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Fixed Borates Anyone?
2011 - IRG/WP 11-30563
The quest for a borate based preservative system that resists leaching or is “fixed” has long been a research goal. Boron fixation has been attempted with numerous strategies but there have been problems associated with past methods. This paper discusses new fixation systems based on bio-materials and presents up to five year outdoor exposure testing on full-size decks. Generally, the new f...
C R McIntyre, M A Lake


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Moisture protection and performance during 5 years exposure of 19 wood coating systems on a cladding in Vienna
2011 - IRG/WP 11-40561
A cladding with vertical boards of Norway spruce (Picea abies) comprising different coating systems had been exposed to natural weathering oriented south west in Vienna for 5 years. Weathering behaviour of the boards was assessed in intervals and wood moisture content was measured over the first 22 months of exposure. The moisture protective properties of the coating systems were assessed using la...
G Grüll, I Spitaler, M Truskaller


Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact:
2011 - IRG/WP 11-50280
Emerging formulations of preservatives made with micronized basic copper carbonates with azoles and/or quat to control copper tolerant fungi have been used to replace formulations containing soluble copper to reduce the leaching of copper and the corrosion of metal in contact with wood. This study proposes to use laboratory soil leaching test AWPA standard (E20-08) to estimate the amount of copper...
Lei Wang, D P Kamdem


A survey on Bio-Resistance of Oak and Elm in Caspian Sea Water
2012 - IRG/WP 12-20483
Logs of Oak (Quercus castanifolia) and Elm (Zelkova carpinifolia) have been cut to lumbers with dimensions of 300×100×30 mm. The oven dried samples have been impregnated with CCA (Chrome–Cupper-Arsenic). Treated and untreated (natural as a control) woods have been established for 3, 6, 9 and 12 months in Amirabad beach of Behshare under fishing environment. The observation results shows that i...
S M Kazemi


Evaluation of fungal infestation and decay in a simulated use class 3 situation (block test) after some years of exposure
2012 - IRG/WP 12-20487
The so named “block test” was designed as part of the assessment methodology for testing the behaviour of natural and modified wood used under use class 3 (EN 335-2) conditions. The test was developed to expose the wood close to the ground to an environment with high humidity and high biological activity, but not in soil contact. The present study describes the evaluation of fungal infestatio...
A Gellerich, K Röhl, S Adamopoulos, H Militz


Performance superiority of CCA-C treated wooden jetty poles and piles used for 30 years in Bangladesh against marine borers
2012 - IRG/WP 12-30582
Observational study along with previous investigation and records revealed that chromated copper arsenate type C (CCA-C) impregnated southern pine poles and piles of jetty constructed in most vulnerable brackish water in Bangladesh are stable and resistant to attack of all types of marine borers after 30 years of use. It is evident from the service records of other construction materials that CCA-...
A K Lahiry


Effect of an antioxidant on the efficacy of organic wood preservatives in an accelerated soil contact decay test
2012 - IRG/WP 12-30583
In comparison to inorganic wood preservatives, organic biocides in transient carriers are considerably less effective when the treated wood is exposed to soil contact. Various oils are used in some formulations with pentachlorophenol to improve the efficacy. However, use of these oils imparts unacceptable properties to products used in residential applications. Consequently, there is a need to de...
D D Nicholas, J Shi, T P Schultz, L Sites


Corrosion of fasteners in heat-treated wood – progress report after nine years’ exposure outdoors
2012 - IRG/WP 12-40601
The corrosion of common fastener materials now in use - mild steel, zinc-coated steel, aluminium and Sanbond Z-coated steel – has been evaluated after nine years’ exposure outdoors in untreated and heat-treated (thermally modified) spruce (Picea abies). Spruce from south-western Sweden was used. The heat-treatment was carried out in Finland by Stora-Enso Oy according to the ThermoWood process ...
J Jermer, B-L Andersson


Environmental safeness of 60% and 72% concentrated CCA-C solution and paste for wood treatment
2012 - IRG/WP 12-50284
In this study 30-years practical and observational experience of the present author about using of 72% concentrated CCA-C paste for preparing treating solutions and for treating wooden poles, anchor logs and cross arms has revealed that the 60% concentrated CCA-C solution is superior to the 72% concentrated CCA-C paste regarding solubility, homogeneity, cleanliness, treatability, sludge formation,...
A K Lahiry


Biodegration of treated wood waste by native fungal communities of tropical soil in French Guiana
2012 - IRG/WP 12-50285
Woods have been protected with fungicides for a long time, and the effects of these fungicides on soil after being leached into the ground have turned out to be a true environmental issue. It is in this perspective that we are proposing to study fungal communities of these contaminated woods in a purpose of bioremediation. Most of precedent studies have focused on ability of some Basidiomycetes an...
A Zaremski, L Gastonguay, C Zaremski, F Chaffannel, J Beauchêne, G LeFloch


