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Fixation and leaching characteristics of Douglas-fir treated with CCA-C
2004 - IRG/WP 04-50213
Fixation and leaching characteristics of CCA-treated Douglas-fir was evaluated using the expressate method and the AWPA E11-97 leaching procedure. CCA fixation, as monitored by the chromium reduction, was much faster in heartwood than in sapwood; however, copper and arsenic fixation in heartwood appeared to be incomplete regardless of the extension of fixation time. This poor fixation of copper a...
Gyu-Hyeok Kim, Yun-Sang Song, Dong-heub Lee


CCA type C depletion of Southern yellow pine utility poles
1995 - IRG/WP 95-50049
Depletion and redistribution of preservative components were evaluated on five CCA-C treated poles in service for over six years in Conley, Georgia. A statistical approach was taken in which retentions below ground were compared to retentions above ground due to a lack of initial data on individual poles. It was hypothesized that the below ground retentions should be lower than the corresponding a...
P D Osborne, R F Fox


Conforming to European standards on preservative treatment
1998 - IRG/WP 98-20150
New European standards require that specifications for the preservative treatment of timber are written in terms of the penetration and retention of preservative within the treated commodity that result from the treatment process. In order to check compliance with this type of specification, suitable methods of quantitative analysis must be available. This paper presents the results of a study by ...
E D Suttie, R J Orsler


Effects of the sulfuric acid modification of CCA treating solution
1987 - IRG/WP 3415
Sulfuric acid modification of CCA treating solution is often used to control the formation of sludges and undesirable deposits on the surface of treated wood. The consequences of sulfuric acid addition are examined in this work and negative effects are shown to far outweigh any benefits. Major risks include the loss of copper due to leaching from treated wood and the accelerated corrosion of treat...
R F Fox, H J Fry, E A Pasek, A S Ross


The potential of high pressure pulsation processes to treat white spruce lumber with water-borne preservatives
1988 - IRG/WP 3471
Laboratory work using end sealed 4x8x46 cm³ white spruce samples has been done to explore the suitability of three variants of a 2.1 MPa pulsation process for the impregnation of white spruce with CCA. The results showed that the process improved significantly the penetration of the preservatives and reduced significantly cell collapse, when compared with the results of treatment using a 2.1 MPa ...
J P Hösli, J N R Ruddick


IRG/COIPM INTERNATIONAL MARINE TEST - to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water. Progress Report 17: Report of fifth inspection (4 years) in Italy
1983 - IRG/WP 4103
The wood samples of Alstonia scholaris, Fagus sylvatica, Pinus sylvestris were submerged in the sea at Follonica, Italy, in April 1977. Follonica, latitude 42°55' North and longitude 10°45' East, is situated on the Tyrrhenian coast. The recorded temperature varies from 13°C to 25°C, salinity 37-38% and pH about 8. The inspections were carried out after 6 months (10/1977), 12 ...
A Gambetta, E Orlandi


Residual CCA levels in CCA treated poles removed from service
2000 - IRG/WP 00-50152
Fifty-two CCA treated poles removed from service after 1 - 50 years were sampled at different depths from their below ground and above ground zones and the preservative levels and mass balances related to the location in the pole and pole age. Generally CCA retentions were still well above the toxic threshold for decay in even the oldest poles. This confirms the good leach resistance of CCA and th...
P A Cooper, D Jeremic, J L Taylor


Wood preservation in Uruguay
1987 - IRG/WP 3404
The purpose of this paper is a brief description of the current status of wood treatment in Uruguay. The forest resources of the country are summarized, the environment, their economic importance and future potential. The present wood treating facilities are described, together with the chemicals used and the standards generally accepted. Wood treated products used in the Uruguayan market are cite...
G Baillod


Interactions between soft rot fungi and CCA preservatives in Betula verrucosa
1988 - IRG/WP 1367
Ultrastructural investigations were carried out to obtain information on the cell wall distribution of CCA elements during soft rot decay of 4% K33 CCA preservative treated birch (Betula verrucosa) wood. TEM observations on fibres at various stages of S2 cavity formation by mutabilis showed a distinct pattern of electron dense materials to occur within the S2 cell wall region. These materials (gra...
G F Daniel, T Nilsson


Leachability of active ingredients from some CCA treated and creosoted poles in service. A progress report after 10 years testing
1990 - IRG/WP 3627
CCA K33 TYPE B treated or creosoted poles, 10 pieces of each treatment type, have been monitored from the treatment plant to an electricity line, which was build up in Southern Finland in 1978. Preservative retention was determined by taking borings at four different levels: 1.5 m from the top end, 1 m above ground line, ground line and 0.5 m below ground. Determinations were made before setting u...
A J Nurmi


PXTS; A Metal Free Oligomer Wood Preserving System - A Summary of Data To Date
2004 - IRG/WP 04-30350
The world is continually looking for new wood preservative technology, especially to address environmental concerns. Recent changes in the USA have limited the use of arsenical containing formulations to industrial use through a negotiated voluntary cancellation of most residential label uses. PXTS (Polymeric Alkylphenol Polysulfide) offers a brand new technology that is an all organic system, lik...
M H Freeman, D D Nicholas, D Renz, R Buff


Effects of CCA treatment on settlement and growth of barnacles under field conditions
1998 - IRG/WP 98-50116
As part of a field experiment at seven European marine sites evaluating the effects of CCA treatments on non-target marine organisms, panels treated to nominal loadings of 12, 24 and 48 kg/m3 CCA were exposed at marine sites around the coast of Europe. Within two weeks of exposure, a heavy settlement of barnacles took place on the panels exposed intertidally in France. The intensity of settlement ...
S M Cragg, C Brown, R M Albuquerque, R A Eaton, P Goulletquer


