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Changes in transverse wood permeability during the drying of rimu and radiata pine
1990 - IRG/WP 3636
When softwoods are dried and subsequently impregnated with waterborne preservatives two problems frequently occur, preservative screening of multi-salt preservatives and difficult re-drying. To study the causes, the permeability of rimu and radiata pine wood has been measured along the three principal directions. The radial and tangential permeabilities of the green sapwood of the two species were...
R E Booker


Silica treatments to protect timber from marine borers
2001 - IRG/WP 01-30270
Siliceous timbers such as turpentine (Syncarpia glomulifera) are highly resistant to certain marine borers. Attempts to mimic this resistance by chemical treatment however, have met with limited success. This paper describes the impregnation of Pinus radiata and eucalypt timber specimens with organo-silicate formulations. The treated timber gains a pattern of resistance to marine borers that appro...
D Scown, L J Cookson, K J McCarthy


Treatment and recycle of CCA hazardous waste
1993 - IRG/WP 93-50007
Chromated copper arsenate containing hazardous materials is generated from the manufacture, treatment of the wood, and from the wood itself, after its life cycle. Laboratory treating of these wastes has resulted in materials suitable for recycle or disposal as non-hazardous residues. The extraction, by both acidic and ammoniacal routes, of CCA production and treating plant waste materials has been...
E A Pasek, C R McIntyre


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


The influence of cement and calcium compounds on the performance of CCA preservatives
1983 - IRG/WP 3221
The influence of cement and calcium compounds on the durability of untreated and CCA treated wood is considered. Calcium compounds were found to reduce the toxicity of a CCA preservative to a soft rot fungus at copper to calcium ratios of 1:1 and 1:10 using a cellulose filter paper technique. Further studies are outlined and some possible mechanisms by which cement and calcium compounds may affect...
R J Murphy


Efficacy of a novel copper-based organic solvent preservative in laboratory and fungus cellar tests
1995 - IRG/WP 95-30071
The efficacy of Chemicca 4, a novel copper-based organic solvent preservative, was compared with that of other LOSP in pure culture laboratory decay tests and with that of CCA and TBTO in a fungus cellar exposure. It was markedly superior to copper and zinc naphthenates at equivalent metal retentions in laboratory decay tests, and similar in activity to TBTO. After 60 months' fungus cella...
M E Hedley, P N Maynard


Variation in field test performance of untreated and CCA-treated lesser-known Surinamese wood species
2000 - IRG/WP 00-20213
In Suriname three different field test sites have been used to verify the biological durability of CCA-treated wood and a range of wood species including lesser-known and lesser-used wood species. In total 37 tropical wood species were tested untreated and for 17 of the less durable species CCA-treatments were included as well. Although the three sites are located in the tropical region they diffe...
J Van Acker, M Stevens, L Comvalius


Performance of Preservative Treated Parallel Strand Lumber in Marine Exposures.
2006 - IRG/WP 06-30407
The performance ACZA treated Douglas-fir and CCA southern pine parallel strand lumber (PSL) was studied in marine exposures in Florida or Oregon. While materials treated to retentions below the recommended levels for marine exposure were attacked in Oregon, properly treated panels of either species performed well. Panels treated with these same chemicals and exposed in Florida experienced attack ...
J J Morrell, C S Love, P Merrick


One year performance of graveyard stakes in the Northern Territory of Australia
2006 - IRG/WP 06-30398
This paper presents the one year progress performance of in ground graveyard stakes exposed to numerous termite species and decay fungi in tropical field conditions. The field study examines the efficacy of a new timber preservative formulation developed at the University of Melbourne, Australia. The biocides used in the formulation are fipronil (a phenyl pyrazole) and trimethyl borate. The pre...
B Ahmed, J Hann, S Przewloka, P Vinden, P Blackwell, P Plews