Fixation and leaching characteristics of Malaysian tropical hardwoods treated with CCA-C
2012 - IRG/WP 12-50289
The fixation and leaching characteristics of 8 Malaysian tropical hardwood (MTH) species treated with chromated copper arsenate (CCA-C) wood preservative were examined. The species evaluated were Acacia (Acacia mangium), Bintangor (Calophyllum sp.), Geronggang (Cratoxylon arborescens), Medang (Litsea sp.), Meranti rambai daun (Shorea acuminata), Putat (Planchonia sp.), Ramin (Gonystylus sp.) and S...
S Salim, S Shahomlail, Z Ashaari, Yong-Seok Choi, Gyu-Hyeok Kim


Effectiveness of CCA-C and CCB preservatives after a 30 years stake test
2012 - IRG/WP 12-30606
The objective of this experiment was to assess the durability of four pine species treated with waterborne preservatives. In order to determinate this, a stake field test, following the IUFRO (International Union of Forestry Research Organizations) recommendations, was installed at Experimental Station of Luiz Antonio (21º 32’ S and 47º 42’ W), State of São Paulo, Brazil. Species under t...
I PJankowsky, E S Lepage, C Salvela, J M Vidal, S Takeshita


The effect on moisture content of water trapped in wood joints
2012 - IRG/WP 12-40613
To predict the service life of a structure, a model where the exposure of a structure is compared to its resistance can be used. Which exposure and resistance parameters that are relevant depend on which materials the structure consist of. This approach, with an exposure and a resistance parameter, is similar to the one used in structural engineering where a load (exposure) is compared to the bear...
M Fredriksson, L Wadsö, P Johansson


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Report on COST E37 Round Robin Tests – Comparison of results from laboratory and field tests
2013 - IRG/WP 13-20535
A round robin involving 15 European participants was set up in 2006. The round robin consists of both a field test according to the double layer test method and a laboratory test with two different preconditioning methods. When comparing EN 84 preconditioning (two weeks water leaching) with natural preconditioning (1 year in field, above ground) according to CEN/TS 15397, no significant difference...
M Westin, E Conti, J Creemers, P-O Flæte, A Gellerich, I Irbe, M Klamer, B Mazela, E Melcher, R Möller, L Nunes, S Palanti, L Reinprecht, E Suttie, H Viitanen


Effect of soil contact on reacted copper(II) levels in micronized copper treated wood
2013 - IRG/WP 13-30616
Small 3 to 4 mm thick and approximately 80 to 100 mm long, samples were removed from wood treated with micronized copper quat (MCQ) or micronized copper azole (MCA) and buried full length in a soil bed. Samples were removed after 2, 4 and 8 weeks. The total copper was determined by x-ray fluorescence (XRF) spectroscopy and the amount of reacted micronized copper measured by electron paramagnetic r...
Wei Xue, P Kennepohl, Xingguo Jin, J N R Ruddick


Copper leaching from copper-ethanolamine treated wood during exposure to terrestrial microorganisms
2013 - IRG/WP 13-30621
Copper-ethanolamine based wood preservatives are still the most important solutions for protection of wood in ground applications in Europe. Wood in ground is exposed to variety of organisms, which can act synergistically. In order to simulate these conditions in laboratory, Scots pine (Pinus sylvestris) specimens impregnated with copper-ethanolamine preservative of three different concentrations ...
M Humar, N Thaler, B Lesar


Bioactivity of Eucalyptus camaldulensis essential oil against Microcerotermes diversus (Isoptera: Termitidae)
2013 - IRG/WP 13-30631
Microcerotermes diversus Silvestri (Isoptera: Termitidae) is the most economically destructive wood pest in structures in Khuzestan province (Iran). Chemicals such as essential oils and plant extracts that are compatible with the environment and that have high potential to be used in integrated pest management programs are extremely important. This study evaluated the repellency, contact and diges...
B Habibpour, E Shafiei Alavijeh, A Rasekh


A Vision of the Chilean Treated Wood Industry
2013 - IRG/WP 13-40619
Chile is an important actor in the world wide forestry industry, activity which represents 3,1% of the Gross National Product (GNP). The wood products sector, which includes pulp and paper, is the second source of export in Chile with USD 6,500 millions income per year. Native species are the main forestry source with 15,9 millions has., but the principal commercial activity is based on 2,3 mil...
F J Latorre, T A Hanke


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


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