New Zealand which came to prominence in 2000. Several in-situ remedial treatment products are used in New Zealand. However, effectiveness of these treatments is still unclear particularly in situations where not all faces of the timber can be assessed. This research was conducted to det...
T Singh, I Simpson, D Page


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


The durability of manufactured structural building materials
2016 - IRG/WP 16-40718
The projected market potential for Engineered Wood Products such as CLT (cross laminated timber) is very positive however, potential prolonged rain leakage or moisture exposure during construction and in-service could pose considerable concern for its durability and reputation. This research was conducted to assess the decay resistance of CLT and OSB (oriented strand board) in an accelerated trial...
T Singh, D Page


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Five-year evaluation of a field trial of Eucalyptus grandis poles treated with zinc and boron
2017 - IRG/WP 17-30721
Round Eucalyptus wood treatment in sequential stages with inorganic borates and metal salts (zinc sulfate and boric acid+borax) was studied; the aims were to form an insoluble precipitate of zinc borate inside wood and to reduce treatment costs by performing the first treatment by simple ascent and diffusion of the preservative, at the same time as it was sought to impregnate the heartwood. The se...
C Ibáñez, A Camargo, C Mantero, M Rabinovich


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


Brief introduction to a research project on preparations of various paste formulations from boron, fluoride and copper for supplemental treatments
2022 - IRG/WP 22-30759
Wood preservatives to be used for supplemental purposes are present in various forms such as powders, liquids, rods, pastes, or gels. Boron compounds have been receiving a lot of attention in supplemental treatments since they have good mobility in wood. Application of boron compounds via internal treatments is vital to stop decay to be occurred inside the wood since large wood elements are too th...
E E Soytürk, D Bakır, E Terzi, C Köse, S N Kartal


Properties of Iron (II) Sulphate treated Norway Spruce
2022 - IRG/WP 22-30765
Exterior wood is exposed to various environmental factors that cause weathering. Weathering is important primarily from an aesthetic standpoint. However, not all parts of the building are equally susceptible to weathering. Parts exposed to moisture will discolour faster than protected parts, such as wood under roof overhangs. To achieve fast and uniform artificial greying, a surface treatment with...
B Lesar, M Humar, M Škamlec


Suitability of boron preservative treatment of minor species as framing in New Zealand buildings
2023 - IRG/WP 23-30778
The inclusion of alternative species to radiata pine, predominantly exotic species, in the building code (NZS 3602) raises questions as to whether they require preservative treatment and, if so, whether they can be adequately treated using current industry processes. Early research with boron indicated that the dip/diffusion method for green timber would give adequate preservative retention in sa...
D Page, I Simpson, T Singh


Preservative properties of boron-treated paulownia wood
2024 - IRG/WP 24-20729
This research was performed to investigate the preservative retention properties of paulownia wood treated using boric acid/borax at mass ratio of 1:1.8. Different portion of paulownia wood (top, middle, bottom) were used as a sample throughout of this study. In the treatment process, the paulownia wood was dipped in the 1% boric acid/borax solution for 1, 24, 72, 120 and 240 hours to achieve requ...
T Khadiran, M A M Abdullah, S Lipeh


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