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Above and Below-Ground Depletion of Copper, Chromium and Arsenic from Pinus radiata and Fagus sylvatica at Thirteen Test Sites in New Zealand and Australia
2006 - IRG/WP 06-30402
The objective was to determine the significance of site and wood species on preservative depletion for a copper chrome arsenate preservative (CCA) from 20 x 20 x 500 mm field test stakes after 5.5 and 4.5 years for pine and beech respectively. At least 5 sacrificial stakes were used to produce site means. Site and wood species had a major effect on copper, chromium and arsenic loss from CCA treate...
R Wakeling


Addition of boron compounds and octanoic acid for improvement of biocidal properties and copper fixation at copper-ethanolamine based wood preservatives
2006 - IRG/WP 06-30408
Copper-ethanolamine based wood preservatives became important active substance (formulation) for wood protection, novelty. As copper itself can not ensure sufficient protection against wood destroying organisms and fixation in wood we combine it with other biocides like ethanolamine, boron and octanoic acid. This investigates were performance on spruce wood impregnated with different combination o...
F Pohleven, M Humar


The Development of a novel method to preserve reeds using an environmentally friendly timber preservative and a unique engineering design.
2006 - IRG/WP 06-40335
Reeds are used in the construction of bush lodges in Northern Kwa- Zulu Natal, South Africa. Fungal, insect and ultra-violet damage to these reeds is posing a severe problem. Within a space of two years, the reeds are attacked and have to be subsequently replaced; a time consuming and costly exercise. A novel method has been used to successfully preserve these reeds with an environmentally friendl...
K Govender, K G Moodley


Paintability and gluability of wood treated with arsenic-free and chromium free preservative treatments
2006 - IRG/WP 06-40342
The objective of this project was to study, in comparison with traditional CCA treatment, the paintability and gluability of wood treated with arsenic-free and chromium-free preservative treatments. Four formulations, all certified CTB P+, were selected in accordance with their representativeness of the preservative product market: one CCA reference formulation and three chromium and arsenic free...
L Podgorski, G Legrand


Corrosiveness of metal by copper-based preservatives
2006 - IRG/WP 06-40329
The corrosive rates of 4 types of metal as well as epoxy-coated metal by a variety of preservatives derived from different copper source and ingredients were conducted in this paper. The main results shown that: CCA is less corrosive to red brass and Q235A steel than other copper formulations; Copper-based preservatives such as ACQ and copper azole derived from basic cupric carbonate or cupric hyd...
Ying Zhang, Mingliang Jiang


Assessment of the ease of preservative treatment in the less-valuable Nigerian-grown Ceiba pentandra wood
2006 - IRG/WP 06-40330
The hardwood Ceiba pentandra locally known as “araba“ in Nigeria is rarely used for structural and construction works due to its high dimensional instability, low strength and durability values. Samples (25 x 50 x 600mm) were removed from four green boards (25 x 200 x 3000mm) of this species originating from a natural forest stand in Nigeria. The sapwood and heartwood were differentiated by me...
L Awoyemi, A J Pitman


Furfurylated wood - An alternative to Preservative-treated wood
2006 - IRG/WP 06-40349
Chemically modified wood is currently being marketed as a non-toxic alternative to traditional preservative treated wood (wood impregnated with biocides). Over the last decade the authors have developed modernised processes for wood modified by furfurylation. These new systems do not add metals or halogens to the product, which is important for an environmentally acceptable product. This presentat...
S Lande, M H Schneider, M Westin, J Phillips


The response of the Formosan subterranean termite (Coptotermes formosanus Shiraki) to different boron compounds
2007 - IRG/WP 07-10609
Although boric acid and other boron compounds have been used since the 1800s as insecticides, their mode of action is not well understood. Borate salts, in particular sodium and zinc formulations, are effective wood preservatives and are used extensively in Hawai’i to protect building materials from both drywood (Kalotermitidae) and subterranean (Rhinotermitidae) termites. The Formosan subterra...
M C Gentz, J K Grace


Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Permethrin: A Critical Review of an Effective Wood Preservative Insecticide
2007 - IRG/WP 07-30413
Permethrin is a synthetic pyrethroid used in the wood preservation industry. The generally favorable environmental profile of pyrethroids coupled with their high efficacy led to their wide substitution of the chemically resistant organochlorines dieldrin, lindane, and chlordane formerly used for protection of buildings against wood destroying organisms. Much of the research on performance of perm...
M H Freeman, D N Obanda, T F Shupe


Efficacy of chitosan in combination with GRAS (Generally Recognised As Safe) compounds as a potential wood preservative
2007 - IRG/WP 07-30414
In vitro studies were undertaken to evaluate the synergy between chitosan and selected GRAS (Generally Recognised As Safe) compounds against two sapstain fungi Sphaeropsis sapinea and Leptographium procerum. Bioassays performed on nutrient medium suggested that some of the GRAS compounds tested including sodium benzoate, potassium sorbate and ascorbic acid had a synergistic effect when combined w...
C Chittenden, K Thämelt, T Singh


Silver – The Next Generation Wood Preservative
2007 - IRG/WP 07-30419
The successful introduction and commercial use of products designed to have controlled release of silver ion over long time periods prompted the Silver Research Consortium and the US Forest Products Laboratory to undertake research to see if silver could also be an effective wood preservative to be used in place of chromated copper arsenate (CCA) now prohibited for use in the United States and els...
J R Ellis, K Jayachandran, D Nicholas