Comparative studies on penetration and retention of CCA (C) and creosote in wood from APHID-killed and sound Kenyan-grown Mexican cypress (Cupressus lusitanica)
2006 - IRG/WP 06-40352
Properties of wood from Kenyan-grown Mexican cypress (Cupressus lusitanica), attacked and killed by the cypress aphid (Cinara cupressi), in terms of density and treatability, were investigated in comparison to the properties of wood from sound trees. Density in small wood samples from aphid-killed trees was found lower than density in samples from sound trees, and reduced with tree age in samples...
R Venkatasamy, F M Opar


Thermal decomposition behavior of CCA-treated wood for safe disposal and the safe recovery of heavy metals through pyrolysis
2006 - IRG/WP 06-50238
If we could estimate the chemical changes in heavy metals by temperature in chromated copper arsenate (CCA)-treated wood during pyrolysis, it is expected that we could solve the environmental problems of heavy metals, which may occur during pyrolysis, and therefore, the thermal decomposition behavior of effective elements of CCA-treated wood was examined to find a safe disposal method. First, CCA-...
Dong Won Son, Dong-heub Lee, Sun-hae Cheon, Myung Jae Lee


Leaching of CCA from Paraserianthus falcataria panels exposed to field conditions at Krishnapatnam harbour, Andhra Pradesh
2006 - IRG/WP 06-50241
This study assessed the leaching of copper, chrome and arsenic (CCA) from Paraserianthus falcataria (=Albizia falcataria) panels exposed to marine condition at Krishnapatnam harbour on the east coast of India. Metal loss was assessed in test panels after 6, 12, 24 and 36 months of exposure using Atomic Absorption spectrophotometer (AAS). The metal loss was found slightly higher in panels treated ...
B Tarakanadha, K S Rao


A Prediction of Arsenic Groundwater Concentrations Influenced by Construction and Demolition Debris Landfills in Florida Containing CCA-Treated Wood
2006 - IRG/WP 06-50242
Groundwater fate and transport models can provide an indication of the potential impacts of arsenic from the infiltration of leachate from unlined C&D debris landfills containing CCA-treated wood. A solute transport model, Migration of Organic/Inorganic Chemicals (MYGRT), was chosen to predict groundwater contaminant concentrations at specified locations from a hypothetical source (C&D lan...
J Jambeck, T Townsend, H Solo-Gabriele


An Investigation of the use and Durability of some Industrial and Domestic woods of Iran against Destructives factor in Caspian Sea
2007 - IRG/WP 07-10613
Use of domestic and commercial woods of the Caspian Sea forest fringes and evaluation of their durability against marine destructive factors were investigated. The samples of species of elm (Zelkova carpinifolia), oak (Quercus castanifolia), beech (Fagus orientalis), Maple (Acer insgin), Alder (Alnus subcordata), and horn beech (Carpinus betulus) were impregnated with CCA (Chrome–Cupper-Arsenic)...
S M Kazemi


Marine exposure assessment in southern Portugal of the natural resistance of a number of lesser known species of tropical hardwoods to teredinid and limnoriid borers
2007 - IRG/WP 07-10614
Naturally durable species of timber are used as an alternative to preservative treated timber for marine structures, but many species have not been evaluated for their potential for use in this environment. EN 275 specifies a 5-year test period - too long a period for screening tests to be economically viable. In this study, candidate timber species were selected for testing in the sea on the basi...
J R Williams, S M Cragg, L M S Borges, J D Icely, G S Sawyer


Corrosion of metal fasteners in contact with copper preservative treated wood
2007 - IRG/WP 07-20370
The corrosion rates of metal fasteners in contact with alkaline copper quat (ACQ) treated wood with or without commercially available water repellent was compared to that of cedar. In this experiment, fasteners were sandwiched between two pieces of treated wood and exposed to a humid environment at a slightly elevated temperature. The use of a “sandwich” design allowed periodic examination of ...
BaekYong Choi, J N R Ruddick


