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40 year results from the largest preservative in-ground stake trial conducted in Australia
2013 - IRG/WP 13-30624
The final results from Australia’s largest preservative in-ground stake trial are listed. There were eight test sites, six in Australia and two in Papua New Guinea. The preservatives tested include low and high temperature creosotes, PCP and various water-borne preservatives including CCA and copper chromate. The main timbers examined were sawn Pinus radiata sapwood, sawn Eucalyptus regnans hear...
L J Cookson


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Combined effects of thermal modification and ACQ-D impregnation on properties of southern yellow pine wood
2013 - IRG/WP 13-40637
In this study, samples of southern yellow pine sapwood were first thermally modified and then treated by the alkaline copper quat-type D (ACQ-D) wood preservative. Two heating temperature (180℃ and 220℃) and two concentrations of ACQ-D solution (0.9% and 1.35%) were used in the experiments. The combined effects of thermal modification and ACQ-D on leaching performance, mechanical prope...
Wang Wang, Yuan Zhu, Jinzhen Cao


Visualization of Copper in the Voids and Cell Walls of Treated Wood using X-Ray Micro-Computed Tomography
2013 - IRG/WP 13-40640
This study extends our observations of the distribution of copper in treated wood. A small wood block was cut from a southern pine batten that had been treated with a particulate-copper preservative and similar sized block was cut from a batten that had been treated with a copper-amine preservative. Both blocks were imaged using X-ray micro-computed tomography. We obtained tomograms of each treate...
P D Evans, A Limaye, H Averdunk, M Turner, T J Senden


Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Incidence of soft rot attack on preservative treated Douglas-fir poles: a preliminary survey
2014 - IRG/WP 14-10818
Occurrence of soft rot decay in Douglas-fir poles treated with ammoniacal copper zinc arsenate (ACZA) or pentachlorophenol in oil was studied. Soft rot was less prevalent in poles treated with penta, but some soft rot was found in approximately 20 % of poles examined. Soft rot was more common in poles treated with ACZA, and, when present, was found in almost 20% of the cells examined. The potenti...
P Torres Andrade, J J Morrell


The effects of copper proximity on oxalate production in Fibroporia radiculosa
2014 - IRG/WP 14-10823
Copper remains a key component used in wood preservatives available today. However, the observed tolerance of several critical wood rotting organisms continues to be problematic. Tolerance to copper has been linked to the production and accumulation of oxalate, which precipitates copper into insoluble copper-oxalate crystals, thus inactivating copper ions. The purpose of this study was to assess d...
K M Jenkins, C A Clausen, F Green III


On-site remediation treatments for framing timber in leaky buildings
2014 - IRG/WP 14-20549
Weathertightness failures in New Zealand buildings due to the combined effects of cladding choices, design and construction faults and the use of untreated framing timber has led to the so called ‘leaky building syndrome’. The latest estimated cost of the leaky building crisis in New Zealand is about NZ$11 billion. This research was conducted to provide a better understanding of the option...
T Singh, D Page, A Bennett


Effectiveness of Copper Indicators in Treated Wood Exposed to Copper Tolerant Fungi
2014 - IRG/WP 14-20554
Wood treated with a copper based wood preservative will typically turn a green color. While the depth of copper penetration can be readily discerned from the green color of the copper it is standard practice in research and commercial treating plants to make use of a color reagent such as Chrome Azurol S, Rubeanic acid or PAN indicator to reveal the penetration more clearly. When copper treat...
L Jin, K Brown, A Zahora, K Archer


Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Three-year field test of preservative-treated Canadian species in Korea
2014 - IRG/WP 14-30646
The purpose of this study was to generate field performance data in Korea on Canadian softwood species preservative-treated to Canadian standards. Two field tests of preservative-treated Canadian softwood species, one in ground contact and one above ground, were installed in Jinju, Korea in November 2010. Western hemlock and white spruce were incised and pressure-treated with alkaline copper quate...
Jieying Wang, Jong Bum Ra, P I Morris


Copper naphthenate treatment for wood crossties and timbers
2014 - IRG/WP 14-30647
Copper naphthenate (CuN) has a long history in wood preservation and is recently finding increased usage as a treatment for wooden crossties and timbers. One of the principal reasons that CuN has gained market acceptance, in addition to its efficacy against decay fungi and wood-destroying insects, is its low mammalian toxicity and environmental impact. CuN is a well proven non-restricted use pres...
J Brient


Chemistry of copper preservative treated wood
2014 - IRG/WP 14-30651
The reaction chemistry of micronized copper wood preservatives is fundamentally different from any previous inorganic preservative system. In order to study the chemistry, analytical procedures had to be developed which allowed the determination of the total copper as well as the copper which reacted with the wood forming copper-wood complexes. With the success of this approach it also became poss...
Wei Xue, P Kennepohl, J N R Ruddick


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Copper and chromium leaching from wood impregnated with chromium-copper containing preservatives: Results of different studies
2014 - IRG/WP 14-50300
Copper and chromium based wood preservatives remained one of the most important ingredients for wood protection solutions for protection of wood in demanding applications all-over the world. Leaching of heavy metals from treated wood is important from two different aspects; firstly from performance point of view, and secondly from environmental issues. However, the importance of these studies is i...
M Humar, N Thaler, E Melcher


Migration of copper from copper naphthenate treated Douglas-fir poles during storage
2014 - IRG/WP 14-50302
Preservative migration from treated wood products has raised concerns among regulators, especially when the biocides move into surface waters. In most cases, chemical levels are well below the acceptable minimum level, but can become a concern if large quantities of treated wood are stored in one location. One such case would be a location where utility poles are stored for use in emergency repai...
C S Love, C M Freitag, J J Morrell


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


Comparison of gauge and assay retention in crossties treated with copper naphthenate
2014 - IRG/WP 14-40667
Creosote has been the most widely used preservative for wooden railroad crossties or sleepers for over 100 years. Alternative preservatives such as copper naphthenate (CuN) have been shown to provide equivalent performance against decay fungi and wood destroying insects; however, the use and specification of CuN involves an education process for treaters and railroad customers alike. One differe...
J Brient, H Tomlinson, J Hughes


New Method for Pretreatment of Railroad Crossties
2014 - IRG/WP 14-40675
Creosote has been successfully utilized for nearly 150 years for the protection of railroad crossties (sleepers) in the USA and remains today as the most widely used wood preservative for this application. One of the few shortcomings of creosote as a preservative is its inability to penetrate many of the refractory hardwood species which make up the majority of crossties in the USA. Lack of full...
A S Ross, R W Clawson Jr


Laboratory Study of Relative Leachability of Chromated Copper Arsenate Preservative from Treated Woods among Soil Types of Sarawak
2014 - IRG/WP 14-50307
Wood and soils are important natural resources from the environment and serves mankind well respectively as structural materials and natural platform erecting such materials. With shortfalls of naturally durable timber species for protected in-ground uses under Malaysian environments, Chromated Copper Arsenate (CCA) treated woods are widely used instead, incurring serious potential threats of pres...
A H H Wong, P K F Chong


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