Leaching from field test stakes. Results from two different methods of analysis
1993 - IRG/WP 93-50013
Field test stakes treated with Boliden K33 containing copper, chromium and arsenic exposed at three different fields in Sweden and rejected due to decay, have in two studies been analysed regarding leaching and remaining preservatives. The stakes have been exposed during 20 to 43 years. The density of the stakes and content of copper, chromium and arsenic have been determined in the top part of th...
F G Evans, M-L Edlund


Preservative treatment of round bamboos by a new technique - Some further studies. Part 1
1990 - IRG/WP 3607
In general, the easy susceptibility of bamboos to wood destroying agencies is a major constraint in its rational utilisation. This is more so in tropical countries like India where wood destroying agencies are quite active. In an earlier publication, it was reported that round bamboo specimens of Bambusa balcooa, having three nodes, could be satisfactorily treated by CCA by a new technique develop...
V R Sonti, B Chatterjee


Toxic wood preserving chemicals in the environment: Kenya - a cause for concern
1998 - IRG/WP 98-50101-17
The uncontrolled release of wood preserving chemicals into the environment, in most African countries, is discussed. Kenya has some 25 wood preservation plants, 23 of which use formulations of Copper- Chrome-Arsenate (CCA). The bulk of treated timbers consists of poles and posts used in ground contact. Poor fixation of CCA elements are associated with the species used, Eucalyptus saligna and Acaci...
R Venkatasamy


Multiple-Phase Pressure (MPP) Process: One-stage CCA treatment and accelerated fixation process. 3. Effect of process variables on sapwood treatment and CCA fixation.
1998 - IRG/WP 98-40114
The Multiple-Phase Pressure (MPP) Process achieves treatment and fixation as combined process using hot CCA, within a 2-3 hour time-frame. Timber is treated to saturation with hot CCA using an empty cell process. During the pneumatic pressure phase, hot solution is held in the wood in an otherwise liquid-free treatment vessel until fixation is >95% complete. This report details a factorial des...
H Pearson, K Nasheri, J A Drysdale, G Durbin, M E Hedley


The susceptibility to sludging of sulfate and oxide CCA
1990 - IRG/WP 3599
Radiata pine sapwood was treated separately with a sulphate CCA-C and an oxide CCA in a pilot scale pressure plant using a full cell process. CCA solutions were recovered from the final vacuum phase, placed in plastic tubes, and their susceptibility to sludging determined by examining changes in solution pH, time required for sludge to form and weight and chemical composition of sludge formed. Sul...
B T Mutandadzi, P D Evans


Fungal degradation of wood treated with metal-based preservatives. Part 1: Fungal tolerance
1996 - IRG/WP 96-10163
In recent years, concerns have arisen about the leaching of heavy metals from wood treated with chromated copper arsenate (CCA), particularly because of the large amount of CCA treated wood that will be discarded in the coming years. The long term objectives of this work are to determine the fate of copper, chromium and arsenic with the aging and potential decay of CCA-treated wood, and to develop...
B Illman, T L Highley


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Comparative study on the leaching of wood preservatives between natural exposure and accelerating laboratory conditions
1999 - IRG/WP 99-50134
Impregnated specimens with CCA, ACQ, and BAAC were subjected to leaching tests. Specimens of 2x2x1 cm3 in size were used for the laboratory leaching test for 10 days according to JIS K 1571. Specimens of 25x1 x1 cm3 were used for outdoor leaching test for 6 months. Total leaching amounts of boron per cm3 of specimens treated with BAAC were 325 µg in the laboratory test and 206 µg in the outdoor ...
K Yamamoto, S Motegi, A Inai


Use of the enzyme-linked immunoassay (ELISA) and immunocytochemistry to detect soft rot in preservative treated and untreated wood
1990 - IRG/WP 2347
A polyclonal antibody was raised against mycelial extracts from the soft rot fungus Phialophora mutabilis. In ELISA assays, the antibody showed strong reactions with its own antigen and strong to moderate cross reactions with 6 other Phialophora soft rot species. With the exception of Ceratocystis albida, the antibody gave only weak or negative reactions with 11 other mold, blue stain and rot fung...
G F Daniel, T Nilsson


Developments in wood preservation
1976 - IRG/WP 366
The purpose of this paper is to comment very briefly upon recent developments in wood preservation so that members of the Working Group have a basic knowledge of the activities in other countries. The last paper was prepared in 1974 and this paper refers to developments since that time. The last edition of this paper was welcomed by members of IRG. Many members wrote to the author to express their...
B A Richardson


Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Changes in transverse wood permeability during the drying of rimu and radiata pine
1990 - IRG/WP 3636
When softwoods are dried and subsequently impregnated with waterborne preservatives two problems frequently occur, preservative screening of multi-salt preservatives and difficult re-drying. To study the causes, the permeability of rimu and radiata pine wood has been measured along the three principal directions. The radial and tangential permeabilities of the green sapwood of the two species were...
R E Booker


Silica treatments to protect timber from marine borers
2001 - IRG/WP 01-30270
Siliceous timbers such as turpentine (Syncarpia glomulifera) are highly resistant to certain marine borers. Attempts to mimic this resistance by chemical treatment however, have met with limited success. This paper describes the impregnation of Pinus radiata and eucalypt timber specimens with organo-silicate formulations. The treated timber gains a pattern of resistance to marine borers that appro...
D Scown, L J Cookson, K J McCarthy


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