IRG Documents Database and Compendium


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A new approach to the maintenance of wooden railway sleepers. (Final Report)
1992 - IRG/WP 92-3724
The micro-environment of wooden railway sleepers was investigated to assess their condition, to determine the necessary treatment, repair and replacement criteria. In the final report the secondary preservative treatment of wooden sleepers with solid boron rods is discussed; the complete development of an in-situ, non-destructive test method based on structural dynamics analysis is described. The ...
W Beauford, A M Brown, D J Dickinson


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell


Borate diffusion in wood from rods and liquid product. Application to laminated beams
1988 - IRG/WP 3482
In the aim to use borate preservatives (fused rods and boracol) in fields of building construction other than external joineries, tests of diffusion of borate rods and secondary boracol, were carried out on different species of woods exposed to different moisture conditions. Tests were also applied on laminated beams very often subjected to high moisture contents and thus decay of rot fungi. Diffu...
D Dirol


Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick


Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman


Effect of vapour boron treatment on mechanical properties of wood based board materials
1992 - IRG/WP 92-3727
The mechanical properties of Medium density fibre board, Chipboard and Oriented strand board were investigated after treatment to two retention levels of boric acid applied as a vapour phase system. A range of mechanical properties were investigated. The vapour boron treatment does not have any significant effect on most of the mechanical properties of the boards. The exception is a reduction in i...
R Hashim, D J Dickinson, R J Murphy, J Dinwoodie


Assessment of the Inhibition of wood decay fungi by volatile organic compounds identified from Trichoderma spp.
1999 - IRG/WP 99-10302
Previous research identified five volatile organic compounds produced by Trichoderma spp. that may be inhibitory to wood decay fungi. The effects of four of these volatile organic compounds, 2-propanone, 2-methyl-1-butanol, heptanal and octanal were tested over a range of concentrations against four selected wood decay fungi. The fungi were incubated in malt extract broth under appropriate conditi...
S N Humphris, R E Wheatley, A Bruce, C Payne


New boron-based biocides for the protection of wood
2002 - IRG/WP 02-30283
Boric acid and other simple inorganic oxides of boron are amongst the oldest wood preservatives currently in use. Their relatively low toxicity and broad-spectrum activity are just some of their desirable characteristics. The primary disadvantage associated with conventional boron-based preservatives is their lack of permanence in exposed applications. A collaborative project between CSIRO and the...
D G Humphrey, P J Duggan, E M Tyndall, J M Carr, L J Cookson


The effect of chemical treatment on the moisture distribution of Pinus radiata D.Don subjected to wick action
1999 - IRG/WP 99-40135
Radiata pine sapwood stakes were treated with a range of chemicals, including an ammoniacal copper quaternary ammonium compound (ACQ), a copper-chrome and arsenic (CCA) solution and a CCA-oil treatment, potassium linoleate copper linoleate, a paraffin wax and a proprietary alkyd resin. The effect of these treatments on the extent of water absorption and moisture movement through the stakes was inv...
J Hann, P Vinden


Field evaluation determining the toxic effect and diffusion properties of Impel, Improsol and TBTO-capsules in L-joints (spruce) for pretreatment application
1991 - IRG/WP 3641
Bonded joints (L-joints and T-joints) are especially at risk from water absorption (rain, condensation) over bare, unprotected radial wood surfaces (joggle joints). It is therefore quite certain that lasting protection against fungi attack cannot be guaranteed in the long term if the surface of coating is damaged. Therefore, in a field investigation, using L-joints (spruce) over a total period of ...
R Gründlinger, K Messner, O Janotta


Aspects of the fungal degradation of quaternary ammonium compounds in liquid culture
1997 - IRG/WP 97-30160
Didecyldimethylammonium chloride (DDAC) is a quaternary ammonium compound (QAC) that has found use as an anti-sapstain preservative for the transportation of softwood lumber from Canada to overseas markets. However, its use is limited by the knowledge that certain mould fungi seem capable of degrading it. The aim of this research was to gain knowledge about the fungal degradation of DDAC. The effe...
J W Dubois, J N R Ruddick


