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Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Non-destructive stress wave measurement of decay and termite attack in experimental wood units
1986 - IRG/WP 2256
The purpose of this study was to determine if stress wave analysis could be used to monitor the degradation of wood specimens exposed to the brown-rot decay fungi (Gloeophyllum trabeum) and of wood specimens subjected to attack by subterranean termites. One hundred fifty 3/4 by 3/4 by 12 in. Southern pine specimens were used for exposure to brown-rot decay fungi and two hundred twenty-five 3/4 by ...
R F Pellerin, R C De Groot, G R Esenther


The WOODCARE project: Development of detection methods for Death watch beetle larvae and fungal decay
1999 - IRG/WP 99-20172
Woodcare was a European project coordinated by English Heritage. The aim of the research was to develop more targeted and more environmentally friendly treatment methods for Death watch beetle infections in Oak constructions of historical buildings. TNO has developed two new methods for fast and reliable detection of Death watch beetle larvae and related fungal decay in Oak. The problem with Death...
P Esser, P Van Staalduinen, A C Tas


Laboratory testing of wood natural durability - In soil-bed assays
1998 - IRG/WP 98-20141
Laboratory methods for assessing wood decay resistance are being investigated in the framework of an ongoing European research project. This paper summarizes the main results obtained for soil-bed tests based on the European prestandard ENV 807-Test 2. The data suggest that this testing methodology is suitable for evaluating the natural durability of timber species in soil-contact under conditions...
R Sierra-Alvarez, I Le Bayon, J K Carey, I Stephan, J Van Acker, M Grinda, G Kleist, H Militz, R-D Peek


Aspects of the fungal degradation of quaternary ammonium compounds in liquid culture
1997 - IRG/WP 97-30160
Didecyldimethylammonium chloride (DDAC) is a quaternary ammonium compound (QAC) that has found use as an anti-sapstain preservative for the transportation of softwood lumber from Canada to overseas markets. However, its use is limited by the knowledge that certain mould fungi seem capable of degrading it. The aim of this research was to gain knowledge about the fungal degradation of DDAC. The effe...
J W Dubois, J N R Ruddick


Laboratory trial to identify potential in-forest treatments to control fungal pre-infections of radiata pine logs
2000 - IRG/WP 00-30220
Development of fungal infections of radiata pine logs by wood degrading fungi commences immediately after tree felling. In general, subsequent antisapstain treatments are unable to control fungal degrade on logs where the pre-treatment log storage time exceeds 2-5 days. However, use of an in-forest treatment of logs may be advantageous to log exporters to control fungal pre-infections during the p...
D R Eden, B Kreber, R N Wakeling, J G Van der Waals, C M Chittenden


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Natural durability transfer from sawmill residues of white cypress (Callitris glaucophylla). - Part 4: Analysis of extracts and treated wood for active components
2000 - IRG/WP 00-20215
In order to facilitate the commercial implementation of a large project aimed at recovering 'waste' durability components from sawmill residues of Callitris glaucophylla, it has been essential to develop analytical methodology for the important bioactive components of the heartwood extract. This methodology will be used 1) to standardise the activity of successive production batc...
Hui Jiang, M J Kennedy, L M Stephens


A preliminary comparison of GC, HPLC and ELISA analysis of resin acids in pulp mill effluents
1997 - IRG/WP 97-20120
Resin acids are naturally occurring diterpenoid carboxylic acids present in most Canadian softwoods. There are eight common resin acids that are classified into two groups; the abietanes and the pimaranes. During processing of wood products they can be released into the environment where they are of concern because of their acute toxicity toward fish and other aquatic life. Traditionally resin aci...
A N Serreqi, K Stark, Xiumei Feng, J N Saddler, C Breuil


Evaluating the resistance of wood-based panel products to fungal attack
1995 - IRG/WP 95-20071
At present there is considerable disagreement among national research institutes within Europe and panel product manufacturers on the most appropriate method of testing and indeed the need for specific biological durability testing. This paper seeks to place before a broader international audience, the issues related to development of a European standard for evaluating the resistance to fungal dec...
R G Lea, R W Berry


Detection of wood decay fungi in wood using a PCR-based analysis
1998 - IRG/WP 98-10279
We have developed a DNA-based assay to reliably detect brown rot and white rot fungi in wood at different stages of decay. DNA, isolated by a series of CTAB and organic extractions, was amplified by the polymerase chain reaction using published universal primers and basidiomycete-specific primers derived from ribosomal DNA sequences. We have surveyed 7 species of brown rot fungi, 7 species of whit...
C Jasalavich, A Ostrofsky, J Jellison