Silver as a Wood Preservative Environmental Requirements and Concerns
2007 - IRG/WP 07-30420
The pesticide uses of silver and its compounds fall under the jurisdiction of the United States Environmental Protection Agency (USEPA) under the US Federal Insecticide Fungicide and Rodenticide Act. In addition, many other national and international organizations maintain close observance of the effects of silver in different environments. The US EPA has also issued a specific announcement that t...
J R Ellis


Electrokinetic Accelerated Ingress of Boron After Surface Treatment of Wood
2007 - IRG/WP 07-40372
In this work electrokinetic acceleration of boron penetration after surface treatment is proposed in order to offer an alternative to the often low penetration rates based on diffusion. Electrodialytic experiments showed that boric acid could be transported as negatively charged complexes with tartaric acid in aqueous solutions at pH 4-5. Boric acid could not be transported when tartaric acid was ...
I V Christensen


Use of Moisture Meters with Treated Wood
2007 - IRG/WP 07-40382
Drying wood treated with waterborne preservatives after treatment to near outdoor EMC conditions improves its physical performance characteristics. This is primarily due to the reduced checking, splitting and warping which can occur when wet wood, particularly if restrained from shrinking by being nailed or otherwise fastened, shrinks in use. Monitoring of the drying process, rate, and end point...
W B Smith, Hwan Myeong Yeo, C Stark, B Morey, C Tascioglu, P Schneider, D Herdman, M Freeman


The effect of wood moisture content and rod dosage on movement of boron through Douglas-fir heartwood
2007 - IRG/WP 07-30431
The potential for moisture sorption by boron rods following application to wood to affect subsequent boron diffusion was investigated in small Douglas-fir blocks conditioned to 30, 60 or 90% moisture content (MC). MCs tended to decline over the 180 day test period, but there was no evidence that the rods acted to draw moisture away from the wood. As expected, boron movement tended to increase with...
Y Cabrera, J J Morrell


Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative. Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril


Tropical In-Ground Durability of CCB-treated Keruing and other Structural Sarawak Timbers after 8 – 10 Years Exposure
2007 - IRG/WP 07-30439
The heartwood of 12 mainly low-durability native timber species of Sarawak [4 Dipterocarpus (Keruing) species, Anisoptera grossivenia (Mersawa kunyit), Canarium apertum (Seladah), Dacryodes incurvata (Seladah laut), Dryobalanops oblongifolia (Kapur kelansau), Mesua macrantha (Mergasing), Podocarpus micropedunculatus (Kayu cina), Shorea compressa (Engkabang langgai), and Pterospermum javanicum (Ba...
A H H Wong, Ling Wang Choon


Micro-Distribution of Metals in Wood Treated with a Nano-Copper Wood Preservative
2007 - IRG/WP 07-40360
The microdistribution of copper in southern pine treated with a newly-developed nano-copper wood preservative was examined to determine if it differed from that reported for wood treated with conventional copper-based wood preservatives. Field Emission Scanning Electron Microscopy (FE-SEM) in combination with x-ray microanalysis (EDX) revealed the presence of nano-sized copper and iron particles i...
H Matsunaga, M Kiguchi, P Evans


Effect of barriers on moisture content of treated and non-treated utility poles
2007 - IRG/WP 07-40369
The potential for non-biocidal barriers to slow moisture sorption was investigated using butt treated western redcedar poles immersed in either water or moist soil over a 2 year period. Moisture sorption was initially slowed by the barriers, but openings at the bottoms of the barriers eventually allowed moisture to migrate upward. Moisture levels in wrapped poles eventually reached those found in...
C S Love, J J Morrell


Comparative Laboratory Leaching Test Methods to Study Post-Treatment Storage Period Impacts on CCA Leachability and Fixation in Treated Kempas (Koompassia malaccensis) Heartwood
2007 - IRG/WP 07-20376
Three laboratory leaching test methods were compared to determine the effects of different post-treatment storage fixation periods on leachability/fixation of CCA components from treated kempas (Koompassia malaccensis) permeable heartwood. End-sealed test wood blocks of permeable were treated with CCA to target retention of 5.6 kg/m3, immediately stored to fix at ambient conditions for 0 and 48 ho...
A H H Wong, H C Lai


Durability of some alternatives to preservative-treated wood. Progress report 2: Results from field tests after 5 years’exposure
2007 - IRG/WP 07-30442
A number of alternatives to preservative-treated wood have been tested according to EN 252 (stake test) and a specially designed ground-proximity field test, the latter in Sweden as well as in Hawaii, USA. Seven untreated wood species and four alternative wood treatments labelled as environmentally friendly (acetylation, linseed oil, heat treatment, vinyl polymer) were included in the study. Four ...
M-L Edlund, J Jermer


Potential of some insecticides as wood protectants in South Indian condition
2007 - IRG/WP 07-30447
Wood continues to be one of the most widely used raw materials in spite of the introduction of many modern materials. This naturally renewable resource being an organic matter is amenable to the attack of biodeteriorating organisms. Though some wood species are known for their natural resistance to agents of biodeterioration, their availability is constantly decreasing, besides being too expensive...
R Sundararaj, O K Remadevi, R Muthukrishnan


Developments in Borate Treatment of Canadian Species for Decay and Termite Resistance
2007 - IRG/WP 07-30443
The increased interest in boron treatment of wood over the past 20 years is mainly due to its environmental acceptability, potentially deep penetration in wood, and its efficacy against decay and termites. Based on Forintek’s research in the past two decades, the boron penetration and retention requirements for decay and termite protection in various national and international standards for Cana...
Jieying Wang, P Morris, S McFarling, T Byrne


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