Use of the Digital Refractometer for the On-site Analysis of Copper-based Preservative Systems
2007 - IRG/WP 07-20371
In some counties, there are no on-site chemical analysis methods available for treatment plants to use to determine the key active ingredients in the preservative treatment solutions. The complexity of the sophisticated methodology; cost of analytical instruments and training required for operating these instruments in treating plant level are the reasons for lacking such practice. In this paper...
L Jin, T Cashman, A Preston, J Trompetter, H Trompetter


Photo-degradation of modified and non-modified wood, coated with water borne acrylic coatings during artificial light exposure
2007 - IRG/WP 07-30416
A series of experiments were carried out to investigate photo-degradation of thermally modified (at 210oC and – 0.9 bars for two hours) and non-modified spruce wood (Picea abies L (Karst)), coated with transparent and semitransparent (with 3% pigment content) acrylic coatings during artificial UV light irradiation for 200 hours. Photo-degradation was evaluated in terms of colour changes througho...
M Deka, M Tomažic, M Petric


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Eucalyptus saligna and Acacia mearnsii
2007 - IRG/WP 07-40383
Penetration, retention, and leaching of CCA (C) in relation to grain orientation were tested in small (50mm x 50mm x 200mm) sapwood and heartwood samples of Eucalyptus saligna and Acacia mearnsii. In both sapwood and heartwood of the two species, the results showed a consistent pattern: Transverse > Radial > Tangential. Whereas penetration, retention, and leaching were significantly high i...
R Venkatasamy


Influence of Grain Direction on Penetration, Retention, and Leaching of CCA(C) in Sapwood and Heartwood of Kenyan-Grown Cupressus lusitanica and Pinus patula
2007 - IRG/WP 07-40384
The influence of grain orientation on penetration, retention, and leaching of CCA (C) was tested on small samples of sapwood and heartwood of Cupressus lusitanica and Pinus patula. Samples measuring 50mm x 50mm, and 200mm in the longitudinal axis were sealed to expose only transverse, or radial, or tangential faces, pressure treated with 6% CCA (C), and penetration, retention and leaching of the ...
R Venkatasamy


Copper fixation in ACQ-D treated Chinese fir at various temperature and relative humidity conditions
2007 - IRG/WP 07-30436
In this study, the effect of different conditions of temperature, relative humidity, and duration of post-treatments on accelerating copper fixation in ACQ-D treated Chinese fir wood blocks was investigated. The conditions include the combination of three temperatures (21, 50, and 70?) and two relative humidity levels (20% and 80%), also include four temperatures (50, 70, 90, and 110?) without con...
Jinzhen Cao, Lili Yu


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


Evaluating the Process of ACQ-Treated Woods with TGAand CEM Analysis
2007 - IRG/WP 07-20374
To provide an understanding of the fundamental thermal behaviour and the disposal-end products of ACQ-treated woods, this study is comprised of two categories of examination. The first is related to the use of TGA under different thermal decomposition conditions (nitrogen or air, and 5 or 40 oC/min), and the use of EDX to examine certain residual elements of the char. The second applies the CEM ...
Han Chien Lin, Tsang-Chyi Shiah, Jung Ting Tsai


Kd values of Cu, Cr, As in different soil matrix
2007 - IRG/WP 07-50247
Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient (Kd) values of these metal components. The results revealed that Kd values were higher in chromium, followed by arsenic and copper in soil matrix. Different...
Sung-Mo Kang, Seung-Hun Shin, Ja-Oon Koo


An Investigation on Use and Durability of Some Industrial and Domestic Woods of Iran against Destructive Factors in Caspian Sea
2008 - IRG/WP 08-10636
In this study the use of domestic and commercial woods of the Caspian Sea forest fringes and evaluation of their durability against marine destructive factors were investigated. The samples of elm (Zelkova carpinifolia), oak (Quercus castanifolia), beech (Fagus orientalis), Maple (Acer insgin), Alder (Alnus subcordata), and horn beech (Carpinus betulus) species were impregnated with CCA (Chrome–...
S M Kazemi


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