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Stabilization of IPBC in wood through the use of organosilicon compounds
2012 - IRG/WP 12-30597
The aim of the research was to increase durability of wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC). The study used a blend of silanes. Biological examination against microfungi was performed to determine resistance of Scots pine wood treated with the tested formulations. Chemical analysis by the Electrospray Ionization Mass Spectrometry (ESI-MS) of water extracts from the leaching per...
B Mazela, W Perdoch


Hydrogels: a solution to reduce boron leachability without reduction of its biodisponibility to wood decaying fungi?
2012 - IRG/WP 12-30602
Products used today for wood protection must fulfill to more and more environmental constraints, such as being of low toxicity in answer to the Biocidal Product Directory, but also to involve waterborne treatments to limit rejection of volatile organic compounds in the atmosphere. Boron preservatives have been described as valuable alternatives for wood protection for non-ground contact applicatio...
F Obounou Akong, P Gérardin, M-F Thévenon, S Parant, C Gérardin-Charbonnier


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Preliminary testing of spiroborate esters as wood preservatives
2013 - IRG/WP 13-30614
Fungicide and insecticide properties of boric acid are known since 30’s of the last century, but high solubility and leachability of inorganic borates limit their use for only applications not directly exposed to liquid water. A number of attempts were made to fixate borate salts into the wood structure but this research topic is still up to date and undiscovered. Water insoluble organoboron est...
D Panov, N Terziev


The Concept of Copper and Boron Synergy: Why Copper Naphthenate and Borates are a Couple Made in Heaven
2013 - IRG/WP 13-30622
Fungicides are often combined for four basic reasons:(1) to widen the spectrum of the fungicidal activity in which to broaden the spectrum of activity, (2) to exploit additive and synergistic activities between actives, and the activities are increased and thereby reducing the needs for the higher loadings of the active in the substrate, (3) to delay the resistance of one of the actives in the for...
M H Freeman


Performance of biocide-free preservative-protective systems modified with organosilicon compounds
2013 - IRG/WP 13-30628
The objective of the research was to determine the influence of organosilicon compounds in preservative-protective systems on the selected properties of pine wood aimed for outdoor use. The investigations were made for biocide-free systems based on alkyd resin and natural oils modified with alkylalkoxy-, amino- and glycidoxysilanes. The special attention was paid on the influence of hydrophobic pr...
B Mazela, P Hochmańska, T Krystofiak


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Potential for using boron for mitigation of Phytophthora ramorum in Douglas-fir logs
2014 - IRG/WP 14-30643
Phytophthora ramorum is a relatively newly described pathogen present in the forests of Northern California and southwest Oregon in the United States. This organism has an extremely wide host range, including a number of commercial important conifers, among them Douglas-fir (Pseudotsuga menziesii). The continuing expansion of the range of P. ramorum will result in an increasing quarantine area w...
J M Hulbert, J J Morrell E M Hansen


Fire resistance of wood treated with potassium carbonate and silanes
2014 - IRG/WP 14-30657
This paper reports on the effect that organosilicon compounds and potassium carbonate and urea (PCU) have on wood flammability. The study focus on reducing wood flammability by promoting char formation through manipulation of the condensed phase decomposition chemistry. Potassium carbonate is known as an effective fire retardant, however it is easily leached out from wood and increases its hygrosc...
B Mazela, M Broda, W Perdoch


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Potential for migration of boron from fused boron rods used as internal remedial treatments of utility poles
2014 - IRG/WP 14-50301
The distribution of boron in Douglas-fir utility poles and in the surrounding soil was assessed over a 54 month period following application of fused boron rods. Boron levels in the wood never reached the levels that might be predicted if diffusion were to produce a uniform chemical distribution, nor did levels in the soil suggest that boron was becoming more concentrated. The results suggest th...
M Konkler, C Freitag, C S Love, J J Morrell, J Renfroe


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Above ground field testing: results of experiments in Brazil after one year
2015 - IRG/WP 15-30660
After the development of new products they need to be field-tested to assess their efficacy under diverse conditions of climate, comparing them with a preservative with proven efficacy. In some testing sites, decay occurs very slowly. The solution would be to bring these tests to locations that are conducive to biodeterioration, like tropical climates. Tropical sites provide higher temperature and...
M F Natale, J M Vidal