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


Mechanisms of Protection by NHA Against Fungal Decay
2002 - IRG/WP 02-10429
Treating wood with the water-borne sodium salt of N'-N-naphthaloylhydroxylamine (Na-NHA) protects wood against decay and termite damage. Initial testing indicated little or no inhibition of sapstain fungi, molds, or soft-rot fungi by Na-NHA, suggesting that the mechanism by which this compound protected wood was complex and not that of a broad-spectrum biocide. Previously, we (Green et...
F Green III, W Henry, T Schultz


Surface retentions of PCP, TCMTB and MTC obtained during a field trial of antisapstain formulations
1993 - IRG/WP 93-20002
Formulations containing NaPCP or TCMTB and MTC were included as reference products in a recent field trial of antisapstain formulations in Queensland. Retentions of these actives on the surface of treated sawn Pinus elliottii were monitored by ultrasonic solvent extraction of excised samples and analytical determination by high performance liquid chromatography. Distribution of actives with depth ...
D E Ferlazzo, M D Needham, M J Kennedy


Screening of the efficacy of tall oils against wood decaying fungi
2004 - IRG/WP 04-30354
Tall oil is a by-product in pulping of resinous wood by the sulphate process. Tall oil contains a complex mixture of wood extractives. Some of these extractives act as natural protection against wood decaying fungi while other serve as nutrition for the fungi. This report describes a screening of the efficacy of four refined tall oils with different chemical composition on wood decaying fungi. ...
G Alfredsen, P O Flæte, A Temiz, M Eikenes, H Militz


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 3: Report of first inspection of samples at Lae, Papua New Guinea
1978 - IRG/WP 446
Samples for the international marine test were placed on frames numbered I to VII. Frames numbered VII of both CCA and CCB trials are being stored dry in the laboratory at F.P.R. & D.C. Frames I to VI of both trials were suspended in the sea at Lae Harbour (Morobe Province, Papua New Guinea) on 6th December 1977. The first inspection of the CCA trial was carried out on 8th June 1978, at which ...
S M Cragg, C R Levy


Determination of boron levels in solution and in treated wood
1994 - IRG/WP 94-20041
Four methods of measuring boron levels in solutions were investigated. The methods compared included the azomethine-H method which is commonly used in soils and plant tissues, the methods outlined in the Australian Standard AS 1605 (1974) and in Wilson (1958), and the atomic absorption spectrophotometry method. Defect-free radiata pine (Pinus radiata D. Don) sapwood and wood flakes were treated to...
F J Romero, P Vinden, P Kho


The remaining concentration of inorganic wood preservative components in EN 252 stakes after ground contact
2000 - IRG/WP 00-50159
In order to determine the biological efficiency and the remaining concentration of different inorganic and organic active ingredients during service, EN 252 specimens were impregnated with 3 copper based wood preservatives. The stakes were installed in the test field of the DESOWAG GmbH, Rheinberg, for at least 7 years. At the end of the field test some of these stakes were divided into 10 uniform...
E Melcher, H-W Wegen


Susceptibility of antisapstain fungicides to rain wash-off
1994 - IRG/WP 94-30046
Results of trials using miniature timber packets and simulated rain wash-off are described. Six fungicidal actives in five commercial antisapstain formulations were involved, and a clear influence of rainfall timing after antisapstain treatment was demonstrated. Differences between actives and formulations were most marked where water-spray was applied in the first hour after treatment, though eve...
R N Wakeling, D J Cross, D R Eden, P N Maynard


Effect of some resin treatments on fungal degradation reactions
1999 - IRG/WP 99-10318
The effect of impregnation of wood with vegetable oil, tall oil and two water soluble on fungal degradation reactions was assessed by hydrolysis and enzyme activity measurements. The experiments were carried out by using isolated enzyme preparations and a living brown-rot fungus Poria placenta. The results indicate that the inhibitory effect of treatments was clearly directec towards the enzymatic...
A-C Ritschkoff, M Rättö, A J Nurmi, H Kokko, A O Rapp, H Militz


Sampling and analysis of NeXgen-treated timber
1998 - IRG/WP 98-20134
Green sawn timber surfaces of the softwood Caribbean pine and the hardwood white cheesewood were treated by dipping, spraying, and precise spiking with the antisapstain product NeXgen. After storing for either two hours or two weeks, the treated surfaces were sampled by one of four alternative protocols, which included two involving a square wad sampling punch (one hit or six hits), one involving ...
M J Kennedy, D E Ferlazzo, T L Woods, M H Freeman


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