Emissions from the combusting of boron and fluoride containing wood
1995 - IRG/WP 95-50040-18
The combustion properties of waste wood and wood residues containing wood preservatives were investigated in several test series after having been blended with untreated wood at a ratio of 1:4. The results for CFB, SF and boric salt show that, provided an optimized combustion, the concentrations of the stack pollutants correspond approximately with those found for untreated wood. Only during the c...
T Salthammer, H Klipp, R-D Peek


The Protection of Wood with Oxy-aluminium Compounds
2002 - IRG/WP 02-30286
Wood inorganic composites (WICs) containing aluminium compounds were developed and tested in relation to some essential requirements of preservative treated wood. Four different oxy-aluminium treatments were developed and identified according to the final insoluble compounds formed (sodium aluminate, aluminium hydroxide, magnesium aluminate and aluminium borate) in wood. Vacuum impregnation or dou...
F A Ximenes, P D Evans


Preservative treatment of two bamboo species Borak (Bambusa balcooa Roxb) and Talla (Bambusa tulda Roxb) by Boucherie method
2003 - IRG/WP 03-40262
Bamboo is widely used as a construction material in rural and urban areas of Bangladesh. It is perishable in nature and highly susceptible to the attack of borer, termites and fungi. As a result, bamboo products do not last long. This short life of bamboo is increasing demand thereby increasing pressure on our homestead and natural reserve of bamboo. For this reason, it is needed to make the bambo...
M N Islam, A S M A Huda, A K Saha, S M Mithue


Determination of chlorine-containing wood preservatives in art objects using Micro-XRF
2003 - IRG/WP 03-20266
The applicability of a mobile energy-dispersive micro X-ray fluorescence (μ-XRF) spectro-meter for the analysis of organochlorine-containing wood preservatives in art objects was tested. Information about the relative degree of contamination and the efficacy of detoxification measures with emulsive solvent systems can be gained using the intensity of the chlorine signals. μ-XRF t...
J Bartoll, A Unger, S Krug, K Püschner, H Bronk


Borate-treated food affects survival, vitamin B12 content, and digestive processes of subterranean termites
1990 - IRG/WP 1448
Toxicity of boron compounds was studied by analyzing survival rates and vitamin B12 contents in Formosan subterranean termites, Coptotermes formosanus Shiraki, that were exposed to dietary treatments for 10 days. The dietary treatments applied in moistened cellulose were (a) 0.05% boric acid equivalent (BAE) of disodium octaborate tetrahydrate, (b) 0.05% BAE of anmonium pentaborate plus sodium sul...
L H Williams, S I Sallay, J A Breznak


Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


Laboratory termite testing of copper boron tebuconazole
2000 - IRG/WP 00-20192
The American Wood Preservers' Association laboratory choice and no choice termite test (AWPA E1-97) was performed on a formulation of copper azole, which is comprised of copper, boric acid, and tebuconazole. The formulation tested has a ratio of copper:boric acid:tebuconazole of 25:25:1. So as to examine the impact of leaching, the southern yellow pine wafers were treated with and without...
R F Fox, E A Pasek, J Patel


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


A study of poplar LVL durability improvement:
1999 - IRG/WP 99-40148
The aim of this study was to optimise the durability of LVL panels by adding boron during the gluing process. Poplar veneers (2,6 mm thickness ) were selected by ISORY a French company . Two types of glue were tested : Phenol resorcine and Melamine Urea Formaldehyde. Each of them was mixed with various concentrations of borax (for the first one) and Boric acid(for the second one). Mechanical prope...
B Charrier, V Bridaux, N Fauroux, F Charrier


Tributyltin compounds in wood preservation: Health and safety aspects
1986 - IRG/WP 3396
The toxicity of organotin compounds of the general formula RnSnX(4-n) depends strongly on the type of organic substituent R and on the degree of substitution n. The residues X, not bound through a tin-carbon bond, are however of much smaller influence. Furthermore, there is evidence that hydrolysis of tributyltin esters will occur under environmental as well as under physiological conditions to TB...
H Schweinfurth, P Günzel, H A B Landsiedel, R Lang, R Reimann, C Schöbel, F Siegmund


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