The effect of preservative treatment on mechanical strength and structural integrity of wood
2015 - IRG/WP 15-30667
The use of wood for demanding construction applications is increasing in Europe. Wooden constructions are frequently designed of susceptible conifer wood, which is endangered by wood decay fungi in wet applications. Therefore in many cases treating wood with preservatives is unavoidable to ensure the desired service life. However, chemical treatment of wood can result in changes of its mechanical ...
M Humar, D Kržišnik, C Brischke


Antifungal properties of wood treated with IPBC and organosilicone compounds against Coniophora puteana
2015 - IRG/WP 15-30676
The aim of the research was to increase durability of Scots pine wood treated with 3-Iodo-2-propynyl butylcarbamate (IPBC) through organosilicon compounds. The IPBC was combined with organosilicon compounds (alkylsilane and alkylsilane with amino groups) for supporting its antifungal properties. The mycological examination against Coniophora puteana was performed to determine the resistance of woo...
W Perdoch, B Mazela, A Waśkiewicz


Bio-friendly preservative systems for enhanced wood durability - the first periodic report on DURAWOOD
2015 - IRG/WP 15-30677
The objective of the paper is the DURAWOOD scientific project carried out within Polish-Norwegian Research Programme, which lasts from September 2013 till August 2016. The aim of the project concentrates on the developing of a new, eco-friendly and biocide-free wood protective systems as an alternative to traditional, commonly used preservatives or coatings, containing biocides. Several wood prese...
B Mazela, M Broda, W Perdoch, L Ross Gobakken, I Ratajczak, G Cofta, W Grześkowiak, A Komasa, A Przybył


Remedial treatment of difficult to access timber in buildings
2015 - IRG/WP 15-40691
The quest to understand remedial treatment for timber framing begun following the ‘leaky building crisis’ in New Zealand which came to prominence in 2000. Several in-situ remedial treatment products are used in New Zealand. However, effectiveness of these treatments is still unclear particularly in situations where not all faces of the timber can be assessed. This research was conducted to det...
T Singh, I Simpson, D Page


Characterization of waste from Pinus radiata generated during industrial thermal-treatment
2016 - IRG/WP 16-20586
The thermal-treatment is an established chemical-free process to modify wood, improving the durability and physical properties of wood through its service life. During the hydro-thermolysis several reactions from wood components occur, releasing volatile and non-volatile compounds from wood to the chamber. Once the process is accomplished, solid residues agglomerate below the wood load and gaseous...
R Herrera, D Thomas da Silva, R Llano-Ponte, J Labidi


Insight in moisture dynamics of wood treated with organosilicon compounds
2016 - IRG/WP 16-20598
The SILEX project “Improving sustainability of construction materials using innovative Silicon based treatment” is a Life+ project with reference LIFE+11 ENV/BE/1046 and started in April 2013. This project intends to demonstrate that a new class of compounds can be used for wood treatment for an extended service life combined with enhanced new testing methodology. The project aims at demonstra...
J Van Acker, J Van den Bulcke, I De Windt, S Colpaert, S De Rocker, S Salvati, J-P Lecomte


Assessment of the biological durability of wood treated with organosilicon compounds
2016 - IRG/WP 16-30685
The European wood construction market is in need of environmentally friendly wood-based products whose service life meets the expectations of end users. Non-biocidal silicon-based water repellents, which can be applied to different materials, help minimize their vulnerability/susceptibility to liquid water. Consequently, they have the potential of increasing wood’s resistance against decay fungi...
M Kutnik, M Montibus, S Derocker, S Salivati, J-P Lecomte


Evaluation of advanced tannin-boron preservative in unsterile soil-bed tests
2016 - IRG/WP 16-30693
In Europe, boron compounds are facing restrictions, and due to their natural solubility into water, the only way to keep using them for wood protection is to fix them into the wood, at very low level (Obanda et al. 2008). In the meantime, the idea of protecting wood with natural preservatives has been back into favour (Lotz and Hollaway 1988, Nakayama et al. 2001, Singh and Singh 2012). Tannin a ...
Jinbo Hu, Yiqiang Wu, Shanshan Chang, Guangming Yuan, G Tondi, M-F Thévenon


The durability of manufactured structural building materials
2016 - IRG/WP 16-40718
The projected market potential for Engineered Wood Products such as CLT (cross laminated timber) is very positive however, potential prolonged rain leakage or moisture exposure during construction and in-service could pose considerable concern for its durability and reputation. This research was conducted to assess the decay resistance of CLT and OSB (oriented strand board) in an accelerated trial...
T Singh, D Page


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


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